A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join     

Giancarlo Della Ventura  Günther J. Redhammer  Gianluca Iezzi  Frank C. Hawthorne  Arnaud Papin  Jean-Louis Robert 《Physics and Chemistry of Minerals》2005,32(2):103-113

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.  相似文献   

Coronal abundance of elements and a model of the quiet Sun from radio observations     

Claudio Chiuderi  Franca Chiuderi Drago  Giancarlo Noci 《Solar physics》1972,26(2):343-353

It is shown that the combined use of radio observations of the quiet Sun and UV line intensities allows to compute the absolute coronal abundance of the elements. The abundances found by this method agree very well with the most recent determinations. A model of the transition region and corona in hydrostatic equilibrium is also presented. Similarities and differences with models based on UV observations are discussed.  相似文献   

Elastic–plastic analysis of geotechnical problems by mathematical programming     

Giancarlo Gioda  Osvaldo de Donato 《国际地质力学数值与分析法杂志》1979,3(4):381-401

A numerical technique, based on a mathematical programming algorithm, is presented for the solution of geotechnical problems where elastic-plastic material behaviour is considered. The proposed approach can be adopted for geotechnical media characterized by any suitable yield condition, accounting, if necessary, for workhardening behaviour. The loading process is subdivided into a series of steps applied to a finite element mesh with geometry and material properties constant along each step, but with possible changes between subsequent steps. As an application some typical geotechnical problems are analysed by means of the proposed algorithm and a comparison is made between the available in situ measurements and the numerical results.  相似文献   

A numerical interpretation of load tests on vibro-piles     

Annamaria Cividini  Livio Locatelli  Alessio Contini  Giancarlo Gioda 《Computers and Geotechnics》2011

The finite element interpretation is discussed of two load tests carried out on instrumented vibro-piles in a granular deposit. A first back analysis, aimed at assessing the improvement of the mechanical characteristics of soil induced by the vibratory construction process, highlights an apparent contradiction between the experimental variation of the axial load along the pile and the numerical results. This suggests introducing as a free variable, in addition to the elastic and shear strength parameters of the granular soil, also the increase of the nominal diameter of pile caused by vibrations. The second back analysis provides some insight into the variation of the diameter with depth and leads to an acceptable interpretation, from the engineering standpoint, of the load tests. On these bases a quantitative comparison is presented between the calculated load–settlement diagram of the vibro-pile and that of a “standard” pile constructed without vibrations in the same granular deposit.  相似文献   

A proof of Nekhoroshev's theorem for the stability times in nearly integrable Hamiltonian systems     

Giancarlo Benettin  Luigi Galgani  Antonio Giorgilli 《Celestial Mechanics and Dynamical Astronomy》1985,37(1):1-25

In the present paper we give a proof of Nekhoroshev's theorem, which is concerned with an exponential estimate for the stability times in nearly integrable Hamiltonian systems. At variance with the already published proof, which refers to the case of an unperturbed Hamiltonian having the generic property of steepness, we consider here the particular case of a convex unperturbed Hamiltonian. The corresponding simplification in the proof might be convenient for an introduction to the subject.  相似文献   

On the non-linear ‘squeezing’ effects around circular tunnels     

Giancarlo Gioda 《国际地质力学数值与分析法杂志》1982,6(1):21-46

An analysis is presented of the non-linear creep effects around a deep circular tunnel driven in ‘squeezing’ ground. The time-dependent behaviour of the geotechnical medium is described by means of a simple viscoplastic rheological model capable of approximating primary, secondary and tertiary creep behaviours. It is shown that tertiary creep can be allowed for by providing a suitable law governing the variation of some material parameters (such as viscosity) with stresses and strains. The basic operations of the ‘evolutive’ procedure adopted for time integration are outlined. Along each time integration step, quadratic variations of the stress and strain fields and linear variations of the material parameters are assumed. The results of various finite element analyses are presented concerning both lined and unlined cases. For the lined cases, the influence of the liner stiffness and of the time elapsed between the end of excavation and the liner installation is considered.  相似文献   

A nonlinear programming analysis of unconfined steady-state seepage     

Giancarlo Gioda  Carmelo Gentile 《国际地质力学数值与分析法杂志》1987,11(3):283-305

A finite element, variable mesh analysis of unconfined steady-state seepage problems is presented based on a nonlinear programming algorithm. It is shown that the minimization of an objective function which merely represents a measure of the total flux leaving or entering the mesh at the free surface nodes (except those that belong also to pervious boundaries) does not permit a unique definition of the free surface geometry. This problem, which is apparently related to the numerical instabilities often met when using variable mesh approaches, can be eliminated by adding to the objective function a term representing a sort of overall ‘regularity’ condition for the shape of the free surface. The modified solution procedure turns out to be stable and able to provide meaningful results for practical problems even when rather coarse meshes are adopted.  相似文献   

Flow in coronal loops with a mass source     

Giancarlo Noci  Francesca Zuccarello 《Solar physics》1983,88(1-2):193-209

This research studies the flow of plasma inside a coronal loop in which an injection of plasma through the lateral surface is permitted. The flow is assumed steady and polytropic. The problem covers two cases: (a) upflow at one footpoint, downflow at the other; (b) downflow at both footpoints. The first case can be shown to be quite similar to that of a mass-conserving flow with variable cross section; the second, instead, is characterized by solutions with a different type of topology; its main new feature is the obvious fact that all the solutions pass through a single point going from negative to positive velocities. In this second case the density ratio between footpoints and top can be much smaller than in a mass conserving flow. This can explain some properties of observed loops.  相似文献   

Hillslope-to-valley transition morphology: New opportunities from high resolution DTMs     

Paolo Tarolli  Giancarlo Dalla Fontana 《Geomorphology》2009,113(1-2):47

The search for the optimal spatial scale for observing landforms to understand physical processes is a fundamental issue in geomorphology. Topographic attributes derived from Digital Terrain Models (DTMs) such as slope, curvature and drainage area provide a basis for topographic analyses. The slope–area relationship has been used to distinguish diffusive (hillslope) from linear (valley) processes, and to infer dominant sediment transport processes. In addition, curvature is also useful in distinguishing the dominant landform process. Recent topographic survey techniques such as LiDAR have permitted detailed topographic analysis by providing high-quality DTMs. This study uses LiDAR-derived DTMs with a spatial scale between 1 and 30 m in order to find the optimal scale for observation of dominant landform processes in a headwater basin in the eastern Italian Alps where shallow landsliding and debris flows are dominant. The analysis considered the scaling regimes of local slope versus drainage area, the spatial distribution of curvature, and field observations of channel head locations. The results indicate that: i) hillslope-to-valley transitions in slope–area diagrams become clearer as the DTM grid size decreases due to the better representation of hillslope morphology, and the topographic signature of valley incision by debris flows and landslides is also best displayed with finer DTMs; ii) regarding the channel head distribution in the slope–area diagrams, the scaling regimes of local slope versus drainage area obtained with grid sizes of 1, 3, and 5 m are more consistent with field data; and iii) the use of thresholds of standard deviation of curvature, particularly at the finest grid size, were proven as a useful and objective methodology for recognizing hollows and related channel heads.  相似文献   

Surface heat fluxes and thermohaline variability in the Ross Sea and in Terra Nova Bay polynya     

Giannetta Fusco  Giorgio Budillon  Giancarlo Spezie 《Continental Shelf Research》2009,29(15):1887-1895

The Ross Sea is an important area for the ventilation of the deep layers of the Southern Ocean (e.g. [Jacobs, S.S., Fairbanks, R.G., Horibe, Y., 1985. Origin and evolution of water masses near the Antarctic continental margin: evidence from H218O/H216O ratios in seawater. In: Jacobs, S.S. (Ed.), Oceanology of the Antarctic Continental Shelf. Antarctic Research Series, vol. 43. pp. 59–85; Orsi, A.H., Johnson, G.C., Bullister, J.L., 1999. Circulation, mixing, and the production of Antarctic bottom water. Progress in Oceanography 109, 43–55]). These processes are driven by the atmospheric forcing which, at high latitude, plays a key role in the formation and thickness of sea ice. In order to investigate the effect of the atmospheric forcing variability at different time scales, we analysed the surface heat budget over the Ross Sea continental shelf and in Terra Nova Bay (TNB) polynya, using analyses for the period 1990–2006 provided by European Centre for Medium-range Weather Forecast (ECMWF). This study was also performed using thermohaline data collected within the activities of Climatic Long-term Interaction for the mass-balance in Antarctica project of the Italian National Programme for Antarctic Research for the summer periods from 1994 until 2001.The annual average of the heat budget over the continental shelf of the Ross Sea estimated in the period 1990–2006 shows an interannual variability ranging between −97 and −123 W m⁻². Assuming that the heat loss must be compensated by the sensible heat carried by the Circumpolar Deep Water we estimated its transport (3.1 Sv) and its variability (0.2 Sv). Similarly in the TNB polynya the heat loss reaches its maximum in 2003 (−313 W m⁻²) and its minimum (−58 W m⁻²) in 1996. The related production of sea ice and the High Salinity Shelf Water (HSSW) were also estimated. The HSSW production switched from the lowest values during the first 10 years of the investigated period (1990–2000) to the highest values for the remaining period (2001–2006).The thermohaline characteristics of the water column in TNB show a general decrease in salinity with a superimposed variability. Comparison between the estimated HSSW production and the salinity observed within the TNB water column show similar tendency in the last years after 2002, while during the period 1995–1998 the behaviour is different. Our hypothesis concern a possible role of the CDW inflow in the TNB area and our results could be explained by a different contribution of CDW transport and HSSW production to the salt content within the water column.  相似文献