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981.
1 Introduction InChina ,coastalcitiesaremostlyregionaleconomicdevelopmentcenters.Becauseoftheirspecialgeogra phiclocations ,typhoonsandassociatedstormsurgescauseheavylossesoflivesandproperties.In 1 992 Qing daowasfloodedduetothecoincidenceoftheastrono m…  相似文献   
982.
983.
Modern ground water characterization and remediation projects routinely require calibration and inverse analysis of large three-dimensional numerical models of complex hydrogeological systems. Hydrogeologic complexity can be prompted by various aquifer characteristics including complicated spatial hydrostratigraphy and aquifer recharge from infiltration through an unsaturated zone. To keep the numerical models computationally efficient, compromises are frequently made in the model development, particularly, about resolution of the computational grid and numerical representation of the governing flow equation. The compromise is required so that the model can be used in calibration, parameter estimation, performance assessment, and analysis of sensitivity and uncertainty in model predictions. However, grid properties and resolution as well as applied computational schemes can have large effects on forward-model predictions and on inverse parameter estimates. We investigate these effects for a series of one- and two-dimensional synthetic cases representing saturated and variably saturated flow problems. We show that "conformable" grids, despite neglecting terms in the numerical formulation, can lead to accurate solutions of problems with complex hydrostratigraphy. Our analysis also demonstrates that, despite slower computer run times and higher memory requirements for a given problem size, the control volume finite-element method showed an advantage over finite-difference techniques in accuracy of parameter estimation for a given grid resolution for most of the test problems.  相似文献   
984.
We have experimentally investigated the kinetics of melting of an aplitic leucogranite (quartz+sodic plagioclase of ≈Ab90+K-feldspar+traces of biotite) at 690, 740, and 800°C, all at 200 MPa H2O. Leucogranite cylinders, 3.5 mm in diameter and 7 mm in length, were run in the presence of excess H2O using cold-seal pressure vessels for 11–2,925 h. At 690 and 740°C and any experimental time, and 800°C and short run times, silicate glass (melt at run conditions) occurs as interconnected films along most of the mineral boundaries and in fractures, with the predominant volume occurring along quartz/feldspars boundaries and quartz/plagioclase/K-feldspar triple junctions. Glass film thickness is roughly constant throughout a given experimental charge and increases with experimental temperature and run duration. The results indicate that H2O-saturated partial melting of a quartzo-feldspathic protolith will produce an interconnected melt phase even at very low degrees (<5 vol%) of partial melting. Crystal grain boundaries are therefore completely occluded with melt films even at the lowest degrees of partial melting, resulting in a change in the mechanism of mass transport through the rock from advection of aqueous vapor to diffusion through silicate melt. At 690 and 740°C the compositions of glasses are homogeneous and (at both temperatures) close to, but not on, the H2O-saturated 200 MPa haplogranite eutectic; glass compositions do not change with run duration. At 800°C glasses are heterogeneous and plot away from the minimum, although their molar ratios ASI (=mol Al2O3/CaO+Na2O+K2O) and Al/Na are constant throughout the entire charge at any experimental time. Glass compositions within individual 800°C experiments form linear trends in (wt%) normative quartz–albite–orthoclase space. The linear trends are oriented perpendicular to the 200 MPa H2O haplogranite cotectic line, reflecting nearly constant albite/orthoclase ratio versus variable quartz/feldspar ratio, and have endpoints between the 800°C isotherms on the quartz and feldspar liquidus surfaces. With increasing experimental duration the trends migrate from the potassic side of the minimum toward the bulk rock composition located on the sodic side, due to more rapid (and complete) dissolution of K-feldspar relative to plagioclase. The results indicate that partial melting at or slightly above the solidus (690–740°C) is interface reaction-controlled, and produces disequilibrium melts of near-minimum composition that persist metastably for up to at least 3 months. Relict feldspars show no change in composition or texture, and equilibration between melt and feldspars might take from a few to tens of millions of years. Partial melting at temperatures well above the solidus (800°C) produces heterogeneous, disequilibrium liquids whose compositions are determined by the diffusive transport properties of the melt and local equilibrium with neighboring mineral phases. Feldspars recrystallize and change composition rapidly. Partial melting and equilibration between liquids and feldspars might take from a few to tens of years (H2O-saturated conditions) at these temperatures well above the solidus.  相似文献   
985.
Peridotite xenoliths found in Cenozoic alkali basalts of northern Victoria Land, Antarctica, vary from fertile spinel-lherzolite to harzburgite. They often contain glass-bearing pockets formed after primary pyroxenes and spinel. Few samples are composite and consist of depleted spinel lherzolite crosscut by amphibole veins and/or lherzolite in contact with poikilitic wehrlite. Peridotite xenoliths are characterized by negative Al2O3–Mg# and TiO2–Mg# covariations of clino- and orthopyroxenes, low to intermediate HREE concentrations in clinopyroxene, negative Cr–Al trend in spinel, suggesting variable degrees of partial melting. Metasomatic overprint is evidenced by trace element enrichment in clinopyroxene and sporadic increase of Ti–Fetot. Preferential Nb, Zr, Sr enrichments in clinopyroxene associated with high Ti–Fetot contents constrain the metasomatic agent to be an alkaline basic melt. In composite xenoliths, clinopyroxene REE contents increase next to the veins suggesting metasomatic diffusion of incompatible element. Oxygen isotope data indicate disequilibrium conditions among clinopyroxene, olivine and orthopyroxene. The highest δ18O values are observed in minerals of the amphibole-bearing xenolith. The δ18Ocpx correlations with clinopyroxene modal abundance and geochemical parameters (e.g. Mg# and Cr#) suggest a possible influence of partial melting on oxygen isotope composition. Thermobarometric estimates define a geotherm of 80°C/GPa for the refractory lithosphere of NVL, in a pressure range between 1 and 2.5 GPa. Clinopyroxene microlites of melt pockets provide P–T data close to the anhydrous peridotite solidus and confirm that they originated from heating and decompression during transport in the host magma. All these geothermometric data constrain the mantle potential temperature to values of 1250–1350°C, consistent with the occurrence of mantle decompressional melting in a transtensive tectonic regime for the Ross Sea region.  相似文献   
986.
Simulations of eight different regional climate models (RCMs) have been performed for the period September 1997–September 1998, which coincides with the Surface Heat Budget of the Arctic Ocean (SHEBA) project period. Each of the models employed approximately the same domain covering the western Arctic, the same horizontal resolution of 50 km, and the same boundary forcing. The models differ in their vertical resolution as well as in the treatments of dynamics and physical parameterizations. Both the common features and differences of the simulated spatiotemporal patterns of geopotential, temperature, cloud cover, and long-/shortwave downward radiation between the individual model simulations are investigated. With this work, we quantify the scatter among the models and therefore the magnitude of disagreement and unreliability of current Arctic RCM simulations. Even with the relatively constrained experimental design we notice a considerable scatter among the different RCMs. We found the largest across-model scatter in the 2 m temperature over land, in the surface radiation fluxes, and in the cloud cover which implies a reduced confidence level for these variables. An erratum to this article can be found at  相似文献   
987.
Spatially-explicit estimation of aboveground biomass(AGB) plays an important role to generate action policies focused in climate change mitigation,since carbon(C) retained in the biomass is vital for regulating Earth’s temperature.This work estimates AGB using both chlorophyll(red,near infrared) and moisture(middle infrared) based normalized vegetation indices constructed with MCD43A4 MODerate-resolution Imaging Spectroradiometer(MODIS) and MOD44B vegetation continuous fields(VCF) data.The study area is located in San Luis Potosí,Mexico,a region that comprises a part of the upper limit of the intertropical zone.AGB estimations were made using both individual tree data from the National Forest Inventory of Mexico and allometric equations reported in scientific literature.Linear and nonlinear(expo-nential) models were fitted to find their predictive potential when using satellite spectral data as explanatory variables.Highly-significant correlations(p = 0.01) were found between all the explaining variables tested.NDVI62,linked to chlorophyll content and moisture stress,showed the highest correlation.The best model(nonlinear) showed an index of fit(Pseudo-r2) equal to 0.77 and a root mean square error equal to 26.00 Mg/ha using NDVI62 and VCF as explanatory variables.Validation correlation coefficients were similar for both models:lin-ear(r = 0.87**) and nonlinear(r = 0.86**).  相似文献   
988.
Geochemical records of bivalve shells have been increasingly studied in the last decade to obtain information on climate conditions. In this paper we present stable isotope compositions of living and prehistoric shells of freshwater mussels (Unionidae) and their relationships with climate conditions in a shallow lake environment of Lake Balaton, West-Central Hungary. Physical conditions and stable oxygen isotope compositions of lake water samples were monitored where living bivalves were collected. Comparisons between seasonal variations in ambient temperature, water composition and within-shell isotopic variations indicate that the shells of Unio pictorum do reflect local changes at high resolution and thus can be used to study past conditions. Additionally, shells covering the last two decades were gathered at several locations along the lake in order to determine spatial and temporal variations in the shells’ isotopic compositions as a function of weather conditions. As an application, prehistoric shells collected in archaeological excavations were analysed in order to study past environmental variations. Climate variations during the Late Copper Age (5460–4870 cal. yr BP) have been assumed on the basis of geomorphological and archaeozoological observations at the site Balatonkeresztúr-Réti-dűlő (south of Lake Balaton), that suggested increasing humidity as a cause of changes in settlement location and domestic livestock husbandry. Stable carbon and oxygen isotope compositions of prehistoric bivalve shells were analyzed from excavations representing five archaeological subphases (Boleráz subphase, 5460–5310 cal. yr BP; two transitional subphases around 5310 cal. yr BP; Early Classic subphase, 5310–5060 cal. yr BP; Late Classic subphase, 5040–4870 cal. yr BP). The analyses revealed significant negative C and O isotope shifts in the transitional subphases relative to the earlier and later subphases. The isotopic variations indicate that the local climate became relatively wet and possibly cold around 5310 cal. yr BP, then it returned to drier (and likely warmer) conditions during the Classic subphases. This interpretation is in agreement with previous studies on climate changes related to the “5.3 ky event” in the European continental area and the North Atlantic Region, indicating an Atlantic influence in the Carpathian Basin.  相似文献   
989.
Maar lakes in the Auckland Volcanic Field are important high-resolution archives of Holocene environmental change in the Southern Hemisphere mid-latitudes. Stable carbon and nitrogen isotope analyses were applied on bulk organic matter and the green alga Botryococcus from a sediment core from Lake Pupuke (Auckland, North Island, New Zealand) spanning the period since 7,165?cal.?year BP. The origin of organic matter was established using total-organic?Ccarbon-to-nitrogen ratios (TOC/TN) as well as organic carbon (??13COM) and nitrogen (??15N) isotope composition of potential modern sources. This approach demonstrated that the contribution of allochthonous organic matter to the lake sediment was negligible for most of the record. The sedimentary TOC/TN ratios that are higher than Redfield ratio (i.e. >7) are attributed to N-limiting conditions throughout the record. Variations of nitrogen and carbon isotopes during the last 7,165?years are interpreted as changes in the dominant processes in the lake. While epilimnetic primary productivity controlled isotope composition before 6,600?cal.?year BP, microbial processes, especially denitrification and methane oxidation, caused overall shifts of the ??15N and ??13C values since the Mid-Holocene. Comparisons with climate reconstructions from the Northern Island suggest that changes in the wind-induced lake overturn and a shift to more pronounced seasonality were the most likely causes for lake-internal changes since 6,600?cal.?year BP.  相似文献   
990.
A sample of 21 light duty vehicles powered by Otto cycle engines were tested on a chassis dynamometer to measure the exhaust emissions of nitrous oxide (N2O). The tests were performed at the Vehicle Emission Laboratory of CETESB (Environmental Company of the State of Sao Paulo) using the US-FTP-75 (Federal Test Procedure) driving cycle. The sample tested included passenger cars running on three types of fuels used in Brazil: gasohol, ethanol and CNG. The measurement of N2O was made using two methods: Non Dispersive InfraRed (NDIR) analyzer and Fourier Transform InfraRed spectroscopy (FTIR). Measurements of regulated pollutants were also made in order to establish correlations between N2O and NOx. The average N2O emission factors obtained by the NDIR method was 78?±?41?mg.km?1 for vehicles running with gasohol, 73?±?45?mg.km?1 for ethanol vehicles and 171?±?69?mg.km?1 for CNG vehicles. Seventeen results using the FTIR method were also obtained. For gasohol vehicles the results showed a good agreement between the two methods, with an average emission factor of 68?±?41?mg.km?1. The FTIR measurement results of N2O for ethanol and CNG vehicles were much lower than those obtained by the NDIR method. The emission factors were 17?±?10?mg.km?1 and 33?±?17?mg.km?1, respectively, possibly because of the interference of water vapor (present at a higher concentration in the exhaust gases of these vehicles) on measurements by the NDIR method.  相似文献   
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