Two tests of real-time ocean wave-height mapping with HF skywave radar     

Maresca  J.  Jr. Georges  T. Carlson  C. Riley  J. 《Oceanic Engineering, IEEE Journal of》1986,11(2):180-186

An estimate of the coverage efficiency of a high-frequency (HF) skywave (ionospheric) radar for mapping ocean wave height and surface wind direction at ranges between 1000 and 3000 km was made for two different but common operational ocean-monitoring applications. In the first test, three days in duration, wind direction and wave height were mapped over the entire coverage area. In the second test, four days in duration, wind direction was mapped over the entire coverage area and wave height was mapped at preselected small regions within the coverage area. On-line quality assessment and real-time ionospheric diagnostics helped select space-time-frequency windows with low ionospheric distortion. Wind direction over the 4 000 000-km²coverage area was mapped every day with the Wide Aperture Research Facility (WARF) skywave radar in about 1 h. For large-area wave-height mapping, 6 h was allowed, and for the coverage of a smaller grid, 3 h was allowed. Within these time windows, high-confidence wave-height measurements were obtained at 59 percent of the locations attempted, using on-line processing for both tests. When postexperiment processing was included, the coverage efficiency increased to 74 percent. Greater efficiencies would be possible operationally with more experience and more sophisticated radars. Eliminating the First day's results from the statistics shows the effects of increased operating experience. Then the overall on-line efficiency increases to 69 percent, and the off-line increases to 82 percent for the six days of the two tests.  相似文献   

Formation and evolution of lateritic profiles in the middle Amazon basin: Insights from radiation-induced defects in kaolinite     

Etienne Balan  Thierry Allard  Madeleine Sélo  François Chabaux  Georges Calas 《Geochimica et cosmochimica acta》2005,69(9):2193-2204

The content of radiation-induced defects (RIDs) in kaolinite samples originating from lateritic soils and continental detritic sediments of the middle Amazon Basin (Brazil) is investigated using electron paramagnetic resonance. The paleodose registered by kaolinites ranges from 80 to 900 kGy. Present-day dose rates of radiation, determined from the whole-rock U and Th content, range between 4000 and 40,000 mGy/ka. In most samples, U and Th concentrations are correlated, suggesting that U has not been remobilized by lateritization. This observation is consistent with the fact that ∼80% of the total U content is incorporated in resistant minerals, such as zircon and Ti oxides. The heterogeneous distribution of U, observed by induced fission tracks mapping, makes it possible to neglect the α-radiation contribution of the U decay chains in the dose-rate calculation. The interpretation of the measured content of RIDs in kaolinite is then performed using the calculated present-day dose rate and assuming equilibrium in the radioactive decay chains. For the sedimentary samples, the amount of RIDs is broadly correlated to the dose rate and provides apparent absolute ages older than 20 Ma. The RID contents in kaolinites from the lateritic soils provide apparent ages ranging from 10 to 6 Ma. The high RID content of these lateritic kaolinites shows that their chemical, isotopic, and crystallographic properties are not representative of present-day weathering conditions. Models assuming the “dynamical equilibrium” of kaolinites with local physical-chemical conditions prevailing in lateritic soils are thus questionable. Alternatively, our findings bring strong support for the use of the isotopic composition of kaolinites to decipher continental paleo-climates.  相似文献   

3D analysis of high ozone production rates observed during the ESCOMPTE campaign   总被引：3，自引：0，他引：3  

Isabelle Coll  Stphanie Pinceloup  Pascal E. Perros  Grard Laverdet  Georges Le Bras 《Atmospheric Research》2005,74(1-4):477-505

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Isotopic constraints on fluid evolution and precipitation mechanisms for the Boléo Cu–Co–Zn district, Mexico     

Andrew G. Conly  Georges Beaudoin  Steven D. Scott 《Mineralium Deposita》2006,41(2):127-151

Stable and radiogenic isotope composition of stratiform Cu–Co–Zn mineralization and associated sedimentary rocks within the Boléo district of the Miocene Santa Rosalía basin, Baja California Sur, constrains the evolution of seawater and hydrothermal fluids and the mechanisms responsible for sulfide and oxide deposition. Stable isotope geochemistry of limestone and evaporite units indicates a strong paleogeographic influence on the chemistry of the water column. Near-shore limestone at the base of the Boléo Formation is characterized by modified marine carbon (δ ¹³C_PDB=−6.0 to +4.4‰) and oxygen (δ ¹⁸O_SMOW=+19.5 to +26.2‰) isotope composition due to the influx of ¹³C- and ¹⁸O-depleted fluvial water. Sulfate sulfur isotope composition (δ ³⁴S_CDT=+17.21 to +22.3‰ and δ ¹⁸O_SMOW=+10.7 to +13.1‰) for basal evaporite and claystone facies are similar to Miocene seawater. Strontium isotopes are less radiogenic than expected for Miocene seawater due to interaction with volcanic rocks. Low S/C ratios, high Mn contents and sedimentological evidence indicate the basin water column was oxidizing. The oxygenated basin restricted sulfide precipitation to within the sedimentary pile by replacement of early diagenetic framboidal pyrite and pore-space filling by Cu–Co–Zn sulfides to produce disseminated sulfides. Quartz–Mn oxide oxygen isotope geothermometry constrains mineralization temperature between 18 and 118°C. Sulfur isotopes indicate the following sources of sulfide: (1) bacterial sulfate reduction within the sedimentary pile produced negative δ ³⁴S values (<−20‰) in framboidal pyrite; and (2) bacterial sulfate reduction at high temperature (80–118°C) within the sedimentary pile during the infiltration of the metal-bearing brines produced Cu–Co–Zn sulfides with negative, but close to 0‰, δ ³⁴S values. Isotope modeling of fluid-rock reaction and fluid mixing indicates: (1) sedimentary and marine carbonates (δ ¹³C=−11.6 to −3.2‰ and δ ¹⁸O=+19.0 to +21.8‰) precipitated from basin seawater/pore water that variably mixed with isotopically depleted meteoric waters; and (2) hydrothermal calcite (δ ¹³C=−7.9 to +4.3‰ and δ ¹⁸O=+22.1 to +25.8‰) formed by dissolution and replacement of authigenic marine calcite by downward-infiltrating metalliferous brine and brine-sediment exchange, that prior to reaction with calcite, had mixed with isotopically depleted pore water. The downward infiltration of metalliferous brine is inferred from lateral and stratigraphic metal distributions and from the concentration of Cu sulfides along the upper contact of pyrite-bearing laminae. The co-existence and textural relationships among framboidal pyrite, base metal sulfides, carbonate and Mn–Fe oxides (including magnetite) within mineralized units are consistent with carbonate replacement and high-temperature bacterial reduction within the sedimentary pile occurring simultaneously below a seawater column under predominantly oxygenated conditions.  相似文献   

Liquefied vs stratified sediment mobilization processes: Insight from the South of the Barbados accretionary prism   总被引：3，自引：1，他引：3  

Eric Deville  Sophie-Hlne Guerlais  Yannick Callec  Roger Griboulard  Pascale Huyghe  Siegfried Lallemant  Alain Mascle  Mark Noble  Julien Schmitz  the collaboration of the Caramba working group 《Tectonophysics》2006,428(1-4):33-47

This paper discusses the nature and origin of subsurface sediment mobilization processes in deep marine clay-rich environments. In the studied area of the southern Barbados accretionary prism, new geophysical acquisitions have emphasized the spectacular widespread development of mud volcanoes that are well-developed along ramp anticlines and along sigmoidal rises with trends that are oblique to the axes of the main folds of the accretionary wedge. On some active mud volcanoes, heat-flow measurements show high positive anomalies related to high fluxes of mud transfer. The mobilized solid fraction expelled by the mud volcanoes does not originate from a unique source bed but from various formations pierced by the mud conduits and is driven by the water phase. The area studied also exhibits trends of structures corresponding to sub-circular massive local uplifts of deformed but well-preserved stratified sediments (turbidites and hemipelagics). No piercing shale diapirs have been encountered in this area. Some of these local uplift structures are complicated by the development of collapses, calderas, and superimposed mud volcanoes. Mud volcanism corresponds fundamentally to fluid displacement (water and gas), whereas massive sedimentary uplift corresponds to large vertical displacements of stratified solid levels but for which the deep cause could be partly the intrusion of mud plugs. Both are dynamic phenomena controlled by the development of overpressure at depth, contributing to sedimentary mobilizations.  相似文献   

Geologic factors controlling groundwater chemistry in the coastal aquifer system of Douala/Cameroon: implication for groundwater system functioning     

Huguette C. Emvoutou  Béatrice Ketchemen Tandia  Suzanne Ngo Boum Nkot  Rodrigue C. S. Ebonji  Yvon B. Nlend  Georges E. Ekodeck  Christine Stumpp  Piotr Maloszewski  Serigne Faye 《Environmental Earth Sciences》2018,77(5):219

Douala city, located in the littoral province of Cameroon, receives abundant rainfall quantities due to its geographical position in the Gulf of Guinea and bears considerable surface water and groundwater resources. Due to socioeconomic development and rapid demographic growth in the city and its consequences of unplanned urbanization and improper sanitation system, these water resources are poorly protected and managed. Streams in the Wouri watershed receive large amounts of wastewater discharge, and hundreds of boreholes have been drilled into the aquifer system without any management plan. A detailed hydrodynamic and hydrogeochemistry study in Douala town and its environs was conducted to get a better insight into the groundwater system functioning in order to provide information for the sustainable management and protection of the groundwater resource. Two field campaigns were carried out with 187 samples collected and analyzed for major ions, stable isotopes (¹⁸O, ²H), and tritium ³H. The results of the sampling have shown that the weathering of silicate minerals is the dominant geochemical process affecting groundwater chemistry in this system. However, acid rainfall in the humid climate has also caused carbonate mineral dissolution, amorphous silica deposition, and ion exchange reactions to occur in aquifers in the region. The various water types identified were categorized into four major clusters C1 to C4, based on the major ion composition and the local hydrogeological conditions. Environmental isotope data reveal that modern-to-submodern waters occur in the phreatic Quaternary/Mio-Pliocene and Oligocene/Upper Eocene aquifers, respectively. These results corroborate with the conceptual model built where modern groundwater types indicated silicate mineral weathering and calcite dissolution (C1 and C2), whereas submodern groundwater mostly showed silica deposition, ion exchange, and, to a lesser extent, carbonate mineral dissolution (C3 and C4). This improved understanding of the aquifer system functioning is essential to provide a reasonable basis for effective control measures and sustainable water management.  相似文献   

Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements     

Philippe Blanc  Hélène Gailhanou  Jacques Rogez  Georges Mikaelian  Hitoshi Kawaji  Fabienne Warmont  Stéphane Gaboreau  Sylvain Grangeon  Jean-Marc Grenèche  Philippe Vieillard  Claire I. Fialips  Eric Giffaut  Eric C. Gaucher  F. Claret 《Physics and Chemistry of Minerals》2014,41(8):603-615

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.  相似文献   

Influence of bioturbation by the polychaete Nereis diversicolor on the structure of bacterial communities in oil contaminated coastal sediments   总被引：1，自引：0，他引：1  

Cuny P  Miralles G  Cornet-Barthaux V  Acquaviva M  Stora G  Grossi V  Gilbert F 《Marine pollution bulletin》2007,54(4):452-459

Patterns of change in the structure of bacterial communities monitored by ribosomal intergenic spacer analysis (RISA) in oil contaminated sediments inhabited or not by the marine polychaete Nereis diversicolor were studied during 45 days under laboratory conditions. Results supported by principal component analysis showed a marked response of the bacterial communities to the oil contamination and to the presence of N. diversicolor. Phylogenetic affiliation of specific RISA bands showed that, in the contaminated sediments, the presence of the marine polychaetes favoured the development of bacteria which may play an active role in natural bioremediation processes of oil polluted environments.  相似文献   

Oxidation modes and thermodynamics of Fe oxyhydroxycarbonate green rust: Dissolution-precipitation versus in situ deprotonation     

Christian Ruby  Mustapha Abdelmoula  Aurélien Renard  Georges Ona-Nguema  Jean-Marie R. Génin 《Geochimica et cosmochimica acta》2010,74(3):953-966

Fe^II-III hydroxycarbonate green rust GR(CO₃²⁻), Fe^II₄ Fe^III₂ (OH)₁₂ CO₃·3H₂O, is oxidized in aqueous solutions with varying reaction kinetics. Rapid oxidation with either H₂O₂ or dissolved oxygen under neutral and alkaline conditions leads to the formation of ferric oxyhydroxycarbonate GR(CO₃²⁻)∗, Fe^III₆ O₁₂ H₈ CO₃·3H₂O, via a solid-state reaction. By decreasing the flow of oxygen bubbled in the solution, goethite α-FeOOH forms by dissolution-precipitation mechanism whereas a mixture of non-stoichiometric magnetite Fe_(3−x)O₄ and goethite is observed for lower oxidation rates. The intermediate Fe^II-III oxyhydroxycarbonate of formula Fe^II_6(1−x) Fe^III_6x O₁₂ H_2(7−3x) CO₃·3H₂O, i.e. GR(x)∗ for which x ? [1/3, 1], is the synthetic compound that is homologous to the fougerite mineral present in hydromorphic gleysol; in situ oxidation accounts for the variation of ferric molar fraction x = [Fe^III]/{[Fe^II]+[Fe^III]} observed in the field as a function of depth and season but limited to the range [1/3, 2/3]. The domain of stability for partially oxidized green rust is observed in the E_h-pH Pourbaix diagrams if thermodynamic properties of GR(x)∗ is compared with those of lepidocrocite, γ-FeOOH, and goethite, α-FeOOH. Electrochemical equilibrium between GR(x)∗ and Fe^II in solution corresponds to E_h-pH conditions close to those measured in the field. Therefore, the reductive dissolution of GR(x)∗ can explain the relatively large concentration of Fe^II measured in aqueous medium of hydromorphic soils containing fougerite.  相似文献   

阿尔金断裂带附近地壳结构的接收函数成像及其地球动力学意义   总被引：2，自引：1，他引：1  

史大年  余钦范  Georges POUPINET  Georges HERQUEL  Gerard WITTLINGER  姜枚 《地质学报》2007,81(1):139-144

利用中法1995年布设在跨过阿尔金断裂剖面上的18个流动三分量地震台站记录到的近5个月的天然地震记录,经筛选得到533个高质量接收函数。通过速度分析和接收函数成像处理,得到了阿尔金断裂附近地壳结构的清晰图像。塔里木盆地的Moho界面非常清楚,近水平地位于~44km深度上。该界面以低缓的角度一直向南延伸到了阿尔金断裂附近的~70km的深度。阿尔金断裂以南柴达木盆地下面的Moho界面也十分清楚,近水平地位于~55km的深度上,在阿尔金断裂附近存在向上挠曲,并抬升到了~45km的深度上。在阿尔金断裂下方,Moho界面存在~15km的错断。塔里木盆地Moho之下还存在另一个震相,我们解释为沉积层多次波与可能来自Hales间断面转换波的复合震相。接收函数成像结果表明阿尔金断裂是一个超壳的岩石圈断裂,具有比较直立的产状和很狭窄的剪切变形带。根据这些结果,我们推测塔里木的下地壳可能要比柴达木的下地壳更硬,柴达木地壳增厚的原因可以部分归结于它有一个相对弱的下地壳,青藏高原隆升没有扩展到塔里木盆地是因为塔里木盆地具有更刚性的下地壳和岩石圈地幔。高原北部地壳变形应该是所谓青藏高原隆升的“硬”变形模式(Tapponnieretal...  相似文献