Precise radiocarbon dating of Late-Glacial cooling in mid-latitude South America     

Irka Hajdas  Georges BonaniPatricio I Moreno  Daniel Ariztegui 《Quaternary Research》2003,59(1):70-78

Variability of atmospheric ¹⁴C content often complicates radiocarbon-based chronologies; however, specific features such as periods of constant ¹⁴C age or steep changes in radiocarbon ages can be useful stratigraphic markers. The Younger Dryas event in the Northern Hemisphere is one of those periods, showing conspicuous ¹⁴C wiggles. Although the origin of those variations is not fully understood, we can make practical use of them and determine: (i) whether the Younger Dryas was global in extent; if so, (ii) were the initial cooling and the final warming synchronous worldwide; and (iii) what are the implications of these similarities/differences? Here we report high-resolution AMS ¹⁴C chronologies from the mid-latitudes of South America that pinpoint a cool episode between 11,400 and 10,200¹⁴C yr B.P. The onset of the final cool episode of the Late Glacial in the southern mid-latitudes, i.e., the Huelmo/Mascardi Cold Reversal, preceded the onset of the Younger Dryas cold event by ∼550 calendar years. Both events ended during a radiocarbon-age plateau at ∼10,200¹⁴C yr B.P. Thus, the Huelmo/Mascardi Cold Reversal encompasses the Younger Dryas, as well as a couple of short-term cool/warm oscillations that immediately preceded its onset in the North Atlantic region.  相似文献   

L'ı̂le de la Dominique, à l'origine des avalanches de débris les plus volumineuses de l'arc des Petites AntillesThe Island of Dominica,site for the generation of the most voluminous debris avalanches in the Lesser Antilles Arc     

Anne Le Friant  Georges Boudon  Jean-Christophe Komorowski  Christine Deplus 《Comptes Rendus Geoscience》2002,334(4):235-243

Results from recent fieldwork and the Aguadomar marine survey in the Lesser Antilles clearly indicate that the volcanic field of southern Dominica has experienced three major edifice collapse events. This led to formation of the most voluminous debris avalanches known in the Caribbean Arc. Submarine hummocky morphology with plurikilometric megablocks is characteristic of debris avalanche deposits. We propose that steep slopes on the western Caribbean side of the island and intense hydrothermal alteration lead to recurrent large-scale edifice collapses. Therefore islands in the Lesser Antilles face a non-negligible risk from generation of tsunamis associated with potential future edifice collapse. To cite this article: A. Le Friant et al., C. R. Geoscience 334 (2002) 235–243.  相似文献   

La biodiversité végétale des gisements d'âge Jurassique supérieur–Crétacé inférieur de Merbah El Asfer (Sud-Tunisien)     

Georges Barale  Mohamed Ouaja 《Cretaceous Research》2002,23(6):707

  相似文献   

Evaluation of TCE and MTBE in situ Biodegradation: Integrating Stable Isotope, Metabolic Intermediate, and Microbial Lines of Evidence     

Jennifer R. McKelvie  Sarah K. Hirschorn  Georges Lacrampe-Couloume  Jon Lindstrom  Joan Braddock  Kevin Finneran  Don Trego  Barbara Sherwood Lollar 《Ground Water Monitoring & Remediation》2007,27(4):63-73

  相似文献   

Suspended sediment and dissolved load budgets of two Amazonian rivers from the Guiana Shield: Maroni River at Langa Tabiki and Oyapock River at Saut Maripa (French Guiana)     

Francis Sondag  Jean Loup Guyot  Jean Sbastien Moquet  Alain Laraque  Georges Adele  Grard Cochonneau  Jean Claude Doudou  Christelle Lagane  Philippe Vauchel 《水文研究》2010,24(11):1433-1445

This study presents the data collected within the framework of an Observatory of Research in Environment on the Amazonian Basin—the ORE HYBAM. It relates to the dissolved and solid loads of the two main rivers of French Guiana, the Maroni and Oyapock rivers, running on the Guiana Shield and draining respectively 64 230 and 24 630 km². The low coefficient of variation of the average annual flows of the two rivers indicates an inter‐annual hydrological stability probably related to the immediate vicinity of the Atlantic Ocean. The sedimentary load is mainly composed of quartz and kaolinite. The total suspended solid (TSS) concentrations are among the world's lowest values; they range from 1 to 130 mg l⁻¹ during the hydrological cycle, with averages of 22 and 12 mg l⁻¹, for the Maroni and Oyapock rivers, respectively. The seasonal variability of these values is significantly higher than that of hydrologic flows, but without simple relationship with the discharge. Water chemical composition of the two rivers indicates a very weak mineralization, very similar to that found in the Amazonian rivers running on the Brazilian and Guianese shields, and in the Congo River and its tributaries in the Central African Shield. Seasonal variations are observed in both basins; they correspond to higher concentrations during low water stage (from October to February) and to more diluted water during the flood, from April to July. A signature enriched in Cl⁻ is present at the Saut Maripa station on the Oyapock River indicating a more marked influence of the trade winds in this basin. The computation of atmospheric contributions to ions budget indicated a weak contribution for Ca²⁺ and Mg²⁺, which originates mainly from water‐rock interactions in both stations, while more than half of Na⁺ is derived from atmospheric inputs. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Effects of waves on the initiation of headland-associated sandbanks     

Nicolas Guillou  Georges Chapalain 《Continental Shelf Research》2011,31(11):1202-1213

Linear sandbanks appear in the lee of coastal headlands where the hydrodynamics are dominated by strong tidal currents and the seabed is characterized by an abundance of sands. They may develop as symmetrical sandbanks on either sides of the headland or as an unique banner bank. The present study numerically investigates the combined effects of waves and tide on the initial development of headland-associated sandbanks. A morphological model based on the coupling of the wave propagation module SWAN (Simulating WAves Nearshore) with the three-dimensional circulation module COHERENS (COupled Hydrodynamical-Ecological model for REgioNal and Shelf seas) is applied to an idealized Gaussian shaped headland for waves conditions varying in heights and directions at the offshore boundary. The coupling considers the effects of the interactions between the wave and current bottom boundary layers, namely the enhanced levels of turbulence near the bottom and the increase of the total bottom shear stress. Waves substantially modify the initial development of sandbanks formed by suspension narrowing their width and reorienting them along the side of the headland. They weakly impact the morphogenesis of sandbanks by bedload favoring on a short-time scale the growth of symmetric circular-shaped features and a central depositional spit prolonging the headland tip. Waves of transverse directions toward the tip of the headland contribute to the initiation by suspension of a well-developed feature in the headland side of low energy limiting the seabed evolution in the exposed area.  相似文献   

Molecular-level modes of As binding to Fe(III) (oxyhydr)oxides precipitated by the anaerobic nitrate-reducing Fe(II)-oxidizing Acidovorax sp. strain BoFeN1     

Claudia Hohmann  Georges Ona-Nguema  Gordon E. Brown Jr.  Andreas Kappler 《Geochimica et cosmochimica acta》2011,75(17):4699-4712

Sorption of contaminants such as arsenic (As) to natural Fe(III) (oxyhydr)oxides is very common and has been demonstrated to occur during abiotic and biotic Fe(II) oxidation. The molecular mechanism of adsorption- and co-precipitation of As has been studied extensively for synthetic Fe(III) (oxyhydr)oxide minerals but is less documented for biogenic ones. In the present study, we used Fe and As K-edge X-ray Absorption Near Edge Structure (XANES), extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Mössbauer spectroscopy, XRD, and TEM in order to investigate the interactions of As(V) and As(III) with biogenic Fe(III) (oxyhydr)oxide minerals formed by the nitrate-reducing Fe(II)-oxidizing bacterium Acidovorax sp. strain BoFeN1. The present results show the As immobilization potential of strain BoFeN1 as well as the influence of As(III) and As(V) on biogenic Fe(III) (oxyhydr)oxide formation. In the absence of As, and at low As loading (As:Fe ≤ 0.008 mol/mol), goethite (Gt) formed exclusively. In contrast, at higher As/Fe ratios (As:Fe = 0.020-0.067), a ferrihydrite (Fh) phase also formed, and its relative amount systematically increased with increasing As:Fe ratio, this effect being stronger for As(V) than for As(III). Therefore, we conclude that the presence of As influences the type of biogenic Fe(III) (oxyhydr)oxide minerals formed during microbial Fe(II) oxidation. Arsenic-K-edge EXAFS analysis of biogenic As-Fe-mineral co-precipitates indicates that both As(V) and As(III) form inner-sphere surface complexes at the surface of the biogenic Fe(III) (oxyhydr)oxides. Differences observed between As-surface complexes in BoFeN1-produced Fe(III) (oxyhydr)oxide samples and in abiotic model compounds suggest that associated organic exopolymers in our biogenic samples may compete with As oxoanions for sorption on Fe(III) (oxyhydr)oxides surfaces. In addition HRTEM-EDXS analysis suggests that As(V) preferentially binds to poorly crystalline phases, such as ferrihydrite, while As(III) did not show any preferential association regarding Fh or Gt.  相似文献   

V oxidation state in Fe–Ti oxides by high-energy resolution fluorescence-detected X-ray absorption spectroscopy     

Amélie Bordage  Etienne Balan  Johan P. R. de Villiers  Robert Cromarty  Amélie Juhin  Claire Carvallo  Georges Calas  P. V. Sunder Raju  Pieter Glatzel 《Physics and Chemistry of Minerals》2011,38(6):449-458

The oxidation state of vanadium in natural and synthetic Fe–Ti oxides is determined using high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS). Eleven natural magnetite-bearing samples from a borehole of the Main Magnetite Layer of the Bushveld Complex (South Africa), five synthetic Fe oxide samples, and three natural hematite-bearing samples from Dharwar supergroup (India) are investigated. V K edge spectra were recorded on the ID26 beamline at the European Synchrotron Radiation Facility (Grenoble, France), and the pre-edge features were used to determine the local environment and oxidation state of vanadium. In the case of the magnetite samples (natural and synthetic), we show that vanadium is incorporated in the octahedral site of the spinel structure under two oxidation states: +III and +IV. The variations of the pre-edge area are interpreted as various proportions in V³⁺ and V⁴⁺ (between 9.5 and 16.3% of V⁴⁺), V³⁺ being the main oxidation state. In particular, the variations of the V⁴⁺/V³⁺ ratio along the profile of the Main Magnetite Layer seem to follow the crystallization sequence of the layer. In the case of the hematite samples from India, the pre-edge features indicate that vanadium is substituted to Fe and mainly incorporated as V⁴⁺ (between 40 and 72% of V⁴⁺). We also demonstrate the potentiality of HERFD-XAS for mineralogical studies, since it can filter out the unwanted fluorescence and give better resolved spectra than conventional XAS.  相似文献   

Significance,mechanisms and environmental implications of microbial biomineralization     

Karim Benzerara  Jennyfer Miot  Guillaume Morin  Georges Ona-Nguema  Feriel Skouri-Panet  Céline Férard 《Comptes Rendus Geoscience》2011,343(2-3):160-167

Microorganisms can mediate the formation of minerals by a process called biomineralization. This process offers an efficient way to sequester inorganic pollutants within relatively stable solid phases. Here we review some of the main mechanisms involved in the mediation of mineral precipitation by microorganisms. This includes supersaturation caused by metabolic activity, the triggering of nucleation by production of more or less specific organic molecules, and the impact of mineral growth. While these processes have been widely studied in the laboratory, assessment of their importance in the environment is more difficult. We illustrate this difficulty using a case study on an As-contaminated acid mine drainage located in the South of France (Carnoulès, Gard). In particular, we explore the potential relationships that might exist between microbial diversity and mineral precipitation. The present review, far from being exhaustive, highlights some recent advances in the field of biomineralogy and provides non-specialists an introduction to some of the main approaches and some questions that remain unanswered.  相似文献   

Deciphering the weathering processes using environmental mineralogy and geochemistry: Towards an integrated model of laterite and podzol genesis in the Upper Amazon Basin     

Emmanuel Fritsch  Etienne Balan  Nadia Régina Do Nascimento  Thierry Allard  Marion Bardy  Guilherme Bueno  Sylvie Derenne  Adolpho José Melfi  Georges Calas 《Comptes Rendus Geoscience》2011,343(2-3):188-198

This article reports major results from collaborative research between France and Brazil on soil and water systems, carried out in the Upper Amazon Basin. It reveals the weathering processes acting in the partly inundated, low elevation plateaus of the Basin, mostly covered by evergreen forest. Our findings are based on geochemical data and mineral spectroscopy that probe the crystal chemistry of Fe and Al in mineral phases (mainly kaolinite, Al- and Fe-(hydr)oxides) of tropical soils (laterites). These techniques reveal crystal alterations in mineral populations of different ages and changes of metal speciation associated with mineral or organic phases. These results provide an integrated model of soil formation and changes (from laterites to podzols) in distinct hydrological compartments of the Amazon landscapes and under altered water regimes.  相似文献