Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: Factors controlling fractionation of REE in hydrothermal systems     

N. S. Bortnikov  N. V. Gorelikova  P. G. Korostelev  V. G. Gonevchuk 《Geology of Ore Deposits》2008,50(6):445-461

The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized.  相似文献   

Normative quartz as an indicator of the mass transfer intensity during the postmagmatic alteration of the Botuobinskaya pipe kimberlites (Yakutia)     

V.B. Vasilenko  A.V. Tolstov  V.A. Minin  L.G. Kuznetsova  N.V. Surkov 《Russian Geology and Geophysics》2008,49(12):894-907

The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO₂–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds.  相似文献   

Soil-to-dwelling radon isotope ratio in the Baikal region     

B.P. Chernyago  A.I. Nepomnyashchikh  G.I. Kalinovskii 《Russian Geology and Geophysics》2008,49(12):971-977

Relations between indoor and soil gas radon were experimentally studied in villages of the Baikal region. On the basis of the obtained data, the soil-to-indoor radon ratio was calculated, which can be used for prediction of radon pollution in buildings of the same kind.  相似文献   

Intrayear irregularities of the Earth’s rotation     

L. D. Akulenko  Yu. G. Markov  V. V. Perepelkin  L. V. Rykhlova 《Astronomy Reports》2008,52(7):590-597

The methods of celestial mechanics can be used to construct a mathematical model for the perturbed rotational motions of the deformable Earth that can adequately describe the astrometric measurements of the International Earth Rotation Service (IERS). This model describes the gravitational and tidal influences of the Sun and Moon. Fine resonant interactions of long-period zonal tides (annual, semiannual, monthly, and biweekly) with the diurnal and semidiurnal tides are revealed. These interactions can be reliably confirmed via a spectral analysis of the IERS data. Numerical modeling of tidal irregularities of the Earth’s axial rotation was carried out, focusing on the analysis and forecasting of variations of the day length occurring within short time intervals of a year or shorter (intrayear variations).  相似文献   

Long-term variability of a complete sample of flat-spectrum radio sources at declinations of 4°–6° (B1950)     

A. G. Gorshkov  V. K. Konnikova  M. G. Mingaliev 《Astronomy Reports》2008,52(4):278-298

We present the results of twenty-year observations of a complete sample of 68 flat-spectrum radio sources with flux densities S _{3.9 GHz} > 200 mJy carried out at centimeter wavelengths with the RATAN-600 radio telescope. Since 1995, we have observed simultaneously at six frequencies between 0.97 and 21.7 GHz. Of the 56 sources identified with optical objects, 41 are quasars with redshifts between 0.293 and 3.263. Based on our analysis of the spectral shapes, we divide the sources into four classes. Changes of spectral class for individual sources are fairly rare. Based on the light curves and spectra, in most cases, a flare’s evolution is in accordance with a model in which the variations result from the evolution of a shock in the radio jet. The main result of our study is that there is no redshift dependence for the true linear sizes of the radiating regions, the variability indices derived for all 20 years of data or for individual flares, or the peak frequencies of the spectra of the compact radio emission. We suggest that this testifies to an absence of cosmological evolution of the sample quasars, at least to z ≈ 3.  相似文献   

The Seyfert 1 galaxy Ark 120. Spectral variability in 1992–2005     

V. T. Doroshenko  S. G. Sergeev  V. I. Pronik 《Astronomy Reports》2008,52(6):442-462

We have studied the variability of the Hβ line and the adjacent continuum in the spectrum of the Seyfert galaxy Ark 120, based on spectral observations of the galaxy’s nucleus obtained in the Crimea in 1992–2005, supplemented by published data for 1988–1996. Irregular variability on various timescales (years to days) can be accompanied by periodic brightness variations in both the continuum and the Hβ line, with a period of P ～ 430 days and an amplitude of Δm ～ 0.2 ^m in the continuum, which were traced for more than 13 cycles. In total, in 1988–2005, the flux variations in the line lag those in the continuum by 55 ± 9 days if calculated from the peak of the cross correlation function, or by 72 ± 7 days, if calculated from the centroid of the CCF. The delay is correlated with the continuum brightness, increasing when the continuum flux increases. The Hβ line profiles indicate both a high degree of diversity and the presence of features that recur after various extended time intervals. Analysis of the evolution of the differences between each individual normalized line profile and the mean normalized profile indicates systematic motion of excesses relative to the average profile from negative to positive radial velocities. In contrast, parts of the Hβ line with low radiation relative to the mean normalized profile evolve in the opposite direction (from the red to the blue Hβ wing). This pattern is also typical for the rotating broad-line region, if this region has the form of a disk. The rotation period exceeds 9000–10000 days, or 25–27 years. The size of the broad-line region calculated form this period corresponds to a reverberation time of no fewer than 30 days, consistent with the results of cross-correlation analysis.  相似文献   

Mirdita Zone ophiolites and associated sediments in Albania reveal Neotethys Ocean origin   总被引：1，自引：1，他引：0  

Hans-Jürgen Gawlick  Wolfgang Frisch  Lirim Hoxha  Paulian Dumitrica  Leopold Krystyn  Richard Lein  Sigrid Missoni  Felix Schlagintweit 《International Journal of Earth Sciences》2008,97(4):865-881

The Mirdita Ophiolite Zone in Albania is associated with widespread mélanges containing components of up to nappe-size. We dated matrix and components of the mélange by radiolarians, conodonts, and other taxa. The components consist of radiolarites, pelagic limestones and shallow-water limestones, all of Triassic age, as well as ophiolites. Triassic radiolarite as a primary cover of ophiolite material proves Middle Triassic onset of Mirdita ocean-floor formation. The mélange contains a turbiditic radiolarite-rich matrix (“radiolaritic flysch”), dated as Late Bajocian to Early Oxfordian. It formed as a synorogenic sediment during west-directed thrusting of ophiolite and sediment-cover nappes representing ocean floor and underplated fragments of the western continental margin. The tectonic structures formed during these orogenic events (“Younger Kimmeridian or Eohellenic Orogeny”) are sealed by Late Jurassic platform carbonates. The geological history conforms with that of the Inner Dinarides and adjoining areas; we therefore correlate the Mirdita-Pindos Ophiolite Zone with the Vardar Zone and explain its present position by far-distance west-directed thrusting.  相似文献   

Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite     

Tracy J Lund  Carla M Koretsky  Christopher J Landry  Melinda S Schaller  Soumya Das 《Geochemical transactions》2008,9(1):9

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.  相似文献   

Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics     

CV Ramana  U Becker  V Shutthanandan  CM Julien 《Geochemical transactions》2008,9(1):8

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.  相似文献   

Spatiotemporal Patterns of Subtidal Benthic Microalgal Biomass and Community Composition in Galveston Bay,Texas, USA     

James L. Pinckney  Alyce R. Lee 《Estuaries and Coasts》2008,31(2):444-454

Many Gulf of Mexico estuaries have low ratios of water volume to bottom surface area, and benthic processes in these systems likely have a major influence on system structure and function. The purpose of this study was to determine the spatiotemporal distribution of biomass and community composition of subtidal benthic microalgal (BMA) communities in Galveston Bay, TX, USA, compare BMA community composition and biomass to phytoplankton in overlying waters, and estimate the potential contribution of BMA to the trophodynamics in this shallow, turbid, subtropical estuary. The estimates of BMA biomass (mean = 4.21 mg Chl a m⁻²) for Galveston Bay were within the range of the reported values for similar Gulf of Mexico estuaries. BMA biomass in the central part of the bay was essentially homogeneous, whereas biomass at the seaward and upper bay ends of the transect were significantly lower. Peridinin, fucoxanthin, and alloxanthin were the three carotenoids with the highest concentrations, with fucoxanthin having the highest mean concentration (1.82 mg m⁻²). The seaward and landward ends of the transect differed from the central region of the bay with respect to the relative abundances of chlorophytes, cyanobacteria, and photosynthetic bacteria. Benthic microalgal community composition also showed a gradual shift over time due to changes in the relative abundances of photosynthetic bacteria, cryptophytes, dinoflagellates, and cyanobacteria. Major changes in community composition occurred in the spring months (March to April). On an areal basis, BMA biomass in Galveston Bay occurred at minor concentrations (16.5%) relative to phytoplankton. Furthermore, the concentrations of carotenoid pigments for phytoplankton and BMA (fucoxanthin, alloxanthin, and zeaxanthin) were correlated (r = 0.48 to 0.61), suggesting a close linkage between microalgae in the water column and sediments. The contribution of BMA to the primary productivity of the deeper waters (>2 m) of Galveston Bay is probably very small in comparison to shallower waters along the bay margins. The significant similarities in the community composition of phytoplankton and BMA illustrate the potential importance of deposition and resuspension processes in this turbid, shallow estuary.  相似文献