Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements     

Philippe Blanc  Hélène Gailhanou  Jacques Rogez  Georges Mikaelian  Hitoshi Kawaji  Fabienne Warmont  Stéphane Gaboreau  Sylvain Grangeon  Jean-Marc Grenèche  Philippe Vieillard  Claire I. Fialips  Eric Giffaut  Eric C. Gaucher  F. Claret 《Physics and Chemistry of Minerals》2014,41(8):603-615

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.  相似文献   

Influence of bioturbation by the polychaete Nereis diversicolor on the structure of bacterial communities in oil contaminated coastal sediments   总被引：1，自引：0，他引：1  

Cuny P  Miralles G  Cornet-Barthaux V  Acquaviva M  Stora G  Grossi V  Gilbert F 《Marine pollution bulletin》2007,54(4):452-459

Patterns of change in the structure of bacterial communities monitored by ribosomal intergenic spacer analysis (RISA) in oil contaminated sediments inhabited or not by the marine polychaete Nereis diversicolor were studied during 45 days under laboratory conditions. Results supported by principal component analysis showed a marked response of the bacterial communities to the oil contamination and to the presence of N. diversicolor. Phylogenetic affiliation of specific RISA bands showed that, in the contaminated sediments, the presence of the marine polychaetes favoured the development of bacteria which may play an active role in natural bioremediation processes of oil polluted environments.  相似文献   

Oxidation modes and thermodynamics of Fe oxyhydroxycarbonate green rust: Dissolution-precipitation versus in situ deprotonation     

Christian Ruby  Mustapha Abdelmoula  Aurélien Renard  Georges Ona-Nguema  Jean-Marie R. Génin 《Geochimica et cosmochimica acta》2010,74(3):953-966

Fe^II-III hydroxycarbonate green rust GR(CO₃²⁻), Fe^II₄ Fe^III₂ (OH)₁₂ CO₃·3H₂O, is oxidized in aqueous solutions with varying reaction kinetics. Rapid oxidation with either H₂O₂ or dissolved oxygen under neutral and alkaline conditions leads to the formation of ferric oxyhydroxycarbonate GR(CO₃²⁻)∗, Fe^III₆ O₁₂ H₈ CO₃·3H₂O, via a solid-state reaction. By decreasing the flow of oxygen bubbled in the solution, goethite α-FeOOH forms by dissolution-precipitation mechanism whereas a mixture of non-stoichiometric magnetite Fe_(3−x)O₄ and goethite is observed for lower oxidation rates. The intermediate Fe^II-III oxyhydroxycarbonate of formula Fe^II_6(1−x) Fe^III_6x O₁₂ H_2(7−3x) CO₃·3H₂O, i.e. GR(x)∗ for which x ? [1/3, 1], is the synthetic compound that is homologous to the fougerite mineral present in hydromorphic gleysol; in situ oxidation accounts for the variation of ferric molar fraction x = [Fe^III]/{[Fe^II]+[Fe^III]} observed in the field as a function of depth and season but limited to the range [1/3, 2/3]. The domain of stability for partially oxidized green rust is observed in the E_h-pH Pourbaix diagrams if thermodynamic properties of GR(x)∗ is compared with those of lepidocrocite, γ-FeOOH, and goethite, α-FeOOH. Electrochemical equilibrium between GR(x)∗ and Fe^II in solution corresponds to E_h-pH conditions close to those measured in the field. Therefore, the reductive dissolution of GR(x)∗ can explain the relatively large concentration of Fe^II measured in aqueous medium of hydromorphic soils containing fougerite.  相似文献   

阿尔金断裂带附近地壳结构的接收函数成像及其地球动力学意义   总被引：2，自引：1，他引：1  

史大年  余钦范  Georges POUPINET  Georges HERQUEL  Gerard WITTLINGER  姜枚 《地质学报》2007,81(1):139-144

利用中法1995年布设在跨过阿尔金断裂剖面上的18个流动三分量地震台站记录到的近5个月的天然地震记录,经筛选得到533个高质量接收函数。通过速度分析和接收函数成像处理,得到了阿尔金断裂附近地壳结构的清晰图像。塔里木盆地的Moho界面非常清楚,近水平地位于~44km深度上。该界面以低缓的角度一直向南延伸到了阿尔金断裂附近的~70km的深度。阿尔金断裂以南柴达木盆地下面的Moho界面也十分清楚,近水平地位于~55km的深度上,在阿尔金断裂附近存在向上挠曲,并抬升到了~45km的深度上。在阿尔金断裂下方,Moho界面存在~15km的错断。塔里木盆地Moho之下还存在另一个震相,我们解释为沉积层多次波与可能来自Hales间断面转换波的复合震相。接收函数成像结果表明阿尔金断裂是一个超壳的岩石圈断裂,具有比较直立的产状和很狭窄的剪切变形带。根据这些结果,我们推测塔里木的下地壳可能要比柴达木的下地壳更硬,柴达木地壳增厚的原因可以部分归结于它有一个相对弱的下地壳,青藏高原隆升没有扩展到塔里木盆地是因为塔里木盆地具有更刚性的下地壳和岩石圈地幔。高原北部地壳变形应该是所谓青藏高原隆升的“硬”变形模式(Tapponnieretal...  相似文献