Hydrochemistry and nutrients dynamic in the Suquía River urban catchment’s,Córdoba,Argentina     

Andrea I. Pasquini  Stella M. Formica  Gabriela A. Sacchi 《Environmental Earth Sciences》2012,65(2):453-467

Suquía River is a medium-sized hydrological system (basin area of ~7,700 km²) that supplies fresh water to Córdoba city, a town of ~1,500,000 inhabitants in central Argentina. This paper examines the present-day hydrochemistry of Suquía River urban catchment analyzing its major and minor dissolved components, and the nutrients variability by means of QUAL-2K modeling software. The Suquía River has bicarbonate-type waters upstream the city and sulfate-type waters right downstream, whereas they exhibit a mixed-to-alkali-type cationic composition. The seasonal analysis of its major dissolved constituents clearly showed a dilution process during the wet season (i.e. austral summer). In the last 20 years, the Suquía River has modified its anionic composition, now showing higher relative concentrations of SO₄ ²⁻ as a consequence of urban activities. However, trace elements dissolved concentrations do not evidence a strong pollution effect. Nutrients [nitrogen species, total phosphorous (TP)] and related parameters, such as biochemical oxygen demand (BOD), and dissolved oxygen (DO), evidence a clear influence of human activities. The QUAL-2K model was used to evaluate the spatial behavior of selected nutrients and associated variables, (i.e. TP, N–NH₄ ⁺, N–NO₃ ⁻, DO, BOD). Nutrient concentrations are affected by point sources of contaminants, particularly domestic waste and sewage, as well as by diffuse agricultural pollution. A calibrated QUAL-2K modeling exercise clearly shows the impact of the Córdoba city’s municipal wastewater treatment plant on the Suquía River water quality.  相似文献   

Geochemical processes and mobilization of toxic metals and metalloids in an As-rich base metal waste pile in Zimapán,Central Mexico     

M.A. Armienta  G. Villaseñor  O. Cruz  N. Ceniceros  A. Aguayo  O. Morton 《Applied Geochemistry》2012

The geochemistry and mineralogy of samples collected along depth profiles from an As-rich tailing deposit with abundant calcite was studied to determine the processes that influence the mobility of Fe, Zn, Cu, Ni, Cd, As, Sb, Cr and Tl. In spite of their near neutral pH, almost all of them are acid potential generators. Total concentrations decreased as: Fe > As > Zn > Pb > Cu > Sb > Cd > Cr > Ni > Tl. Soluble contents were lower and followed a slightly different order. Mobility decreased as: Tl > Cd, Zn, Cu, Sb, Ni, As > Fe, Pb > Cr. Higher soluble concentrations of Fe, Cu, Zn, As, Pb, and Ni were found in low-pH samples and of Sb and Tl in near-neutral samples. Sulfide oxidation processes are developing in the tailing’s dam. These processes do not have a trend with depth but occur mainly in acid layers. Near neutral layers formed by primary sulfides and calcite probably correspond to wastes produced from the processing of ore coming mainly from pods within the skarn, and acid layers with abundant secondary minerals from material mined from chimneys and mantos. The presence of calcite influences speciation, neutralizes acid mine drainage (AMD), and decreases the mobility of most toxic metals and metalloids (TMMs). However, a hard-pan layer was not observed in the studied profiles. Retention of TMM within tailings probably occurs through the formation of low solubility metal carbonates and from elevation of pH that promotes Fe hydroxides precipitation that may retain As, Sb and metals. Calcite occurrence promotes As, Cd, Cu, Fe, Zn, Pb, Cd and Cr retention, does not play a role on Tl and Ni mobilization, and increases Sb release.  相似文献   

On Frontal Zone Analysis in the Tropical Region of the Northeast Brazil     

Natalia Fedorova  Vladimir Levit  Cezar Duarte da Cruz 《Pure and Applied Geophysics》2016,173(4):1403-1421

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Experimental constraints on the relative stabilities of the two systems monazite-(Ce) – allanite-(Ce) – fluorapatite and xenotime-(Y) – (Y,HREE)-rich epidote – (Y,HREE)-rich fluorapatite,in high Ca and Na-Ca environments under P-T conditions of 200–1000 MPa and 450–750 °C     

Budzyń  Bartosz  Harlov  Daniel E.  Kozub-Budzyń  Gabriela A.  Majka  Jarosław 《Mineralogy and Petrology》2017,111(2):183-217

Mineralogy and Petrology - The relative stabilities of phases within the two systems monazite-(Ce) – fluorapatite – allanite-(Ce) and xenotime-(Y) – (Y,HREE)-rich fluorapatite...  相似文献   

A model for CO<Subscript>2</Subscript> storage and seismic monitoring combining multiphase fluid flow and wave propagation simulators. The Sleipner-field case     

Gabriela B. Savioli  Juan E. Santos  José M. Carcione  Davide Gei 《Computational Geosciences》2017,21(2):223-239

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Modal response analysis of multi‐support structures using a random vibration approach          下载免费PDF全文

Ernesto Heredia‐Zavoni  Sandra Santa‐Cruz  Francisco L. Silva‐González 《地震工程与结构动力学》2015,44(13):2241-2260

A formulation is developed for modal response analysis of multi‐support structures using a random vibration approach. The spectral moments of the structural response are rigorously decomposed into contributions from spectral moments of uncoupled modal responses. An advantage of the proposed formulation is that the total dynamic response can be obtained on the basis of mode by mode uncoupled analyses. The contributions to the total response from modal responses under individual support ground motions and under cross‐correlated pairs of support ground motions can be recognized explicitly. The application and performance of the formulation is illustrated by means of an example using a well‐established coherency spectrum model and widely known power spectra models, such as white noise and Kanai–Tajimi. The first three spectral moments of displacement, shear, and bending moment responses are computed, showing that the formulation produces the same results as the exact solution. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Early angiosperm diversification: evidence from southern South America     

Sergio Archangelsky  Viviana Barreda  Mauro G. Passalia  Maria Gandolfo  Mercedes Prámparo  Edgardo Romero  Rubén Cúneo  Alba Zamuner  Ari Iglesias  Magdalena Llorens  Gabriela G. Puebla  Mirta Quattrocchio  Wolfgang Volkheimer 《Cretaceous Research》2009,30(5):1073-1082

In this report, we analyze the angiosperm fossil record (micro- and megafossil) from the central and southern basins of Argentina, southern South America, deposited between the late Barremian (128.3 Ma) to the end of the Coniacian (85.8 Ma). Based on this analysis, three major stages in the evolution of the angiosperms in the southernmost region of South America are established as follows: the late Barremian–Aptian, the latest Aptian-earliest Albian, and the middle Albian- Coniacian. The comparison between our fossil data set and those from Australia, North America, Asia and Europe suggest that the evolution and diversification of the angiosperms at mid and high latitudes in both hemispheres occurred roughly synchronously.  相似文献   

基于Gabor-Daubechies小波束叠前深度偏移的角度域共成像道集   总被引：11，自引：5，他引：6       下载免费PDF全文

陈凌  吴如山  王伟君 《地球物理学报》2004,47(5):876-885

传统炮检距域共像集（CIG）在复杂介质中因波传播的多路径而存在反射体位置不确定的问题. 角度域CIG由于克服了这一缺陷而逐步成为速度分析、AVA以及振幅保真偏移成像等研究的主要手段. 以波动理论为基础的地震偏移成像方法的发展为获得高质量的角度域CIG提供了可靠的实现途径. 其中,基于波场局域化分解和传播的小波束域波场延拓和偏移成像方法,因其波场分解基本函数和传播算子在空间和方向上的双重局域特性,而成为角度相关分析研究的有效工具. 本文在采用Gabor Daubechies框架分解的小波束叠前角度域偏移成像基础上,利用不同的叠加方法由局部角度域像矩阵得到了反射角域CIG（CRAIG）和倾角域CIG（CDAIG）. 以SEG EAGE二维盐体模型为例,通过对CRAIG和CDAIG的对比,探讨了这两种角度域CIG的特点及其在地震偏移成像中的潜在应用.  相似文献   

Determination of the spinel group end-members based on electron microprobe analyses     

Gabriela R. Ferracutti  M. Florencia Gargiulo  M. Luján Ganuza  Ernesto A. Bjerg  Silvia M. Castro 《Mineralogy and Petrology》2015,109(2):153-160

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Sensitivity of near-surface Tropical Instability Waves to submonthly wind forcing in the tropical Atlantic     

Gabriela Athi  Frdric Marin  Anne-Marie Treguier  Bernard Bourls  Catherine Guiavarc&#x;h 《Ocean Modelling》2009,30(4):241-255

This study demonstrates the sensitivity of the near-surface properties in the tropical Atlantic Ocean to the high-frequency of the winds in numerical simulations. At intra-seasonal timescales (2–50 days), two distinct period ranges dominate the variability in the upper ocean: periods between 2 and 20 days, which are essentially wind-forced and periods between 20 and 50 days, due mostly to Tropical Instability Waves (TIWs). Using a numerical model forced by different wind fields, it is shown that the characteristics of the intra-seasonal variability in the ocean surface mixed-layer are strongly dependent on the wind forcing. Submonthly winds are shown to force large variability in the upper ocean that can strikingly decrease the amplitude of the TIWs in the mixed-layer and their imprint on the horizontal distribution of sea surface temperatures. Wind products containing too much energy at submonthly periods thus prevent wind-forced simulations from reproducing a realistic surface signature of TIWs, when compared to satellite observations of sea surface temperature. In addition, submonthly wind variability may be responsible for part of the observed interannual variability of the TIW signature in the temperature. The impact of submonthly winds is strongest in the mixed-layer: beneath the mixed-layer, all simulations show similar characteristics of the TIWs.  相似文献