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91.
Possible xenoestrogenic effects were investigated, for the first time, in two bivalve species from the Lagoon of Venice (Italy): the clam Tapes philippinarum and the cockle Cerastoderma glaucum. Bivalves were collected far from their reproductive phase at the very early stage of gametogenesis (January), and in the pre-spawning period (June) in six sites. Vitellogenin (Vg)-like proteins (a biomarker of exposure to estrogenic compounds) were measured by the alkali-labile phosphate method (ALP), in both haemolymph and digestive gland from males and females (when it was possible to distinguish sex by microscopic observation of gonadal tissue). Haemolymph calcium concentrations (a parameter considered closely related to the presence of Vg-like proteins) and the bivalve condition index (CI) were also measured. In both seasons, bivalves collected at Campalto (near a sewage treatment plant) and Marghera (a highly contaminated area) had higher Vg-like protein levels, particularly in haemolymph, than animals from the other sampling sites. Interestingly, CI had high values in these polluted sites. In June only, Vg-like proteins and Ca2+ levels in haemolymph exhibited similar trends in both bivalve species at most sampling sites. The responsiveness of bivalves to environmental xenoestrogens was higher in June, allowing better discrimination among sites. The present study demonstrates that animals from highly polluted areas have increased Vg-like protein levels. As endocrine disruption due to exposure to estrogenic compounds may cause fertility reduction, alterations in the sex ratio, and a decrease in reproductive rate, a condition of potential risk for bivalve populations in estuarine areas is highlighted. 相似文献
92.
The steep, south facing slopes of the central Vinschgau (Val Venosta, South Tyrol, northern Italy) are characterized by deep-seated compound rockslides affecting 51 km2 and reaching beneath the Quaternary valley fill. Morphological features include double ridges, trenches, scarps, and counterscarps, whereby the extent of displacement rises from W to E. Near the toe of these slopes, abundant fractures are present whose orientation and spatial strongly suggest that they are related to the gravitational slope deformations. These fractures host carbonate speleothems which are associated with local tufa occurrences at the surface. Given that the metamorphic host rock is essentially carbonate-free, these carbonate deposits require extensive water-rock interactions to form. Modern springs along the toe of the slope are also mostly supersaturated with respect to calcite and locally also aragonite. The invariant chemical composition, very low tritium levels, and in particular the low oxygen isotope values indicate that this groundwater infiltrates at high elevation and is characterized by a long residence time. On the other hand, local infiltration in the lower reaches of the slope is very limited due to the semiarid climate and is incompatible with the measured groundwater stable isotope composition and the high degree of mineralization. We therefore propose a conceptual model which reconciles the deep-seated gravitational slope deformation with the occurrence of mineralized groundwater and associated carbonate precipitates in fractures near the toe of the slope. These deposits provide a means to place constraints on the timing of rock fracturing and hence the slope movements. U/Th dating of 34 samples from eight sites shows that speleothem deposition started 14.2 ka BP and occurred semi-continuously throughout the Holocene. Thus, gravitational displacements likely commenced with a lag of ~3–4 ka after the deglaciation of the valley, which is also consistent with the few available dates on the onset of other deep-seated slope deformations in the Alps. 相似文献
93.
Pietro Marescotti Cristina Carbone Paola Comodi Francesco Frondini Gabriella Lucchetti 《Applied Geochemistry》2012
The mineralogical and chemical evolution of ochreous precipitates forming from acid mine drainage (AMD) from the abandoned Libiola Fe–Cu-sulfide mine (Eastern Liguria, Italy) was followed through a multianalytical approach (XRD, TEM, XRF, ICP) applied to surface precipitates and associated waters collected from several mine adits. The mineralogy of the precipitates changed significantly as a consequence of the variations of the chemical parameters of the circulating solutions (mainly pH, Eh, and sulfate concentrations) which, in turn, were mainly controlled by mixing with unpolluted stream and rill waters of the mining area. A progressive transition from jarosite-, to schwertmannite-, to goethite-, to ferrihydrite-, to amorphous-dominated precipitates was observed, mainly as a consequence of an increase in the pH of the associated solutions. This mineralogical evolution agrees well with the aqueous speciation and Eh–pH stability calculations performed on the waters associated with the different precipitate types. Furthermore, TEM analysis indicated that metastable pristine phases (schwertmannite) tend to transform progressively to well-crystallized more stable species, here represented by goethite. The comparison of the water chemistry and the crystal chemistry of the different precipitates showed a significant decrease in the Zn, Cu, Ni, Co contents in waters where the coexisting precipitates were almost exclusively composed of goethite. The distribution of V, Sr, As concentrations within the different precipitates showed that the most efficient scavenging phase for these elements was jarosite, whereas ferrihydrite efficiently took up Pb ions, and schwermannite acted as a natural sink for Cr. 相似文献
94.
The main objective of the Effects of Climate Change On the Inland waterway Networks (ECCONET) EU FP7 project was to assess the effect of climate change on the inland waterway transport network with special emphasis on the Rhine and Upper Danube catchments. The assessment was based on consolidation and analysis of earlier and existing research work as well as application of existing climate change and hydrological modelling tools. A key premise at the planning stage of the project had been that all impact studies conducted within ECCONET should be comparable with each other. This can be guaranteed by the common meteorological and hydrological basis. The climate model simulations, which are the most physics- and process-oriented tools for projecting the future climate evolution, include several uncertainties. In addition, uncertainties exist in the hydrological model simulations. In ECCONET, an effort was made to quantify the uncertainty range by using “representative projections” that represent both the lower and upper signals of hydrological low-flow parameters for 2021–2050 over the Rhine catchment. Their evaluation indicated that the finally chosen two regional climate model simulations could be applied also for the Upper Danube catchments as representative projections. The raw climate model outputs have been corrected to the observation data set through application of the linear scaling and the delta-change method. The first impact studies carried out after validation of the hydrological models resulted in discharge scenarios used as input to the economic models in ECCONET. 相似文献
95.
M. Gabriella Carboni Luisa Bergamin Daniela Esu Emanuela Pisegna Cerone Vladimiro Verrubbi 《Quaternary Research》2010,74(2):265-128
Foraminifera and molluscs from the 90 m deep ENEA borehole (Versilian plain, central Italy) were studied for paleoenvironmental purposes. Palaeontological analyses, integrated with U/Th and radiocarbon data, helped to recognize late Quaternary sea-level changes and supplied results on tectonic mobility of the area. The study highlighted four sedimentary phases. The first phase consists of a shore environment attributed to MIS 7.1. A hiatus corresponding to MIS 6 is hypothesized at the top of this interval. Recognition of the paleo-shoreline of MIS 7.1 at − 72.8 m signifies a vertical displacement due to the extensional tectonics of the Apennine orogenesis. The second phase consists of a transgressive succession with evidence of warm temperatures, which was interpreted as part of the transgression leading to the MIS 5.5 highstand. The third phase includes sub-aerial and lacustrine deposits. Radiocarbon dates and palaeoecological reconstruction led us to attribute this interval to MIS 4, MIS 3 and MIS 2. The fourth phase begins with a lagoon environment attributable to Holocene sea-level rise and ends with marsh episodes, signifying the progradation of the alluvial plain. This reconstruction confirms the hypothesis of tectonic stability for the Versilian area during the Holocene. 相似文献
96.
Evolution of river planforms downstream of dams: Effect of dam construction or earlier human‐induced changes?
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Marcin Słowik József Dezső Adam Marciniak Gabriella Tóth János Kovács 《地球表面变化过程与地形》2018,43(10):2045-2063
When studying the evolution of landscape, it is difficult to discriminate the influence of anthropogenic from natural causes, or recognise changes caused by different sources of human action. This is especially challenging when the influence of certain sources is overprinted. For instance, although dam closure is the most common method of altering river courses, dam construction is often preceded by hydro‐technical works such as channel straightening, embankment construction or sediment mining. Both dam construction and the hydro‐technical works that precede dam closure can result in changes in the balance between sediment supply and transport capacity, and often, changes in river planform. The main objective of this study was to verify whether the works preceding dam closure are an important driver of river planform changes on the lower Drava River (Hungary). The case study is based on geological and geophysical surveys, as well as the analysis of historical maps covering an anabranching, 23 km long valley section. We show that channel straightening conducted prior to dam closure resulted in a transition from a meandering to sinuous planform with channel bars. Dam construction itself then caused enhanced incision, exposure of bar surfaces, vegetation encroachment and the formation of an anabranching planform. Based on this study, we developed models of alluvial island and channel planform evolution downstream of dams. Dam construction enhances channel incision, narrowing, and the reduction of flow caused by earlier hydro‐technical works. Many rivers downstream of dams experience episodes of anabranching or wandering, with a multi‐thread pattern replacing sinuous, braided and meandering courses. When incision continues, river patterns evolve from anabranching to sinuous via the attachment of alluvial islands to floodplains. However, the timing and sequence of these changes depend on hydrological and sediment supply regimes, geomorphic settings and anthropogenic actions accompanying dam construction. Copyright © 2018 John Wiley & Sons, Ltd. 相似文献