Insights into cation exchange selectivity of a natural clinoptilolite by means of dielectric relaxation spectroscopy     

Gerardo Rodríguez-Fuentes  Sabine Devautour-Vinot  Sekou Diaby  François Henn 《Physics and Chemistry of Minerals》2011,38(8):613-621

Purified natural clinoptilolite from the Tasajeras deposit, Cuba, and some of its metal exchanged forms are studied, at the dehydrated state, by means of dielectric relaxation spectroscopy (DRS) using two different modus operandi: complex impedance spectroscopy and dielectric dynamic thermal analysis. Data analysis yields the determination of the extra-framework cation (EFC) population into the various possible crystallographic sites of the zeolitic framework as well as of the activation energy characterizing the localized hopping mechanism of EFC. First, it is shown that the DRS responses obtained here match well with the previous reported data, which were previously localized EFCs in positions close to M1 and M2 sites when the clinoptilolite is modified to almost homoionic form. From this outcome, it can be concluded that all EFCs are in the same crystallographic situation regarding solvation or, in other terms, that no steric effect can be taken into account to explain cationic selectivity. Second, based on the assumption that the activation energy for EFC hopping is directly connected to the EFC/framework interaction and on simple thermodynamics consideration, we show this interaction does not govern the EFC exchange reaction. So, it is emphasized that EFC/H₂O interaction is the key factor for cation exchange selectivity.  相似文献   

Analysis with C- and X-band satellite SAR data of the Portalet landslide area   总被引：1，自引：0，他引：1  

Gerardo Herrera  Davide Notti  Juan Carlos Garc��a-Davalillo  Oscar Mora  Geraint Cooksley  M��nica S��nchez  Alain Arnaud  Michele Crosetto 《Landslides》2011,8(2):195-206

This paper describes the use of the Stable Point Network technique, a Persistent Scatterer Interferometry SAR technique, for the analysis of the Portalet landslide area (Central Pyrenees, Spain). For this purpose, different SAR datasets acquired by ERS-1, ERS-2, ENVISAT and TerraSAR-X satellites have been analysed. The use of different SAR images acquired by satellite radar sensors operating at different microwave lengths has allowed for a comparative assessment and illustration of the advantages and disadvantages of these satellites for landslide detection and monitoring. In the introduction, differential interferometry and the study area are briefly described. Then the specifics of the SPN processing and the results of the different datasets are described and compared. In Analysis of the results: the Portalet landslide area, the Portalet landslide area is introduced and the radar displacement measurements are analysed with available geo-information data. Additionally, X-band measurements are compared with those gathered by a ground-based SAR for a previous project. Finally, the most relevant conclusions of this work are discussed.  相似文献   

New rurality and the experience of place: the small rural locality of La Niña,Buenos Aires,Argentina     

Pedro S. Urquijo  Gerardo Bocco  Andrew F. Boni-Noguez 《GeoJournal》2018,83(6):1301-1315

This paper presents a cultural geographic approach for understanding local social processes of territorial re-appropriation taking place in response to non-local forces and interests. This approach is applied to the small rural locality of La Niña, in Buenos Aires Province, Argentina. The small village of La Niña is currently in a locally-led process of recovering from a recent depopulation trend caused mainly by the irruption of transnational agribusiness. As economic opportunities have dwindled in the last decades, more recently local inhabitants and new settlers have set forth diverse strategies aimed at mitigating the effects of depopulation on the social structure. We focus our attention on the way the living experience of place is involved in all these strategies. We contend that despite economic and cultural homogenization caused by globalization, the experience of place is a permanent though ever-changing aspect of social life. Our research was based on archival and hemerographic surveys and ethnographic field techniques, encompassing participatory observation, semistructured and in-depth interviews with social and government leaders and local producers as well as field landscape appraisals.  相似文献   

Estimation of the Risk Management Index (RMI) using statistical analysis   总被引：1，自引：1，他引：0  

David A. Novelo-Casanova  Gerardo Suárez 《Natural Hazards》2015,77(3):1501-1514

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The Son Poc rockfall (Mallorca,Spain) on the 6th of March 2013: 3D simulation     

Roberto Sarro  Rosa María Mateos  Inmaculada García-Moreno  Gerardo Herrera  Paola Reichenbach  Luís Laín  Carlos Paredes 《Landslides》2014,11(3):493-503

The Son Poc rockfall took place on the 6th of March 2013 in the municipality of Bunyola, on the southern side of the Tramuntana Range (Mallorca) and after a rainy and cold period on the region. A volume of rock of 4.000 m³ was detached from the cliff crowning the peak falling down by toppling. The impact of the boulder caused its fragmentation, and numerous boulders bounced and rolled downslope with volumes from 1 to 35 m³, following two trajectories: southwest (SW) and southeast (SE). The SE trajectory, with a larger runout (376 m), reached an urban area, where some of the boulders hit the roofs and walls of nearby houses, stopping others in their gardening areas. Fortunately, no fatalities occurred despite of the presence of some people at that moment, but the event caused great concern in a region which lives from and for tourism. The Son Poc rockfall has been simulated using RocPro3D software which uses GIS technology to produce 3D rockfall trajectories lines, estimated velocity and energy of falling blocks, as well as bounce heights, impacts, and stopping points. The results are in agreement with field observations and with a very good accuracy between real and modeled outcomes.  相似文献   

DInSAR analysis of ALOS PALSAR images for the assessment of very slow landslides: the Tena Valley case study   总被引：2，自引：2，他引：0  

Juan Carlos García-Davalillo  Gerardo Herrera  Davide Notti  Tazio Strozzi  Inmaculada Álvarez-Fernández 《Landslides》2014,11(2):225-246

In this work we analyse the performance of advanced land observing satellite (ALOS) phased array type L-band syntetic aperture radar (PALSAR) images for mapping and monitoring of very slow landslides using conventional differential interferometry in the Tena Valley (Central Pyrenees, Spain). These results are compared with those retrieved in previous works where multi-band advanced differential interferometric synthetic aperture radar (DInSAR) analysis was performed for the same area using PSI techniques. The study area is largely underlain by slates (ca. 80 %) where large deep-seated very slow earth flows are dominant. The results reveal that DInSAR analysis is able to measure displacements of landslides with a greater spatial coverage than PSI analysis, but for a lower amount of them (nine against 51). Overall, the combination of the DInSAR and multi-band PSI analysis permitted to map and monitor 68 % of the landslides in Tena Valley. From this amount, 63 landslides are considered as active. The main advantage of DInSAR with respect to PSI analysis is the capability to detect faster movements (up to 145 cm?year^?1) derived from the 46 days interferograms. That is the case of Sextas and La Selva landslides where an acceleration of the moving mass was measured after intense rainfall periods producing major damages to linear infrastructures. The combination of measured displacement from ALOS interferograms, with the observed damages on the A-136 road, was useful to assess the potential damage that could cause these slow movements. In general, it is demonstrated that even though PSI analysis provides a better performance in terms of landslide mapping, L-band DInSAR analysis provides an added value for landslide hazard assessment through radar remote sensing. For this reason it is necessary to encourage the launch of new satellite missions similar to ALOS PALSAR that could operate with shorter revisiting time periods.  相似文献   

Impact of the 2010 tsunami on an endangered insular soil–plant system     

Ingo J. Hahn  Pablo M. Vergara  Julia Baumeister  Gerardo E. Soto  Uwe Römer 《Natural Hazards》2014,71(1):987-993

Natural catastrophes could damage island biodiversity and ecosystems, and their effects could become devastating if combined with human disturbances. In this study, we determined the effects of the tsunami occurred in Robinson Crusoe Island (Chile) on 27 February 2010 on an endangered soil–plant system. Using data of endemic Cabbage Trees (Dendroseris litoralis Skottsb.) and soil attributes taken before and after the 2010 event, we developed thematic maps to assess the changes in population size and soil substrate of Cabbage Trees caused by the tsunami. We determined that from 153 pre-tsunami (2009) standing Cabbage Trees, only 66 (43 %) survived in 2011, mostly in elevations above 25 m a.s.l. Before the tsunami, 86 (56 %) of Cabbage Trees were established in humus-rich soil sites whereas after the tsunami, this number declined to 53 (35 %). These results represent the first report of a severe population decline after a tsunami and indicate that tsunamis are an important source of species extinction in small oceanic islands not only by reducing the population size but also by reducing the quality of sites for plant growth.  相似文献   

Current Topics on Deformation Monitoring and Modelling,Geodynamics and Natural Hazards: Introduction     

Pablo J. González  Gerardo Herrera  Francisco Luzón  Pietro Tizzani 《Pure and Applied Geophysics》2015,172(11):2961-2964

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A User-Oriented Methodology for DInSAR Time Series Analysis and Interpretation: Landslides and Subsidence Case Studies     

Davide Notti  Fabiana Calò  Francesca Cigna  Michele Manunta  Gerardo Herrera  Matteo Berti  Claudia Meisina  Deodato Tapete  Francesco Zucca 《Pure and Applied Geophysics》2015,172(11):3081-3105

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Analytical versus observational fragilities: the case of Pettino (L’Aquila) damage data database   总被引：2，自引：1，他引：1  

Flavia De Luca  Gerardo M. Verderame  Gaetano Manfredi 《Bulletin of Earthquake Engineering》2015,13(4):1161-1181

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