Tracing sources and cycling of phosphorus in Peru Margin sediments using oxygen isotopes in authigenic and detrital phosphates   总被引：4，自引：0，他引：4  

Deb P. Jaisi  Ruth E. Blake 《Geochimica et cosmochimica acta》2010,74(11):3199-6261

Many (bio)geochemical processes that bring about changes in sediment chemistry normally begin at the sediment-water interface, continue at depth within the sediment column and may persist throughout the lifetime of sediments. Because of the differential reactivity of sedimentary phosphate phases in response to diagenesis, dissolution/precipitation and biological cycling, the oxygen isotope ratios of phosphate (δ¹⁸O_P) can carry a distinct signature of these processes, as well as inform on the origin of specific P phases. Here, we present results of sequential sediment extraction (SEDEX) analyses combined with δ¹⁸O_P measurements, aimed at characterizing authigenic and detrital phosphate phases in continental margin sediments from three sites (Sites 1227, 1228 and 1229) along the Peru Margin collected during ODP Leg 201. Our results show that the amount of P in different reservoirs varies significantly in the upper 50 m of the sediment column, but with a consistent pattern, for example, detrital P is highest in siliciclastic-rich layers. The δ¹⁸O_P values of authigenic phosphate vary between 20.2‰ and 24.8‰ and can be classified into at least two major groups: authigenic phosphate precipitated at/near the sediment-water interface in equilibrium with paleo-water oxygen isotope ratios (δ¹⁸O_w) and temperature, and phosphate derived from hydrolysis of organic matter (P_org) with subsequent incomplete to complete re-equlibration and precipitated deeper in the sediments column. The δ¹⁸O_P values of detrital phosphate, which vary from 7.7-15.4‰, suggest two possible terrigenous sources and their mixtures in different proportions: phosphate from igneous/metamorphic rocks and phosphate precipitated in source regions in equilibrium with δ¹⁸O_w of meteoric water. More importantly, original isotopic compositions of at least one phase of authigenic phosphates and all detrital phosphates are not altered by diagenesis and other biogeochemical changes within the sediment column. These findings help to understand the origin and provenance of P phases and paleoenvironmental conditions at/near the sediment-water interface, and to infer post-depositional activities within the sediment column.  相似文献   

Detailed analysis of successive pTRMs carried by pyrrhotite in Himalayan metacarbonates: an example from Hidden Valley, Central Nepal     

C. Crouzet  H. Stang  E. Appel  E. Schill  P. Gautam 《Geophysical Journal International》2001,146(3):607-618

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Evaluation of rainfall–runoff model performance under non-stationary hydroclimatic conditions     

Proloy Deb  Anthony S. Kiem 《水文科学杂志》2020,65(10):1667-1684

ABSTRACT

Understanding of rainfall–runoff model performance under non-stationary hydroclimatic conditions is limited. This study compared lumped (IHACRES), semi-distributed (HEC-HMS) and fully-distributed (SWATgrid) hydrological models to determine which most realistically simulates runoff in catchments where non-stationarity in rainfall–runoff relationships exists. The models were calibrated and validated under different hydroclimatic conditions (Average, Wet and Dry) for two heterogeneous catchments in southeast Australia (SEA). SWATgrid realistically simulates runoff in the smaller catchment under most hydroclimatic conditions but fails when the model is calibrated in Dry conditions and validated in Wet. All three models perform poorly in the larger catchment irrespective of hydroclimatic conditions. This highlights the need for more research aimed at improving the ability of hydrological models to realistically incorporate the physical processes causing non-stationarity in rainfall–runoff relationships. Although the study is focussed on SEA, the insights gained are useful for all regions which experience large hydroclimatic variability and multi-year/decadal droughts.  相似文献   

Surface-level moisture transport over the Indian Ocean during southwest monsoon months using NOAA/HIRS data     

C. M. Kishtawal  N. Gautam  S. Jaggi  P. C. Pandey 《Boundary-Layer Meteorology》1994,69(1-2):159-171

Surface-level moisture transport over the Indian Ocean has been computed using NOAA/HIRS data for the years 1980, 1981 and 1984. The global relation between monthly mean surface-level humidity and precipitable water (Liu, 1986) has been applied for the computation of surface-level humidity using monthly mean satellite-derived water vapour. The monthly mean surface wind fields over the Indian ocean provided by Florida State University have been used for the surface-level moisture flux computations. Our analysis indicates net positive surface-level moisture flux divergence over the Arabian Sea and negative moisture flux divergence over the Bay of Bengal. It has also been found that evaporation over the Arabian Sea is a variable quantity and forms a significant part of the net moisture budget over the Arabian Sea. The relative contribution of cross-equatorial flux and evaporation from the Arabian Sea has been studied for all three years.  相似文献   

Remote sensing of dust storms over the indo-gangetic basin     

Hesham El-Askary  Ritesh Gautam  Menas Kafatos 《Journal of the Indian Society of Remote Sensing》2004,32(2):121-124

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Kinematics of large scale asymmetric folds and associated smaller scale brittle — Ductile structures in the proterozoic somnur formation, pranhita — Godavari Valley, South India     

Gautam Ghosh  Dilip Saha 《Journal of Earth System Science》2005,114(2):125-142

The development of structural elements and finite strain data are analysed to constrain kinematics of folds and faults at various scales within a Proterozoic fold-and-thrust belt in Pranhita-Godavari basin, south India. The first order structures in this belt are interpreted as large scale buckle folds above a subsurface decollement emphasizing the importance of detachment folding in thin skinned deformation of a sedimentary prism lying above a gneissic basement. That the folds have developed through fixed-hinge buckling is constrained by the nature of variation of mesoscopic fabric over large folds and finite strain data. Relatively low, irrotational flattening strain (X:Z-3.1-4.8, k<1) are associated with zones of near upright early mesoscopic folds and cleavage, whereas large flattening strain (X:Z-3.9-7.3, k<1) involving noncoaxiality are linked to domains of asymmetric, later inclined folds, faults and intense cleavage on the hanging wall of thrusts on the flanks of large folds. In the latter case, the bulk strain can be factorized to components of pure shear and simple shear with a maximum shearing strain of 3. The present work reiterates the importance of analysis of minor structures in conjunction with strain data to unravel the kinematic history of fold-and-thrust belts developed at shallow crustal level.  相似文献   

Analysis of sinkhole occurrences over abandoned mines using fuzzy reasoning: a case study     

Debasis Deb  Sung O. Choi 《Geotechnical and Geological Engineering》2006,24(5):1243-1258

In Korea most of the old mine workings were worked with room and pillar method or sublevel caving method and today they possess great possibility of surface subsidence especially for shallow depth mines. In most of the cases, mine roadways, rooms and pillars are irregular in shape and information about the local geology is uncertain. For these reasons, it is difficult to standardize the estimating method of subsidence especially sinkhole type over abandoned mine area. This paper describes the application procedure for the fuzzy reasoning techniques to analyze the possibility of sinkhole occurrences over abandoned mines. This technique is implemented in software which can simplify the analysis procedure and present the possibility of sinkhole subsidence without having precise information about local geological/mining conditions. This technique has been applied to forecast sinkhole possibilities at Bonghwa site where a massive sinkhole has already been occurred.  相似文献   

Simulation of Indian summer monsoon: experiments with SSTs     

S. K. Deb  H. C. Upadhyaya  O. P. Sharma  A. Chakraborty 《Meteorology and Atmospheric Physics》2006,94(1-4):43-64

Summary Hindcasts for the Indian summer monsoons (ISMs) of 2002 and 2003 have been produced from an ensemble of numerical simulations performed with a global model by changing SST. Two sets of ensemble simulations have been produced without vegetation: (i) by prescribing the weekly observed SST from ECMWF (European Centre for Medium Range Weather Forecasting) analyses, and (ii) by adding weekly SST anomalies (SSTA) of April to the climatological SST during the simulation period from May to August. For each ensemble, 10 simulations have been realized with different initial conditions that are prepared from ECMWF data with five each from April and May analyses of both the years. The predicted June–July monsoon rainfall over the Indian region shows good agreement with the GPCP (observed) pentad rainfall distribution when 5 member ensemble is taken from May initial conditions. The All-India June–July simulated rainfall time series matches favourably with the observed time series in both the years for the five member ensemble from May initial condition but drifts away from observation with April initial conditions. This underscores the role of initial conditions in the seasonal forecasting. But the model has failed to capture the strong intra-seasonal oscillation in July 2002. Heating over equatorial Indian Ocean for June 2002 in a particular experiment using 29th May 12 GMT as initial conditions shows some intra-seasonal oscillation in July 2002 rainfall, as in observation. Further evaluation of the seasonal simulations from this model is done by calculating the empirical orthogonal functions (EOFs) of the GPCP rainfall over India. The first four EOFs explain more than 80% of the total variance of the observed rainfall. The time series of expansion coefficients (principal components), obtained by projecting on the observed EOFs, provide a better framework for inter-comparing model simulations and their evaluation with observed data. The main finding of this study is that the All-India rainfall from various experiments with prescribed SST is better predicted on seasonal scale as compares to prescribed SST anomalies. This is indicative of a possible useful seasonal forecasts from a GCM at least for the case when monsoon is going to be good. The model responses do not differ much for 2002 and 2003 since the evolution of SST during these years was very similar, hence July rainfall seems to be largely modulated by the other feedbacks on the overall circulation.  相似文献   

4D-variational assimilation over the Bay of Bengal using the Adjoint of a Variable Resolution Global Ocean Model     

S. K. Deb  H. C. Upadhyaya  O. P. Sharma 《Meteorology and Atmospheric Physics》2006,93(3-4):129-145

Summary The adjoint technique has been widely used over the last two decades in applications involving the dynamics of the Atmosphere and Ocean. This present study applies this technique in the assimilation of oceanic parameters such as temperature and net-surface heat flux, in a variable resolution Ocean General Circulation Model (OGCM). The National Center for Environmental Prediction (NCEP) 1999 July–August global data (sea-surface temperature and derived surface heat flux) and vertical temperature profiles collected from ORV Sagar Kanya and INS Sagardhwani during the Bay of Bengal Monsoon Experiment (BOBMEX 1999) are used for assimilation over the Bay of Bengal. The net-surface heat flux and temperature obtained after assimilation show good agreement with their respective seasonal patterns over the whole Indian Ocean, though there are some differences in the numerical values of heat fluxes. The vertical profiles of temperature after assimilation over the Bay of Bengal show strong resemblance with the corresponding ship observations, emphasizing the importance of the adjoint technique in ocean data assimilation.  相似文献   

Significance of rare hydrous alkaline melts in Hawaiian xenoliths     

Gautam Sen  Andrew Macfarlane  N. Srimal 《Contributions to Mineralogy and Petrology》1996,122(4):415-427

 Two types of melt pockets occur in Hawaiian mantle xenoliths: amphibole-bearing (AMP) and spinel-bearing (SMP). AMPs contain amphibole (kaersutite), olivine (Fo₉₂), clinopyroxene (with 7–11% Al₂O₃), vesicles and glass. SMPs contain olivine, clinopyroxene, spinel, glass, and vesicles. The glasses in SMPs (SiO₂=44–45%, 11–12% alkalis, La=90–110 ppm) and AMPs (SiO₂=49–54%, 6–8.5% alkalis, La=8–14 ppm) are distinct in color and composition. Both glasses are generally characterized by LREE-enriched (chondrite-normalized) patterns. Amphibole and clinopyroxene have gently convex upward-to-moderately LREE-enriched patterns. Mineral/glass trace element abundance ratio plots show a strong negative Ti anomaly and a gentle negative Zr anomaly for clinopyroxene/glass; whereas amphibole/glass patterns show a distinctive positive Ti spike. The amphibole/glass trace element ratios are similar to published megacryst/lava values. An earlier study showed that the Hawaiian spinel lherzolites (lithosphere) have largely been metasomatized during post-erosional Honolulu magmatic activity. REE abundances of SMP glasses (melts) overlap the REE abundances calculated for such metasomes. The occurrence of hydrous, alkaline, mafic melt pockets in Hawaiian upper mantle xenoliths implies that (1) such hydrous liquids are generated in the upper mantle, and (2) water plays a role in magmatic activity associated with the Hawaiian plume. Although we are uncertain about the source (plume, lithosphere, or asthenosphere) of this water, we speculate that such melts and other alkalic lavas erupted on Oahu and on the sea-floor over the Hawaiian arch were generated from a broad „wet“ rim of a radially layered Hawaiian plume, whose hot and „dry“ core supplied the shield-forming magmas. Received: 6 February 1995 / Accepted: 28 August 1995  相似文献