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581.
A very coarse grained graywacke from Strassberg in the Lower Harz Mountains (Germany) consists of rock-fragments, feldspars, quartz, chlorites, micas, accessories and ores. Low grade metamorphic mineral reactions are indicated by the formation of 2M-muscovite +chlorite+sphene+albite in the matrix of the graywacke, by prehnite+chlorite+ sphene+calcite+sericite+albite (±quartz) in volcanic rock-fragments, and by prehnite +calcite+quartz along fine fissures. The newly formed minerals in the coarse grained graywacke belong to the laumontite-prehnite-quartz-facies of the burial metmorphism. However, the formation of the low grade minerals is caused by thermal metamorphism in outer contact zones of the Ramberg granite intrusion in the Strassberg area. 相似文献
582.
583.
Daniel Smrzka Jennifer Zwicker David Misch Christoph Walkner Susanne Gier Patrick Monien Gerhard Bohrmann Jrn Peckmann 《Sedimentology》2019,66(6):2318-2353
Oil seeps from the southern Gulf of Mexico can be regarded as natural laboratories where the effect of crude oil seepage on chemosynthesis‐based communities and carbonate precipitation can be studied. During R/V Meteor cruise 114 the seep sites UNAM (Universidad Nacional Autónoma de México) Ridge, Mictlan Knoll and Tsanyao Yang Knoll (Bay of Campeche, southern Gulf of Mexico) were investigated and sampled for authigenic carbonate deposits containing large amounts of liquid oil and solid asphalt. The δ13C values of individual carbonate phases including: (i) microcrystalline matrix aragonite and calcite; (ii) grey, cryptocrystalline to microcrystalline aragonite; and (iii) clear, fibrous aragonite cement, are between ?30‰ and ?20‰, agreeing with oil as the primary carbon source. Raman spectra reveal that residual heavy oils from all sites are immature and most likely originate from the same reservoir. Geochemical batch modelling using the software code PHREEQC demonstrates how sulphate‐driven oxidation of oil‐derived low‐molecular to high‐molecular weight hydrocarbons affects carbonate saturation state, and shows that the oxidation state of carbon in hydrocarbon compounds and oxidation rates of hydrocarbons control carbonate saturation and precipitation at oil seeps. Phase‐specific trace and rare earth element contents of microcrystalline aragonite and calcite, grey cryptocrystalline aragonite and clear aragonite were determined, revealing enrichment in light rare earth elements for grey aragonite. By comparing trace element patterns of carbonates with those of associated oils, it becomes apparent that liquid hydrocarbons constitute an additional source of trace metals to sedimentary pore waters. This work not only demonstrates that the microbial degradation of oil at seeps may result in the precipitation of carbonate minerals, it also elucidates that trace metal inventories of seep carbonates archive diagnostic elemental patterns, which can be assigned to the presence of heavy hydrocarbons in interstitial pore waters. 相似文献
584.
A three-dimensional two-phase flow model is coupled to a non-linear reactive transport model to study the efficacy of potassium permanganate treatment on dense, non-aqueous phase liquid (DNAPL) source removal in porous media. A linear relationship between the soil permeability (k) and concentration of manganese dioxide precipitate ([MnO2(s)]), k = ko + Srind [MnO2(s)], is utilized to simulate nodal permeability reductions due to precipitate formation. Using published experimental column studies, an Srind = −5.5 × 10−16 m2 L/mg was determined for trichloroethylene (TCE) DNAPL. This Srind was then applied to treatment simulations on three-dimensional TCE DNAPL source zones comprising either DNAPL at residual saturations, or DNAPL at pooled saturations. 相似文献
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586.
E. Churazov W. Forman A. Vikhlinin S. Tremaine O. Gerhard C. Jones 《Monthly notices of the Royal Astronomical Society》2008,388(3):1062-1078
We compare the gravitational potential profiles of the elliptical galaxies NGC 4486 (M87) and NGC 1399 (the central galaxy in the Fornax cluster) derived from X-ray and optical data. This comparison suggests that the combined contribution of cosmic rays, magnetic fields and microturbulence to the pressure is ∼10 per cent of the gas thermal pressure in the cores of NGC 1399 and M87, although the uncertainties in our model assumptions (e.g. spherical symmetry) are sufficiently large that the contribution could be consistent with zero. In the absence of any other form of non-thermal pressure support, these upper bounds translate into upper limits on the magnetic field of ∼10–20 μG at a distance of 1–2 arcmin from the centers of NGC 1399 and M87. We show that these results are consistent with the current paradigm of cool cluster cores, based on the assumption that active galactic nuclei regulate the thermal state of the gas by injecting energy into the intracluster medium. The limit of ∼10–20 per cent on the energy density in the form of relativistic protons applies not only to the current state of the gas, but also essentially to the entire history of the intracluster medium, provided that cosmic ray protons evolve adiabatically and that their spatial diffusion is suppressed. 相似文献
587.
588.
Cadée GC 《Marine pollution bulletin》2002,44(11):1294-1295
80% of floating plastic debris freshly washed ashore on a Dutch coast showed peckmarks made by birds at sea. They either mistake these debris for cuttlebones or simply test all floating objects. Ingestion of plastic is deleterious for marine organisms. It is urgent to set measures to plastic litter production. 相似文献
589.
Gerhard Held 《Pure and Applied Geophysics》1974,112(5):765-776
Summary Hail observations were made in the Transvaal, South Africa, during the decade 1962 to 1972. The hail-reporting network covered an area of 2800 km2 with Pretoria in the northeast and the also densely-populated Witwatersrand in the south. A panel of about 800 voluntary observers contributed 10 560 hail reports during this period. Isopleths of hail frequency within the network were plotted. The pattern was strikingly similar to the isohyetal map. More rain and hail occurred in the urban areas than elsewhere and there was a relationship to topography. Pretoria received less hail than the Witwatersrand, a ridge about 300 m higher than Pretoria. 相似文献
590.
Gerhard?LammelEmail author Thomas?Engelhardt Adrian?Leip Christian?Neusü? Andreas?R?hrl Birgit?Wehner Alfred?Wiedensohler Paul?Wieser 《Journal of Atmospheric Chemistry》2005,51(1):95-117
The change of the chemical composition of the near-ground level atmospheric aerosol was studied during two summer episodes by a Lagrangian type of experimental approach. Bulk and single-particle chemical analyses of ions and elements in the particulate phase were deployed. N(-III) and N(V) components were also measured in the gas-phase. The measurements were completed by particle size distributions.Secondary inorganic aerosols (SIA) and fine particles of ≈0.2–0.4 μm size were still elevated 50 km downwind of the city. The direct comparison of transport over the city in contrast to transport over the surrounding areas showed that SIA was formed from emission from the city within less than 3 h. Relative increases, i.e., enrichment during transport were observed for primary and secondary aerosol components. The degree of mixing on the individual particle level increased significantly during transport in the area. In particular, newly emitted carbonaceous particles became internally mixed within hours with pre-existing sulphate particles. Mostly due to secondary aerosol formation the average particle size (mass median diameter) of major constituents of the aerosol was significantly decreased while being transported over 13 h. Given recent insights which link fine particles number and mass concentrations with health risks, the results suggest that rural populations in areas which frequently are located within an urban plume might run an elevated health risk relative to populations in areas not affected by urban plumes. 相似文献