Selenium in volcanic environments: A review   总被引：1，自引：0，他引：1  

Geerke H. Floor  Gabriela Román-Ross 《Applied Geochemistry》2012

Selenium is a chemical element with major environmental implications, due to the extremely narrow range between essential and toxic concentrations. Volcanoes emit significant amounts of Se, which has an enormous impact on the Se cycle and potentially human and animal health. This paper presents a broad overview of the current state of knowledge of major aspects of volcanic derived Se, focussing on the processes in soils and aquifers.  相似文献   

Aggregation of humic acid in solution: Contributions of different fractions     

Gabriela Chilom  Angela S. Bruns  James A. Rice 《Organic Geochemistry》2009,40(4):455-460

The role of lipid components in the aggregation of several humic acids isolated from different sources was investigated using surface tensiometry. A combination of aqueous alkaline and organic solvent extractions was used to isolate two humic-like fractions (HA₁ and HA₂) and one lipid-like fraction from each humic acid. Fraction HA₁ represents approximately two-thirds of the total organic carbon of the original humic acid and under alkaline conditions is a weak surfactant that lowers the surface tension of water by only a small amount. The HA₂ fraction represents up to one-third of the humic acid and significantly lowers the surface tension of water. It is also intimately associated with the lipid fraction. Unlike the original humic acid samples, HA₂ does not show micelle-like aggregation over the concentration range studied. Aggregate formation is discussed as an emergent characteristic that results from the interaction of the humic acid’s components with the lipid components serving a facilitative role.  相似文献   

Present Limnological Conditions and Recent (ca. 340 yr) Palaeolimnology of a Tropical Lake in the Sierra de Los Tuxtlas, Eastern Mexico     

Margarita Caballero  Gabriela Vázquez  Socorro Lozano-García  Alejandro Rodríguez  Susana Sosa-Nájera  Ana Carolina Ruiz-Fernández  Beatriz Ortega 《Journal of Paleolimnology》2006,35(1):83-97

The Sierra de Los Tuxtlas is a recently active volcanic field, with eruptions in 1664 and 1792. It holds one of the reserves of tropical evergreen forest in Mexico, as well as several maar lakes. One of them, Lago Verde, was chosen for a three-fold study (1) on its present limnological conditions, (2) on the algal community living in the water column and preserved in the surface sediments; and (3) on its recent history (ca. 340 yr). The palaeolimnological study was based on multiproxy analyses on core material dated by ²¹⁰Pb, ¹³⁷Cs and ¹⁴C. Lago Verde is a small, shallow lake with dilute, slightly alkaline water (CO₃²⁻ + HCO₃⁻ > Cl⁻ > SO₄²⁻, Na⁺ + K⁺ > Ca²⁺ > Mg²⁺). It is turbid, eutrophic, with high phosphorus levels. It is a warm polymictic lake, with thermal and oxygen stratification establishing by midday during the warm months. The lake does not stratify in winter. Diatoms dominate the phytoplankton community in the cold ‘nortes’ season, Cyanobacteria in summer, and Chlorophyta in autumn. Cyanobacteria (Chroococcales) are not well preserved in the surface sediments while Chlorophyta are better preserved. Sedimentary diatoms are well preserved, dominated by the three most abundant species in the water column: Achnanthidium minutissimum, Fragilaria capucina and Aulacoseira granulata. The base of the studied sequences is constrained by the historic eruption of 1664. The period from 1664 to 1963 is characterised by a meso-eutrophic lake. Tropical Forest vegetation reaches maximum values between ca. 1800 and 1963. Between ca. 1785 and 1885 the lake was slightly shallower than in the rest of the 1664–1963 period, probably recording climatic variability. An early pulse of anthropogenic disturbance was recorded by ca. 1921 and after ca. 1963 intense forest clearance and high erosion rates led to a more turbid, more productive, nutrient-rich lake. The highest anthropogenic impact was reached by ca. 1988; afterwards the lake and its basin reached a new balance, with the establishment of the present modern conditions.  相似文献   

Transtensional fault-termination basins: an important basin type illustrated by the Pliocene San Jose Island basin and related basins in the southern Gulf of California, Mexico     

Paul J. Umhoefer  Tobias Schwennicke†  Maya T. Del Margo  Gabriela Ruiz-Geraldo†  James C. Ingle Jr.  ‡  William McIntosh§ 《Basin Research》2007,19(2):297-322

Transtensional basins are sparsely described in the literature compared with other basin types. The oblique‐divergent plate boundary in the southern Gulf of California has many transtensional basins: we have studied those on San Jose island and two other transtensional basins in the region. One major type of transtensional basin common in the southern Gulf of California region is a fault‐termination basin formed where normal faults splay off of strike‐slip faults. These basins suggest a model for transtensional fault‐termination basins that includes traits that show a hybrid nature between classic rift and strike‐slip (pull‐apart) basins. The traits include combinations of oblique, strike‐slip and normal faults with common steps and bends, buttress unconformities between the fault steps and beyond the ends of faults, a common facies pattern of terrestrial strata changing upward and away from the faults into marine strata, small fault blocks within the basin that result in complex lateral facies relations, common Gilbert deltas, dramatic termination of the margin of the basin by means of fault reorganization and boundary faults dying and an overall short basin history (few million years). Similar transtensional fault‐termination basins are present in Death Valley and other parts of the Eastern California shear zone of the western United States, northern Aegean Sea and along ancient strike‐slip faults.  相似文献   

Regional deterministic characterization of fracture networks and its application to GIS-based rock fall risk assessment     

M. Sturzenegger  M. Sartori  M. Jaboyedoff  D. Stead 《Engineering Geology》2007,94(3-4):201-214

The study investigates the possibility to incorporate fracture intensity and block geometry as spatially continuous parameters in GIS-based systems. For this purpose, a deterministic method has been implemented to estimate block size (Bloc3D) and joint frequency (COLTOP). In addition to measuring the block size, the Bloc3D Method provides a 3D representation of the shape of individual blocks. These two methods were applied using field measurements (joint set orientation and spacing) performed over a large field area, in the Swiss Alps. This area is characterized by a complex geology, a number of different rock masses and varying degrees of metamorphism. The spatial variability of the parameters was evaluated with regard to lithology and major faults. A model incorporating these measurements and observations into a GIS system to assess the risk associated with rock falls is proposed. The analysis concludes with a discussion on the feasibility of such an application in regularly and irregularly jointed rock masses, with persistent and impersistent discontinuities.  相似文献   

Using the photons from the Crab Nebula seen by GLAST to calibrate MAGIC and the imaging air Cherenkov telescopes     

D. Bastieri  C. Bigongiari  E. Bisesi  G. Busetto  A. De Angelis  B. De Lotto  T. Lenisa  F. Longo  M. Mariotti  A. Moralejo  D. Pascoli  L. Peruzzo  R. Rando  A. Saggion  P. Sartori  V. Scalzotto 《Astroparticle Physics》2005,23(6):572-576

In this article we discuss the possibility of using the observations by GLAST of standard gamma sources, as the Crab Nebula, to calibrate imaging air Cherenkov detectors, MAGIC in particular, and optimise their energy resolution. We show that at around 100 GeV the absolute energy calibration uncertainty of Cherenkov telescopes can be reduced to 10% by means of such cross-calibration procedure.  相似文献   

Disrupting biogeochemical cycles - Consequences of damming   总被引：12，自引：0，他引：12  

Gabriela Friedl  Alfred Wüest 《Aquatic Sciences - Research Across Boundaries》2002,64(1):55-65

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Textural evidence for recent co-seismic circulation of fluids in the Nojima fault zone, Awaji island, Japan     

Anne-Marie Boullier  Koichiro Fujimoto  Tomoyuki Ohtani  Gabriela Roman-Ross  ric Lewin  Hisao Ito  Philippe Pezard  Benoît Ildefonse 《Tectonophysics》2004,378(3-4):165

The Hirabayashi borehole (Awaji Island, Japan) was drilled by the Geological Survey of Japan (GSJ) 1 year after the Hyogo-ken Nanbu (Kobe) earthquake (1995, M_JMA=7.2). This has enabled scientists to study the complete sequence of deformation across the active Nojima fault, from undeformed granodiorite to the fault core. In the fault core, different types of gouge and fractures have been observed and can be interpreted in terms of a complex history of faulting and fluid circulation. Above the fault core and within the hanging wall, compacted cataclasites and gouge are cut by fractures which show high apparent porosity and are filled by 5–50 μm euhedral and zoned siderite and ankerite crystals. These carbonate-filled fractures have been observed within a 5.5-m-wide zone above the fault, but are especially abundant in the vicinity (1 m) of the fault. The log-normal crystal size distributions of the siderite and ankerite suggest that they originated by decaying-rate nucleation accompanied by surface-controlled growth in a fluid saturated with respect to these carbonates. These carbonate-filled fractures are interpreted as the result of co-seismic hydraulic fracturing and upward circulation of fluids in the hanging wall of the fault, with the fast nucleation of carbonates attributed to a sudden fluid or CO₂ partial pressure drop due to fracturing. The fractures cut almost all visible structures at a thin section scale, although in some places, the original idiomorphic shape of carbonates is modified by a pressure-solution mechanism or the carbonate-filled fractures are cut and brecciated by very thin gouge zones; these features are attributed to low and high strain-rate mechanisms, respectively. The composition of the present-day groundwater is at near equilibrium or slightly oversaturated with respect to the siderite, calcite, dolomite and rhodochrosite. Taken together, this suggests that these fractures formed very late in the evolution of the fault zone, and may be induced by co-seismic hydraulic fracturing and circulation of a fluid with a similar composition to the present-day groundwater. They are therefore potentially related to recent earthquake activity (<1.2 Ma) on the Nojima fault.  相似文献   

Current status,distribution, life cycle and ecology ofRhithrogena germanica Eaton, 1885 in Switzerland: Preliminary results (Ephemeroptera,Heptageniidae)     

Verena Lubini  Michel Sartori 《Aquatic Sciences - Research Across Boundaries》1994,56(4):388-397

Rh. germanica is a European species that, due to human impacts, has progressively disappeared from its original territories and is now considered rare. In SwitzerlandRh. germanica has disappeared from the Aare, Broye and Kleine Emme rivers and is actually found in a limited reach of the River Rhine and some of its tributaries (Limmat, Sihl, Thur and Töss rivers).Rh. germanica is a univoltine species, hatching probably in summer. The emergence occurs from February to the beginning of April. It takes place on the water surface. Laboratory observations have shown that the subimaginal stage lasts four days.Rh. germanica occurs on different substrate types, ranging from stones and cobbles to pebbles and gravel. The larvae are more abundant in zones of erosion with coarse and porous sediments than in depositional zones with fine sediments and silts. They are most abundant in riffles with water velocities from 20 to 150 cm/sec. The species tolerates moderately organic-polluted waters.The particular strategy concerning growth and emergence ofRh. germanica is also discussed.  相似文献   

Santite,a new mineral phase from Larderello,Tuscany     

Stefano Merlino  Franco Sartori 《Contributions to Mineralogy and Petrology》1970,27(2):159-165

A new borate mineral has been found in a sample from Larderello, mixed with larderellite and lesser amounts of sassolite. The mineral is never well crystallized, but it constantly appears as very small, clear and colourless grains; its refractive indices are: =1.422, =1.435, =1.480. Single-crystal X-ray photographs show that the mineral is orthorombic with cell dimensions: =11.10 Å, b=11.18 Å, c=9.08 Å. X-ray powder diffraction and partial chemical analyses carried out on the whole sample (it being impossible to separate a sufficient quantity of pure material) confirm the foregoing data, according to which the mineral may be considered as the natural equivalent of the synthetic compound KB₅O₈ · 4H₂O. It is likely that it originated from the reaction between potassium-bearing hot solutions and primary deposits of larderellite. It is named for the Tuscan naturalist Giorgio Santi.This new mineral has been approved by the Commission on New Minerals and New Mineral Names of the International Mineralogical Association.This research was supported by Consiglio Nazionale delle Ricerche, Roma.  相似文献