Variational stabilization of the ionic charge densities in the electron-gas theory of crystals: Applications to MgO and CaO     

George H. Wolf  Mark S. T. Bukowinski 《Physics and Chemistry of Minerals》1988,15(3):209-220

The electron-gas theory of crystals is extended to include the effects of many-body forces that arise from both electrostatic and overlap interactions. These effects are incorporated through a self-consistent spherical relaxation of the ionic charge distributions such that the crystal binding energy is minimized. This variational model is used to compute the elastic constants and equations of state of MgO and CaO, and we compare its results to those derived from earlier electron-gas models. In the variational model, the anion charge distributions are markedly more sensitive to the local crystal environment than they are in the PIB or other electron-gas models. We find that for these oxides the variational model gives the best overall agreement with experiment for lattice constants, equations of state, dissociation energies, and elastic moduli.  相似文献   

Spongy pahoehoe in Hawaii: A study of vesicle-distribution patterns in basalt and their significance     

George P. L. Walker 《Bulletin of Volcanology》1989,51(3):199-209

A well-defined pahoehoe lava type that is very common medially and distally in Hawaii is characterized by a high concentration and fairly uniform distribution of spherical or near-spherical vesicles. Measurements of vesicle sizes and concentrations have been made on ten of these spongy pahoehoe lava flow-units. The vesicles increase in size toward the middle, accompanied by a moderate increase in lava porosity. The close approach to bilateral symmetry on either side of the horizontal median plane and the common occurrence of a median gas blister shows that no significant upward movement of vesicles occurred, suggesting that the lava possessed a yield strength and was more or less static. Olivine phenocrysts when present are, however, concentrated in the lower half of the same flow units, showing that the lava previously lacked a significant yield strength. The vesicles are regarded as early, inherited from the vent, but the size characteristics of the vesicle population are a late-formed feature. Vesicles grew in static lava mostly by coalescence, and it is postulated that coalescence was promoted by the presence of abundant diktytaxitic voids which punctured the walls of contiguous vesicles. Zones in which the vesicle concentration is lower and the vesicles are larger and strongly deformed interrupt the symmetry of some spongy pahoehoe units, and gas blisters higher than the median plane occur in many examples. These zones are interpreted to result from late-stage shearing, and point to a mechanism by which vesicles may be eliminated from a lava.  相似文献   

The surface of labradorite feldspar after acid hydrolysis     

William H. Casey  Henry R. Westrich  Thomas Massis  Jillian F. Banfield  George W. Arnold 《Chemical Geology》1989,78(3-4):205-218

After reaction with a pH < 4, the surface of labradorite is extensively enriched in Si and H, and depleted in Al, Ca and Na relative to an unreacted crystal. However, the amount of hydrogen measured in the reacted surface is less than that predicted on the basis of exchange of hydrogen (or hydronium) ions for cations in the feldspar. By analogy with studies of silicate glass, this low concentration of hydrogen suggests that some silanol groups in the reacted surface repolymerize subsequent to ion-exchange and depolymerization reactions. The net result is a relatively porous, Si-rich leached layer which is amorphous to electron diffraction, and which allows rapid diffusion of unreactive solutes.

Both the surface area of the reacted feldspar and the porosity increase with acid hydrolysis. Modeling of nitrogen sorption onto the surface suggests that the pores have a nominal radius of 20–80 Å or less. This distribution of pore sizes resembles other acid-reacted silicate materials, such as glass, chrysotile and kaolinite. Although the mineral surface clearly becomes more porous during acid hydrolysis, the increase in powder area also does not coincide with an increase in the flux of dissolved Si from the powder. We thus attribute most of this increase in area to spallation of the silica-rich surface from the feldspar upon drying.  相似文献   

Introduction to the Third Richard H. Jahns distinguished Lecture in Engineering Geology     

George A. Kiersch 《Engineering Geology》1993,33(4):255-256

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International study onArtemia. L. Review of the literature onArtemia from salt lakes in the People's Republic of China     

George V. Triantaphyllidis  Bo Zhang  Lixiang Zhu  Patrick Sorgeloos 《International Journal of Salt Lake Research》1994,3(1):93-104

This literature survey covers data on the distribution, genetics and biology ofArtemia from the People's Republic of China (P. R. China) and the use of the brine shrimp in aquaculture and salt production. The vastness of the territory, the unfamiliar geography and the diversity of the habitats, have often lead to ambiguities and contradictions, leaving a gap in our knowledge about the Chinese populations ofArtemia. However, information aboutArtemia from P. R. China has recently become available and this is an attempt to summarize it.International interdisciplinary study onArtemia populations coordinated by the Laboratory of Aquaculture &Artemia Reference Center, University of Ghent, Belgium.  相似文献   

Array analysis of the large-aperture array of the 1988–89 PASSCAL Basin and Range Passive-Source Seismic Experiment     

George E. Randall  Thomas J. Owens 《Geophysical Journal International》1994,116(3):618-636

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Efficient calculation of complete differential seismograms for laterally homogeneous earth models   总被引：5，自引：0，他引：5  

George E. Randall 《Geophysical Journal International》1994,118(1):245-254

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Silver and copper accumulation in two estuarine bivalves,the eastern oyster (Crassostrea virginica) and the hooked mussel (Ischadium recurvum) in the Patuxent River estuary,Maryland     

Gerhardt F. Riedel  George R. Abbe  James G. Sanders 《Estuaries and Coasts》1995,18(3):445-455

In order to assess the source of trace elements and to compare uptake between different bivalve species, oysters and mussels were transplanted to five sites in the upper Patuxent River estuary during 1988. Transplant sites were located above and below the discharge of Chalk Point Steam Electric Station (CPSES)—a historic point source for copper. Organisms were sampled approximately monthly for 1 yr and analyzed for copper and silver. During spring and summer, concentrations of silver and copper increased in oysters at the upstream stations. There was very little change in silver and copper concentrations in the mussels with either time or among stations. Copper concentrations accumulated by oysters approached those found during previous periods when CPSES used Cu?Ni alloy condenser tubes (1966–1987), suggesting that corrosion from the Cu?Ni condenser tubes was only a minor contributor to the copper burdens of oysters in the river nearby. The lack of accumulation by mussels at the same sites suggests that part of the reason for the accumulation by oysters may be a taxonomically specific physiological effect caused by the salinity regime in the upper Patuxent.  相似文献   

Estimation of resolution and covariance for large matrix inversions     

Jie Zhang  George A. McMechan 《Geophysical Journal International》1995,121(2):409-426

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Composite memory variables for viscoelastic synthetic seismograms   总被引：1，自引：0，他引：1  

Tong Xu  George A. McMechan 《Geophysical Journal International》1995,121(2):634-639

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