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11.
Remote sensing techniques using Landsat ETM+ applied to the detection of iron ore deposits in Western Africa 总被引：1，自引：0，他引：1
Andrea Ciampalini Francesca Garfagnoli Benedetta Antonielli Sandro Moretti Gaia Righini 《Arabian Journal of Geosciences》2013,6(11):4529-4546
Remote sensing methods enable the rapid and inexpensive mapping of surface geological and mineralogical features. This capability proves highly useful when working on isolated or inaccessible areas. In this study, several enhancements of Landsat Enhanced Thematic Mapper plus (i.e. band ratios, false colour composites and principal component analysis) were used and evaluated to obtain the best possible visualisation of iron deposits hosted in the Devonian sedimentary rocks of northwestern Africa. In particular, two test sites were chosen: southern Algeria (Djebilet area), where the literature mineralogical and geological data on iron mine fields were already available, and the Western Sahara (the southern flank of Tindouf Basin), which was investigated during a field campaign and was where the occurrence of an analogous sedimentary succession led us to hypothesise the possible presence of exploitable iron deposits. This work demonstrates the usefulness of multispectral imagery in the detection of iron-rich areas and establishes a full remote sensing procedure, which can be profitably applied to a wider region of Western Sahara and can provide interesting perspectives on the possibility of detecting new exploitable iron ore deposits in arid environments. 相似文献
12.
A Generalized Structure-Activity Relationship for the Decomposition of (Substituted) Alkoxy Radicals
A novel and readily applicable Structure-Activity Relationship (SAR) for predicting the barrier height Eb to decomposition by C-C scission of (substituted) alkoxy radicals is presented. Alkoxy radicals are pivotal intermediates in the atmospheric oxidation of (biogenic) volatile organic compounds, and their fate is therefore of crucial importance to the understanding of atmospheric VOC degradation mechanisms. The SAR is based on available theoretical energy barriers and validated against barriers derived from experimental data. The SAR is expressed solely in terms of the number(s) Ni of alkyl-, hydroxy- and/or oxo-substituents on the - and -carbons of the breaking bond: Eb(kcal/mol) =17.5 – 2.1 × N(alk) – 3.1 ×N(alk) – 8.0 × N,(OH) – 8.0 × N(O=) – 12 × N(O=). For barriers below 7 kcal/mol, an additional, second-order term accounts for the curvature. The SAR reproduces the available experimental and theoretical data within 0.5 to 1 kcal/mol. The SAR generally allows conclusive predictions as to the fate of alkoxy radicals; several examples concerning oxy radicals from prominent atmospheric VOC are presented. Specific limitations of the SAR are also discussed. Using the predicted barrier height Eb, the high-pressure rate coefficient for alkoxy decomposition k
diss
(298 K) can be obtained from k
diss
(298 K) = L ×1.8 × 1013 exp(–Eb/RT) s–1, with L the reaction path degeneracy. 相似文献
13.
Gaia Fantechi Niels R. Jensen Ole Saastad Jens Hjorth Jozef Peeters 《Journal of Atmospheric Chemistry》1998,31(3):247-267
The reactions of isoprene, MBO (2-methyl-3-buten-2-ol) and toluene with chlorine atoms have been studied at 298 ± 5 K and 740 ± 5 Torr with the use of FTIR spectroscopy. Major products of the isoprene-Cl reaction and of the MBO-Cl reaction have been identified and quantified, and reaction mechanisms have been tentatively proposed in order to explain the products formed. The reaction between isoprene and Cl atoms yields mainly HCl, formyl chloride, formic acid, methylglyoxal (pyruvic aldehyde), CO and CO2, while the MBO-Cl reaction forms acetone, HCl, formyl chloride, formic acid, CO, CO2. As products from the reaction between toluene and Cl we identified and quantified HCl and benzaldehyde. The rate constants for the reactions of isoprene and toluene with Cl atoms have also been determined using a relative rate method. The measured values are: kisoprene = (5.5 ± 1.0) × 10–10 cm3 molecule–1 s–1 and ktoluene = (5.6 ± 1.3) × 10–11 cm3 molecule–1 s–1. Atmospheric lifetimes have been estimated from these values. 相似文献
14.
The Roman Villa on the Marina di Equa (Vico Equense, Sorrento Peninsula, Italy), built in the first century A.D., is an important coastal site where the geological effects of the A.D. 79 eruption of Vesuvius are combined with archaeological remains, thus representing an interaction of both human and natural events. At this site, a patrician Roman villa, located at the outlet of a steep V‐shaped valley on the northern flank of a ridge in the Lattari Mountains, was completely destroyed by the A.D. 79 eruption and by subsequent mud/debris flows and floods. During these catastrophic events, the villa was rebuilt twice, in the second and third centuries A.D., as shown by archaeological evidence on the beach. A marine geophysical survey was conducted to study the unexplored portion of this archaeological site. A geographical information system (GIS) analysis of integrated geophysical survey data has identified and mapped (in two and three dimensions) the major underwater archaeological structures on and below the seabed in the villa harbor. A map of the ancient port of the Roman villa has been created by correlating the submerged remains with the construction phases of the villa. 相似文献
15.
An integrated approach for investigating geomorphic response to extreme events: methodological framework and application to the October 2011 flood in the Magra River catchment,Italy 
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下载免费PDF全文 Massimo Rinaldi William Amponsah Marco Benvenuti Marco Borga Francesco Comiti Ana Lucía Lorenzo Marchi Laura Nardi Margherita Righini Nicola Surian 《地球表面变化过程与地形》2016,41(6):835-846
A high‐magnitude flash flood, which took place on 25 October 2011 in the Magra River catchment (1717 km2), central‐northern Italy, is used to illustrate some aspects of the geomorphic response to the flood. An overall methodological framework is described for using interlinked observations and analyses of the geomorphic impacts of an extreme event. The following methods and analyses were carried out: (i) hydrological and hydraulic analysis of the event; (ii) sediment delivery by event landslide mapping; (iii) identification and estimation of wood recruitment, deposition, and budgeting; (iv) interpretation of morphological processes by analysing fluvial deposits; (v) remote sensing and geographic information system (GIS) analysis of channel width changes. In response to the high‐magnitude hydrological event, a large number of landslides occurred, consisting of earth flows, soil slips, and translational slides, and a large quantity of wood was recruited, in most part deriving from floodplain erosion caused by bank retreat and channel widening. The most important impact of the flood event within the valley floor was an impressive widening of the overall channel bed and the reactivation of wide portions of the pre‐event floodplain. Along the investigated (unconfined or partly confined) streams (total investigated length of 93.5 km), the channel width after the flood was up to about 20 times the channel width before the event. The study has shown that a synergic use of different methods and types of evidence provides fundamental information for characterizing and understanding the geomorphic effects of intense flood events. The prediction of geomorphic response to a flood event is still challenging and many limitations exist; however a robust geomorphological analysis can contribute to the identification of the most critical reaches. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
16.
M. Di Martino S. Montebugnoli S. Ostro S. Righini S. Poppi A. Orlati C. Bortolotti Y. Gavrik 《Planetary and Space Science》2004,52(4):325-330
We describe the first intercontinental planetary radar initiative undertaken in Italy.We present the results of the observations of Near-Earth Asteroid (NEA) 33342 (1998 WT24), performed in December 2001 using the bistatic configurations Goldstone-Medicina and Evpatoria-Medicina, with the 32-m Medicina dish used to receive echoes in both cases.The experiment goal was to characterise the system for radar follow-up observations of NEA and artificial orbiting debris, in the framework of a feasibility study which aims at using the Sardinia Radio Telescope, at present under construction, also as a planetary radar facility. 相似文献