Geochemistry, mineralogy and genesis of pyrophyllite deposits in the Pötürge Region (Malatya, Eastern Turkey)     

F. Öner  A. Taş 《Geochemistry International》2013,51(2):140-154

In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.  相似文献   

Mobility and Transport of Nd Isotopes in the Vadose Zone During Weathering of Granitic Till in a Boreal Forest     

Björn Öhlander  Magnus Land  Johan Ingri  Anders Widerlund 《Aquatic Geochemistry》2014,20(1):1-17

There is a broad correlation between the ε_Nd values for rivers (including both the water and the particulate material it carries) and the age of the source terrain. This paper presents Nd isotope distribution data for soil, soil water, groundwater, and stream water samples gathered in a small catchment in northern Sweden. The results show that the release of Nd and Sm from boreal forests into streams and, eventually, into the oceans is more complicated than previously realized. The weathering of till causes changes in both the Nd isotopic composition and Sm/Nd ratios. Both the Sm/Nd ratio and ε_Nd were higher in strongly weathered soils horizons than in less weathered till, since minerals with high Sm/Nd ratios were, on average, more resistant to weathering than those with low Sm/Nd ratios. In contrast to the situation for the main minerals and the major elements, the weathering of rare earth elements (REE) was not restricted to the E-horizon: the measured REE concentrations continued to increase with depth in the C-horizon. In addition, REE released by weathering in the upper parts of the soil profile were partly secondarily retained at deeper levels. Therefore, the dissolved Nd released by weathering in the upper soil horizons was trapped and did not enter the groundwater directly. Rather, the Nd in the groundwater largely originated from weathering within the groundwater zone. However, this was not the only source of Nd in the stream water. The Nd isotope composition and Sm/Nd ratio were determined by the mixing between of Nd and Sm in the groundwater and REE-carrying organic material washed out of the soil profile. The groundwater close to the stream reaches the upper soil horizons during high discharge events such as snowmelts, and organic matter carrying Nd and Sm is washed out of the soils and thus released into the stream. Therefore, the Nd exported from catchment is derived from both the weathering within the groundwater zone, and the organic matter washed out from the soil. If longer timescales with more advanced weathering stages in the groundwater zone are considered, it cannot be ruled out that there will be a shift towards more radiogenic values in the exported Nd. Recorded shifts in the Nd isotopic composition in the ocean may thus not only reflect changed source regions, but also the weathering history of the same source region.  相似文献   

Degradation of digested sewage sludge residue under anaerobic conditions for mine tailings remediation     

Yu Jia  Peter Nason  Lena Alakangas  Christian Maurice  Björn Öhlander 《Environmental Earth Sciences》2014,72(9):3643-3654

Previous studies showed that 85 % of total organic matter (TOM) in digested sewage sludge (biosolids) used as a sealing layer material over sulfide tailings at the Kristineberg Mine, northern Sweden, had been degraded 8 years after application, resulting in a TOM reduction from 78 to 14 %. To achieve a better understanding of the field observations, laboratory studies were performed to evaluate biodegradation rates of the TOM under anaerobic conditions. Results reveal that the original biosolid consisted of ca. 60 % TOM (48.0 % lignin and 11.8 % carbohydrates) that had not been fully degraded. The incubation experiments proved that 27.8 % TOM in the biosolid was further degraded anaerobically at 20–22 °C during the 230 days’ incubation period, and that a plateau to the biodegradation rate was approached. Based on model results, the degradation constant was found to be 0.0125 (day^?1). The calculated theoretical gas formation potential was ca. 50 % higher than the modeled results based on the average degradation rate. Cumulated H₂S equated to 0.65 μmoL g^?1 of biosolid at 230 days. However, the large sulfurous compounds reservoir (1.76 g SO₄ ^2? kg^?1 biosolid) together with anaerobic conditions can generate high concentrations of this gas over a long-term perspective. Due to the rate of biodegradability identified via anaerobic processes, the function of the biosolid to serve as an effective barrier to inhibit oxygen migration to underlying tailings, may decrease over time. However, a lack of readily degradable organic fractions in the biosolid and a large fraction of organic matter that was recalcitrant to degradation suggest a longer degradation duration, which would prolong the biosolid material’s function and integrity.  相似文献   

Plan‐form evolution of ancient meandering rivers reconstructed from longitudinal outcrop sections     

Massimiliano Ghinassi  Wojciech Nemec  Mauro Aldinucci  Slavomir Nehyba  Volkan Özaksoy  Francesco Fidolini 《Sedimentology》2014,61(4):952-977

The mode of channel‐bend transformation (i.e. expansion, translation, rotation or a combination thereof) has a direct bearing on the dimensions, shape, bedding architecture and connectivity of point‐bar sandstone bodies within a fluvial meander belt, but is generally difficult to recognize in vertical outcrops. This study demonstrates how the bend transformation mode and relative rate of channel‐floor aggradation can be deciphered from longitudinal outcrop sections aligned parallel to the meander‐belt axis, as a crucial methodological aid to the reconstruction of ancient fluvial systems and the development of outcrop analogue models for fluvial petroleum reservoirs. The study focuses on single‐storey and multi‐storey fluvial meander‐belt sandstone bodies in the Palaeogene piggyback Boyabat Basin of north‐central Turkey. The sandstone bodies are several hundred metres wide, 5 to 40 m thick and encased in muddy floodplain deposits. The individual channel‐belt storeys are 5 to 9 m thick and their transverse sections show lateral‐accretion bed packages representing point bars. Point bars in longitudinal sections are recognizable as broad mounds whose parts with downstream‐inclined, subhorizontal and upstream‐inclined bedding represent, respectively, the bar downstream, central and upstream parts. The inter‐bar channel thalweg is recognizable as the transition zone between adjacent point‐bar bedsets with opposing dip directions into or out of the outcrop section. The diverging or converging adjacent thalweg trajectories, or a trajectory migrating in up‐valley direction, indicate point‐bar broadening and hence channel‐bend expansion. A concurrent down‐valley migration of adjacent trajectories indicates channel‐bend translation. Bend rotation is recognizable from the replacement of a depositional riffle by an erosional pool zone or vice versa along the thalweg trajectory. The steepness of the thalweg trajectory reflects the relative rate of channel‐floor aggradation. This study discusses further how the late‐stage foreland tectonics, with its alternating pulses of uplift and subsidence and a progressive narrowing of the basin, has forced aggradation of fluvial channels and caused vertical stacking of meander belts.  相似文献   

ISRM Suggested Method for Determining the Abrasivity of Rock by the CERCHAR Abrasivity Test     

Michael Alber  Olgay Yaralı  Filip Dahl  Amund Bruland  Heiko Käsling  Theodore N. Michalakopoulos  Marilena Cardu  Paul Hagan  Hamit Aydın  Ahmet Özarslan 《Rock Mechanics and Rock Engineering》2014,47(1):261-266

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The Inference of Geo-Mechanical Properties of Soft Rocks and their Degradation from Needle Penetration Tests   总被引：2，自引：1，他引：1  

Ömer Aydan  Akira Sato  Masatoshi Yagi 《Rock Mechanics and Rock Engineering》2014,47(5):1867-1890

Needle penetration tests (NPTs) are used for inferring the uniaxial compressive strength of soft rocks, particularly in tunneling through squeezing rocks and foundations on weathered rocks in Japan. The device measures the applied load and the penetration depth of its needle. The ratio of applied load to penetration depth was originally called the needle penetration index (NPI). In this study, this device has been used to infer the geo-mechanical properties of soft rocks from Japan, Turkey, Indonesia, and Egypt. Various equations are presented to infer the geo-mechanical properties in terms of the NPI and compared with the experimental results. The possibility of evaluating the anisotropy of geo-mechanical properties is shown. Furthermore, the characterization of geo-mechanical properties of fault/fracture and slip (shear) surfaces is explained. Some additional equations are given to consider the degradation of geo-mechanical properties as a function of water content, weathering state, and number of cycles of freezing–thawing. Furthermore, the possibility of evaluating the time-dependency characteristics of soft rocks by needle penetration testing is discussed through experiments. It is shown that the effects of water content, weathering state, and number of cycles of freezing–thawing and time-dependency can be evaluated using the NPT technique.  相似文献   

New lessons for technology policy and climate change: investment for innovation     

JONATHAN KÖHLER  TERRY BARKER  HAORAN PAN  PAOLO AGNOLUCCI  PAUL EKINS  TIM FOXON 《Climate Policy》2013,13(2):156-161

The direction of UK energy policy requires a renewed impetus if the goal of climate change stabilization is to be met. Cost is not the main issue: a transformation to a low-carbon energy system may be no more expensive than meeting future energy demands with fossil fuels. Institutional barriers are preventing the large-scale adoption of the necessary technologies. New institutions to promote low-carbon technologies have not yet led to investment on the necessary scale. Further changes to the operation of the UK electricity markets to create a ‘level playing field’ for small-scale and intermittent generation are necessary. UK policy can contribute to international agreements following on from the Kyoto Accord, which also need to address the institutional barriers to energy technology development and transfer.  相似文献   

Evaluating the anthropogenic and geologic impacts on water quality of the Eğirdir Lake, Turkey     

Şehnaz Şener  Ayşen Davraz  Remzi Karagüzel 《Environmental Earth Sciences》2013,70(6):2527-2544

E?irdir Lake is the second largest fresh water lake with 482 km² surface area of Turkey. The lake is an indispensable water source for our country and region because of available water capacity and usage aims such as drinking-irrigation water, tourism, and fishing. However, especially contaminants located in the E?irdir Lake catchment affect the lake water quality negatively in times. Therefore, determination of the water quality of the lake has quite importance for region human health and sustainable usage of the lake. The major factors that control the quality of the E?irdir Lake water are agricultural activities in the basin, water–rock interaction, and domestic and industrial wastes. This study investigates the anthropogenic and geologic impact originated from pollution sources and water–rock interaction in the lake watershed basin to the E?irdir Lake water quality. For this purpose, geological, hydrogeological, and hydrological properties of the lake basin with point and nonpoint pollution sources were investigated. To determine the water quality of the lake, 48 water samples were collected especially from locations representing effects of pollutants in May and October 2009. The analysis results were compared with maximum permissible limit values recommended by World Health Organization and Turkish drinking water standards. The contents of all chemical and physical parameters are higher in dry periods than wet period, and water pollution was observed at discharge points of the streams into the lake. Also, pH, turbidity, potassium, chemical oxygen demand, ammonium, aluminum, iron, and lead concentrations were found to be above drinking water standards.  相似文献   

Fluid inclusion and sulfur isotope thermometry of the Inkaya (Simav-Kütahya) Cu-Pb-Zn-(Ag) mineralization, NW TURKEY     

Yeşim Özen  Fetullah Arik 《Central European Journal of Geosciences》2013,5(3):435-449

The Inkaya Cu-Pb-Zn-(Ag) mineralization, located about 20 km west of the Simav (Kütahya-Turkey), is situated in the northern part of the Menderes Massif Metamorphics. The mineralization is located along an E-W trending fault in the Cambrian Simav metamorphics consisting of quartz-muscovite schist, quartz-biotite schist, muscovite schist, biotite schist and the Ar?kayas? formation composed of marbles. Mineralized veins are 30–35 cm in width. The primary mineralization is represented by abundant galena, sphalerite, chalcopyrite, pyrite, fahlore and minor amounts of cerussite, anglesite, digenite, enargite, chalcocite, covellite, bornite, limonite, hematite and goethite with gangue quartz. Fluid inclusion studies on the quartz samples collected from the mineralized veins indicate that the temperature range of the fluids is 235°C to 340°C and the salinities are 0.7 to 4.49 wt. % NaCl equivalent. The wide range of homogenization temperatures indicates that two different fluid generations were trapped in quartz. Sulfur isotope studies of the sulfide minerals showed that all of the δ ³⁴S values are between ?2.1 and 2.6 per mil. These values are a typical range for hydrothermal sulfide minerals that have sulfur derived from a magmatic source. Pyrite-galena and pyrite-chalcopyrite sulfur isotope fractionation is consistent with an approach to isotopic equilibrium, and calculated temperatures are 254.6 and 277.4°C for pyrite-galena and 274.7°C for pyrite-chalcopyrite. The microthermometric data and sulfur isotope thermometry indicate the existence of a hydrothermal fluid that circulated along the fault crossing the Simav metamorphics and Ar?kayas? formation. Fluid inclusion and sulfur isotope thermometry can be used in combination with ore petrographical and geological information to provide site-specific targets for meso-hypothermal metal concentrations.  相似文献   

New insights into the mineralogy and weathering of the Meridiani Planum meteorite,Mars     

Iris FLEISCHER  Christian SCHRÖDER  Göstar KLINGELHÖFER  Jutta ZIPFEL  Richard V. MORRIS  James W. ASHLEY  Ralf GELLERT  Simon WEHRHEIM  Sandro EBERT 《Meteoritics & planetary science》2011,46(1):21-34

Meridiani Planum is the first officially recognized meteorite find on the surface of Mars. It was discovered at and named after the landing site of the Mars Exploration Rover Opportunity. Based on its composition, it was classified as a IAB complex iron meteorite. Mössbauer spectra obtained by Opportunity are dominated by kamacite (α‐Fe‐Ni) and exhibit a small contribution of ferric oxide. Several small features in the spectra have been neglected to date. To shed more light on these features, five iron meteorite specimens were investigated as analogs to Meridiani Planum with a laboratory Mössbauer setup. Measurements were performed on (1) their metallic bulk, (2) troilite (FeS) inclusions, (3) cohenite ((Fe,Ni,Co)₃C) and schreibersite ((Fe,Ni)₃P), and (4) corroded rims. In addition to these room‐temperature measurements, a specimen from the Mundrabilla IAB‐ungrouped meteorite was measured at Mars‐equivalent temperatures. Based on these measurements, the features in Meridiani Planum spectra can be explained with the presence of small amounts of schreibersite and/or cohenite and iron oxides. The iron oxides can be attributed to a previously reported coating on Meridiani Planum. Their presence indicates weathering through the interaction of the meteorite with small amounts of water.  相似文献