Development of a conceptual hydrogeological model for the evaluation of residence times of water in soil and groundwater: the state of Hesse case study, Germany   总被引：1，自引：1，他引：0  

Frank Herrmann  Georg Berthold  Johann-Gerhard Fritsche  Ralf Kunkel  Hans-Jürgen Voigt  Frank Wendland 《Environmental Earth Sciences》2012,67(8):2239-2250

A regional conceptual hydrogeological model has been developed for evaluating residence times of both, percolate water in the unsaturated zone and groundwater in upper aquifers. The model is based on digitally geo-data bases available at the regional level and has been applied for the entire Federal State of Hesse (Germany) with a spatial resolution of 60?×?60?m. Residence times determined for unconsolidated rock areas typically ranged between 10 and 25?years, whereas residence times of <5?years were assessed for consolidated rock areas. With regard to the implementation of the EU Water Framework Directive, the determined residence times may help to assess the time periods between the introduction of well-targeted groundwater protection measures and their impact on groundwater and surface water quality, respectively.  相似文献   

Volcanic arcs as archives of plate tectonic change     

Susanne M. Straub  Georg F. Zellmer 《Gondwana Research》2012,21(2-3):495-516

Processing of the oceanic lithosphere in subduction zones gives rise to arc magmatism, and strong compositional links exist between trench input and arc output. Here we address the question whether these compositional links are sufficiently strong to allow for ‘tracing’ the composition of the sedimentary and igneous oceanic crust through the chemistry of arcs. The tracing approach hinges critically on whether key characteristics of the subducted slab are transmitted to arcs. Results from forward and inverse modeling, verified by observations from modern arc settings, demonstrate that elements Sr, Pb, Nd and Hf that are associated with radiogenic isotopes may preserve chemical characteristics of the subducted slab in arc magmas. The data indicate that the much thicker igneous subducted crust dominates the recycled flux to arcs. The flux from the highly enriched, but thin sediment layer is buffered, and may be even concealed, by the concomitant contributions from igneous crust, and/or subarc mantle, despite the much better visibility of sediment components in trace element and isotope space. Arc Pb and Pb isotopes are the most promising tracers that may capture the isotopic diversity of subducted MORB-type and OIB-type crust with sufficient temporal and spatial resolution. While arc Sr is also strongly controlled by the flux from the subducted crust, arc data may allow for distinguishing among radiogenic Sr recycled from altered oceanic crust or from subducted sediment in moderately radiogenic arcs (⁸⁷Sr/⁸⁶Sr < ~ 0.7045). Co-mingling of Nd and Hf from igneous subducted crust with mantle contributions mostly hinders the isotopic identification of subducted crust through arc chemistry. However, Nd and Hf may provide complementary information about the efficiency of recycling, and recycling via subduction erosion.The tracing approach appears feasible in Cenozoic arcs where much of the original subduction context is preserved. First results from the Izu Bonin and Central American arcs show that plate tectonic events like oceanic plate formation and destruction, subduction of hotspot tracks and the closure of oceanic gateways are recorded in the chemistry of arcs. A comparative evaluation of Cenozoic global arcs may hence significantly complement the information from the modern oceanic basins, help to obtain a more complete image of the oceanic crustal composition and implicate the geochemical processes by which it formed. Possibly, the tracing approach may also be useful in ancient, inactive arcs to obtain information on the composition of oceanic crust subducted in the geological past.  相似文献   

BaMn[CO3]2 – a previously unrecognized double carbonate in low-temperature environments: Structural,spectroscopic, and textural tools for future identification     

Michael E. Böttcher  Herta S. Effenberger  Peer-Lennart Gehlken  Georg H. Grathoff  Burkhard C. Schmidt  Patrizia Geprägs  Rainer Bahlo  Olaf Dellwig  Thomas Leipe  Vera Winde  André Deutschmann  Alexander Stark  David Gallego-Torres  Francisca Martinez-Ruiz 《Chemie der Erde / Geochemistry》2012,72(1):85-89

Following a tentative evidence for the occurrence of low-temperature barium manganese(II) carbonates in brackish sediments of the Baltic Sea, a stoichiometric double carbonate, BaMn[CO₃]₂, was synthesized from aqueous solutions at ambient temperature for the first time. Here we report the results of a multi-method approach, including scanning electron microscopy (SEM–EDX) investigations, the chemical composition, and, in particular, the diagnostic powder X-ray diffraction pattern, as well as diagnostic parts of the FT infrared absorption and Raman spectra for future identification of this new carbonate in low-temperature environments, like brackish sediments.  相似文献   

The Ksar Ghilane 002 shergottite—The 100th registered Martian meteorite fragment     

Jordi Llorca  Julia Roszjar  Julia A. Cartwright  Addi Bischoff  Ulrich Ott  Andreas Pack  Silke Merchel  Georg Rugel  Leticia Fimiani  Peter Ludwig  José V. Casado  David Allepuz 《Meteoritics & planetary science》2013,48(3):493-513

We report on the discovery of a new shergottite from Tunisia, Ksar Ghilane (KG) 002. This single stone, weighing 538 g, is a coarse‐grained basaltic shergottite, mainly composed of maskelynitized plagioclase (approximately 52 vol%) and pyroxene (approximately 37 vol%). It also contains Fe‐rich olivine (approximately 4.5 vol%), large Ca‐phosphates, including both merrillites and Cl‐apatites (approximately 3.4 vol%), minor amounts of silica or SiO₂‐normative K‐rich glass, pyrrhotite, Ti‐magnetite, ilmenite, and accessory baddeleyite. The largest crystals of pyroxene and plagioclase reach sizes of approximately 4 to 5 mm. Pyroxenes (Fs_26–96En_5–50Wo_2–41). They typically range from cores of about Fs₂₉En₄₁Wo₃₀ to rims of about Fs₆₈En₁₄Wo₁₇. Maskelynite is Ab_41–49An_39–58Or_1–7 in composition, but some can be as anorthitic as An₉₃. Olivine (Fa_91–96) occurs mainly within symplectitic intergrowths, in paragenesis with ilmenite, or at neighboring areas of symplectites. KG 002 is heavily shocked (S5) as indicated by mosaic extinction of pyroxenes, maskelynitized plagioclase, the occurrence of localized shock melt glass pockets, and low radiogenic He concentration. Oxygen isotopes confirm that it is a normal member of the SNC suite. KG 002 is slightly depleted in LREE and shows a positive Eu anomaly, providing evidence for complex magma genesis and mantle processes on Mars. Noble gases with a composition thought to be characteristic for Martian interior is a dominant component. Measurements of ¹⁰Be, ²⁶Al, and ⁵³Mn and comparison with Monte Carlo calculations of production rates indicate that KG 002 has been exposed to cosmic rays most likely as a single meteoroid body of 35–65 cm radius. KG 002 strongly resembles Los Angeles and NWA 2800 basaltic shergottites in element composition, petrography, and mineral chemistry, suggesting a possible launch‐pairing. The similar CRE ages of KG 002 and Los Angeles may suggest an ejection event at approximately 3.0 Ma.  相似文献   

New Apparatus and Experimental Setup for Long-Term Swelling Tests on Sulphatic Claystones     

Erich Pimentel  Georg Anagnostou 《Rock Mechanics and Rock Engineering》2013,46(6):1271-1285

An apparatus and experimental setup were developed to carry out a series of extremely slow and long-lasting swelling, creep or chemo-mechanics tests simultaneously. The equipment was designed specifically for investigating the behaviour of sulphatic claystones. The tests will take at least 10–15 years to complete and will provide unprecedented information about the so-called swelling law, i.e. the relationship between swelling strain and swelling stress. The swelling law is very important for designing tunnels in swelling rock. Our knowledge of the swelling law, however, is only sufficiently reliable with respect to claystones without anhydrite (e.g. marls, opalinus clay). The swelling law for sulphatic claystones remains unknown, even in qualitative terms. This is due to the underlying physico-chemical mechanisms, which are fundamentally different from those of purely argillaceous rocks. Another reason is the extremely long duration of the swelling process of clay-sulphate rocks, which makes systematic field or laboratory investigations very difficult. In order to close this knowledge gap, a series of 25 long-term simultaneous swelling tests has been started.  相似文献   

Nonlinear internal waves in ideal rotating basins     

Georg Bauer  Stefan Diebels  Kolumban Hutter 《地球物理与天体物理流体动力学》2013,107(1-4):21-46

Abstract

Starting from Euler's equations of motion a nonlinear model for internal waves in fluids is developed by an appropriate scaling and a vertical integration over two layers of different but constant density. The model allows the barotropic and the first baroclinic mode to be calculated. In addition to the nonlinear advective terms dispersion and Coriolis force due to the Earth's rotation are taken into account. The model equations are solved numerically by an implicit finite difference scheme. In this paper we discuss the results for ideal basins: the effects of nonlinear terms, dispersion and Coriolis force, the mechanism of wind forcing, the evolution of Kelvin waves and the corresponding transport of particles and, finally, wave propagation over variable topography. First applications to Lake Constance are shown, but a detailed analysis is deferred to a second paper [Bauer et al. (1994)].  相似文献   

Neoendemic ground beetles and private tree haplotypes: two independent proxies attest a moderate last glacial maximum summer temperature depression of 3–4 °C for the southern Tibetan Plateau     

Joachim Schmidt  Lars Opgenoorth  Jochen Martens  Georg Miehe 《Quaternary Science Reviews》2011,30(15-16):1918-1925

Previous findings regarding the Last Glacial Maximum LGM summer temperature depression (maxΔT in July) on the Tibetan Plateau varied over a large range (between 0 and 9 °C). Geologic proxies usually provided higher values than palynological data. Because of this wide temperature range, it was hitherto impossible to reconstruct the glacial environment of the Tibetan Plateau. Here, we present for the first time data indicating that local neoendemics of modern species groups are promising proxies for assessing the LGM temperature depression in Tibet. We used biogeographical and phylogenetic data from small, wingless edaphous ground beetles of the genus Trechus, and from private juniper tree haplotypes. The derived values of the maxΔT in July ranged between 3 and 4 °C. Our data support previous findings that were based on palynological data. At the same time, our data are spatially more specific as they are not bound to specific archives. Our study shows that the use of modern endemics enables a detailed mapping of local LGM conditions in High Asia. A prerequisite for this is an extensive biogeographical and phylogenetic exploration of the area and the inclusion of additional endemic taxa and evolutionary lines.  相似文献   

Global,regional and local scale factors determining glaciation extent in Eastern Siberia over the last 140,000 years     

Gerhard Krinner  Bernhard Diekmann  Florence Colleoni  Georg Stauch 《Quaternary Science Reviews》2011,30(7-8):821-831

The aim of this work is to evaluate the effect of variations of greenhouse gas concentrations, orbital parameters, sea-surface conditions, vegetation and dust deposition on the extent of East Siberian mountain glaciations during the late Quaternary. An atmosphere-only general circulation model is used in a series of 16 sensitivity tests at high spatial resolution over the region of interest to systematically evaluate the relative importance of these different forcing parameters. No attempt was made to reproduce in detail the history of late Quaternary mountain glaciations in East Siberia, because, given (a) the temporal and spatial scarcity of available evidence of mountain glaciations in this region and (b) the large uncertainties concerning the boundary conditions to be prescribed in this model, such an exercise must necessarily remain incomplete and partially inconclusive. The results of this study suggest that moisture delivery from the Atlantic is an important factor determining mountain glacier mass balance in Eastern Siberia and is very sensitive to the geometry of the West Eurasian ice sheet. This means that variable moisture blocking by the West Eurasian ice sheet during the Weichselian is the most important single factor explaining the opposite history of glacier and ice sheet extent in West and East Eurasia during the Weichselian. This work confirms earlier results showing that the large 140 kyr BP West Eurasian ice sheet caused regional-scale cooling extending towards Eastern Eurasia. Nevertheless, the simulated response of the regional summer temperature (and thus glacier extent because of the strong dependency of glacier mass balance of summer melt rates) is to a very large extent directly determined by insolation. For the Early Weichselian, this leads to a clear maximum of local glacier extent at 70 kyr BP, which is in line with the variations of top-of-the-atmosphere insolation on orbital time scales, but to some degree at odds with geological evidence which suggests larger glacier extent at 115 and 90 kyr BP than at 70 kyr BP. Through snow feedbacks, the effects of changes in the prescribed vegetation distribution and dust deposition rate are also substantial. In summary, it appears that the broad features of late Quaternary glaciation history in Eastern Eurasia can be understood in terms of known forcings.  相似文献   

Flow dynamics of groundwater and soil water in the former heap Gessenhalde at the uranium mining area of Ronneburg: a stable isotope approach     

Martin Lonschinski  Kay Knöller  Dirk Merten  Georg Büchel 《水文研究》2011,25(6):861-872

Stable isotopes, ²H_water, ¹⁸O_water as well as ¹⁸O_sulphate and ³⁴S_sulphate, were used to study the flow system of shallow groundwater and soil water at the base area of a former leaching heap at the uranium mining area of Ronneburg, Germany. The flow paths and water‐retention times were estimated by comparison of δ²H and δ¹⁸O values in groundwater and soil water to the δ²H and δ¹⁸O signature of precipitation, giving distinctive inputs of summer or winter precipitation. The points of measuring the groundwater were divided into three categories with different flow conditions: rapid flow, stagnant conditions and a transition zone by hierarchical cluster analysis of δ²H and δ¹⁸O values of groundwater. The transit time of groundwater in the rapid flow area is less than 6 months, whereas water in the stagnant zone is stored for at least 1 year. In soil water, a clear response to different input signals is detectable only in the 30‐cm horizon (retention time is about 6 months), whereas at deeper levels a mixing with older water is taking place. The isotopic composition of the dissolved sulphate was used to identify oxidation of sulphides as the source of sulphate. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Modern and early Holocene mollusc fauna of the Ounianga lakes (northern Chad): implications for the palaeohydrology of the central Sahara     

Bert Van Bocxlaer  Dirk Verschuren  Georg Schettler  Stefan Kröpelin 《第四纪科学杂志》2011,26(4):433-447

The fresh and saline lakes of Ounianga Kebir and Serir in northeastern Chad are among the very few permanent aquatic ecosystems currently existing in the hyper‐arid core of the Sahara desert. The confirmed modern fauna of aquatic molluscs at Ounianga comprises three widespread species (Melanoides tuberculata, Biomphalaria pfeifferi and Lymnaea natalensis), of which only the first appears to maintain a thriving population. We recovered seven more species of gastropods, among which one is new to science (Gabbiella ouniangaensis), and one bivalve species from early Holocene outcrops of diatomaceous limestone at Ounianga Serir. All species except one are known to be commonly spread between lake and river systems by birds, and in its entirety this species‐rich fossil mollusc fauna of Ounianga Serir resembles that of other Saharan lake sites known to have been hydrologically isolated during the early Holocene. The impoverished modern mollusc fauna, which lacks even the widespread and opportunistic species Bulinus truncatus, may have become established relatively recently through new colonisation events, following eradication of the early Holocene mollusc fauna during a later episode of high salinity or desiccation. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献