A MEG study of the olivine and spinel forms of Mg2SiO4     

Mark D. Jackson  Roy G. Gordon 《Physics and Chemistry of Minerals》1988,15(6):514-520

In this paper we present a theoretical investigation of the structures and relative stability of the olivine and spinel phases of Mg₂SiO₄. We use both a purely ionic model, based on the Modified Electron Gas (MEG) model of intermolecular forces, and a bond polarization model, developed for low pressure silica phases, to investigate the role of covalency in these compounds. The standard MEG ionic model gives adequate structural results for the two phases but incorrectly predicts the spinel phase to be more stable at zero pressure. This is mainly because the ionic modeling of Mg₂SiO₄ only accounts for 95 percent of the lattice energy. The remainder can be attributed to covalency and many-body effects. An extension of the MEG ionic model using “many-body” pair potentials corrects the phase stability error, but predicts structures which are in poorer agreement with experiment than the standard ionic approach. In addition, calculations using these many-body pair potentials can only account for 10 percent of the missing lattice energy. This model predicts an olivine-spinel phase transition of 8 GPa, below the experimental value of 20 GPa. Therefore, in order to understand more fully the stability of these structures we must consider polarization. A two-shell bond polarization model enhances the stability of both structures, with the olivine structure being stabilized more. This model predicts a phase transition at about 80 GPa, well above the observed value. Also, the olivine and spinel structures calculated with this approach are in poorer agreement with experiment than the ionic model. Therefore, based on our investigations, to properly model covalency in Mg₂SiO₄, a treatment more sophisticated than the two-shell model is needed.  相似文献   

Crystal-chemical examination of natural diopsides: Some geometrical indications of Si-Ti tetrahedral substitution     

Susanna Carbonin  Gabriella Salviulol  Rosalba Munno  Mirella Desiderio  A. Dal Negro 《Mineralogy and Petrology》1989,41(1):1-10

Summary The crystal structures of 20 natural diopsides have been refined. For some samples, microprobe analyses show a Si deficiency in the tetrahedron with no A1 present; this suggests that some Ti⁴⁺ may enter the tetrahedral site. Geometrical variations in these samples with respect to the others are discussed in the light of this Si Ti⁴⁺ substitution. The volumes of their M1 sites are larger because of the absence of R³⁺ cations, the octahedron being very regular; in the same way, the volumes of M2 sites of these samples are greater not because of different site occupancies but because of significant charge modifications around the O3 and O1 oxygens, caused by the tetrahedral site. The low distortion of M1 site and the lengthening of (M2-O1) and M2-O3 bond lengths are a clue to the presence of small amounts of Ti at the tetrahedral site.

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Kristallchemische untersuchung natürlicher diopside: Geometrische hinweise für tetraedrische Si-Ti substitution

Zusammenfassung Die Kristallstrukturen von zwanzig natürlichen Diopsiden sind verfeinert worden. In einigen Proben zeigen Mikrosondenanalysen zu geringe Si-Werte im Tetraeder ohne daß A1 anwesend wäre. Dies weist darauf hin, daß Ti⁴⁺ Tetraederplätze einnehmen könnte. Geometrische Variationen in diesen Proben werden im Lichte der genannten Substitution diskutiert. Die Volumen von M1-Plätzen sind größer wegen der Abwesenheit von R³⁺ Kationen, wobei das Oktaeder sehr gleichmäßig ist. Die Volumina von M2-Plätzen sind noch größer nicht wegen verschiedener Besetzungen dieser Plätze sondern wegen signifikanter Ladungsmodifikationen im Bereich von O3 und O1 Sauerstoffen, die durch die tetraedrische Position bewirkt wird. Die geringe Distortion der M1-Plätze und die Verlängerung der (M2-O1) und (M2-O3) Abstände weisen auf die Anwesenheit von geringen Titangehalten auf Tetraederplätzen hin.

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Active tectonics,R. E. Wallance (panel chairman), National Academy Press,Washington, D.C., 1986. No of pages: 266. Price: £28.70     

J. A. Jackson 《地震工程与结构动力学》1988,16(1):154-154

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Focal mechanisms of large earthquakes in the South Island of New Zealand: implications for the accommodation of Pacific-Australia plate motion     

Helen Anderson  Terry Webb  James Jackson 《Geophysical Journal International》1993,115(3):1032-1054

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Reply to the 'Comment On Two Recent Teleseismic Waveform Inversion Articles By Taymaz Et Al.' By R. Westaway     

James Jackson  Dan Mckenzie 《Geophysical Journal International》1993,112(3):543-543

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Andesite and dacite genesis via contrasting processes: the geology and geochemistry of El Valle Volcano,Panama   总被引：3，自引：0，他引：3  

Mare J. Defant  Lee F. Clark  Robert H. Stewart  Mark S. Drummond  Jelle Z. de Boer  René C. Maury  Hervé Bellon  Thomas E. Jackson  Juan F. Restrepo 《Contributions to Mineralogy and Petrology》1991,106(3):309-324

The easternmost stratovolcano along the Central American arc is El Valle volcano, Panama. Several andesitic and dacitic lava flows, which range in age 5–10 Ma, are termed the old group. After a long period of quiescence (approximately 3.4 Ma), volcanic activity resumed approximately 1.55 Ma with the emplacement of dacitic domes and the deposition of dacitic pyroclastic flows 0.9–0.2 Ma. These are referred to as the young group. All of the samples analyzed are calc-alkaline andesites and dacites. The mineralogy of the two groups is distinct; two pyroxenes occur in the old-group rocks but are commonly absent in the young group. In contrast, amphibole has been found only in the young-group samples. Several disequilibrium features have been observed in the minerals (e.g., oscillatory zoning within clinopyroxenes). These disequilibrium textures appear to be more prevalent among the old- as compared with the young-group samples and are most likely the result of magma-mixing, assimilation, and/or polybaric crystallization. Mass-balance fractionation models for major and trace elements were successful in relating samples from the old group but failed to show a relationship among the young-group rocks or between the old- and young-group volcanics. We believe that the old-group volcanics were derived through differentiation processes from basaltic magmas generated within the mantlewedge. The young group, however, does not appear to be related to more primitive magmas by differentiation. The young-group samples cannot be related by fractionation including realistic amounts of amphibole. Distinctive geochemical features of the young group, including La/Yb ratios〉15, Yb〈1, Sr/Y〉150, and Y〈6, suggest that these rocks were derived from the partial melting of the subducted lithosphere. These characteristics can be explained by the partial melting of a source with residual garnet and amphibole. Dacitic material with the geochemical characteristics of subducted-lithosphere melting is generated apparently only where relatively hot crust is subducted, based on recent work. The young dacite-genesis at El Valle volcano is related to the subduction of relatively hot lithosphere.  相似文献   

Some geophysical constraints on the chemical composition of the earth's lower mantle     

Ian Jackson 《Earth and Planetary Science Letters》1983,62(1):91-103

The physical properties(?, K, K′) of the adiabatically decompressed lower mantle are interpreted in terms of an (Mg,Fe)SiO₃ perovskite + magnesiowüstite mineralogy. The approach employed in this paper involves the removal of the relatively better characterised magnesiowüstite component from the two-phase mixture in order to highlight the physical properties required of the perovskite phase for consistency between the seismological data and any proposed compositional model. It is concluded that a wide tradeoff (emphasized by Davies [1]) between composition, temperature and the physical properties (especially thermal expansion) of the perovskite phase accommodates most recently proposed compositional models including Ringwood's [2] pyrolite and the more silicic models of Burdick and Anderson [3], Anderson [4], Sawamoto [5], Butler and Anderson [6], Liu [7,8] and Watt and Ahrens [9].  相似文献   

Oceanic magnetic anomaly amplitudes: variation with sea-floor spreading rate and possible implications     

H.R. Jackson  I. Reid 《Earth and Planetary Science Letters》1983,63(3):368-378

A qualitative examination of oceanic magnetic anomalies suggests that their amplitudes increase with the spreading rate of the ocean floor. This suggestion has been investigated quantitatively by inversion of the anomalies. A variance matching technique has been used to calculate the average magnetisation of the crust with crustal thickness held constant or to calculate the thickness with the magnetisation fixed. In spite of variations in the computed intensities of magnetisation and thickness when compared to spreading rates the results show an over-all increase in the intensities with the rate of spreading. The mechanisms responsible for this could include greater irregularity in distribution of magnetic polarities within the crust at slow spreading ridges, greater intensity of magnetisation in crust produced at fast spreading due to initial chemical properties or enhanced hydrothermal alteration, and a dependence of crustal thickness on spreading rate.  相似文献   

Effect of a kelp forest on coastal currents   总被引：1，自引：0，他引：1  

George A. Jackson  Clinton D. Winant 《Continental Shelf Research》1983,2(1):75-80

Ocean currents supply a kelp ecosystem with nutrients, planktonic food, and larvae. We have found that these currents in a kelp forest (Macrocystis pyrifera) are slower than currents outside. At the Pt. Loma, San Diego, California, site that we studied, current velocities were about a third of those outside. A comparison of frequency spectra shows that semi-diurnal frequencies are preferentially passed by the kelp. This effect of a kelp forest on the currents that nurture it is similar to that of a terrestrial forest on local winds.  相似文献   

The seismicity of Kohistan, Pakistan: Source studies of the Hamran (1972.9.3), Darel (1981.9.12) and Patan (1974.12.28) earthquakes     

James Jackson  Graham Yielding 《Tectonophysics》1983,91(1-2)

Long period body waves are examined to show that the Hamran (1972.9.3), Darel (1981.9.12) and Patan (1974.12.28) earthquakes in Kohistan had focal depths of about 8–10 km. All involved high angle reverse faulting (thrusting) and had seismic moments of about 2.2 to 2.7·10²⁵ dyne cm. These shallow depths contrast with the deeper hypocentres found in the Hindu Kush and northeast Karakoram to the north and in Hazara to the south. The Hamran and Patan shocks were assigned depths of 45 km by the ISC, indicating that even well-recorded events in this region may have focal depths in error by 30 km  相似文献