Asbestos fibre identification vs. evaluation of asbestos hazard in ophiolitic rock mélanges,a case study from the Ligurian Alps (Italy)   总被引：1，自引：1，他引：0  

Gianluca Vignaroli  Paolo Ballirano  Girolamo Belardi  Federico Rossetti 《Environmental Earth Sciences》2014,72(9):3679-3698

In recent years, the high incidence of harmful health effects through inhalation of airborne asbestos from amphibole-bearing rock mélanges has been thoroughly documented. Here, we present a field-based, multi-scale geological approach aimed at illustrating the occurrence of amphibole fibrous mineralisation in an ophiolitic suite from the Ligurian Alps (Italy) and discussing the implication on in situ determination of the asbestos hazard. The rock mélange is composed of plurimetre-sized blocks of different lithotypes (metagabbro, serpentinite, chloritoschist) juxtaposed by the meaning of tectonic structures. The geological-structural survey revealed that the fibrous mineralisation is localised in specific structural sites of the rock volume, including veins and schistosity. Both micro-chemical and crystal structure analyses on selected fibrous samples revealed that actinolite fibres grow in veins within the metagabbro and in chloritoschists, while fibrous tremolite occurs in serpentinite schistosity. The morphological features of these amphibole fibres have been analysed in TEM images and used for classifying them as “asbestiform” or “non-asbestiform”. The results show that the asbestos hazard determination is not unequivocally identified when different procedures for asbestos fibre identification and classification are applied. This may have impact on normatives and regulations in defining environmental hazards due to asbestos occurrence.  相似文献   

Dependence of clinopyroxene composition on cooling rate in basaltic magmas: Implications for thermobarometry     

Silvio Mollo  Pierdomenico Del Gaudio  Guido Ventura  Gianluca Iezzi  Piergiorgio Scarlato 《Lithos》2010,118(3-4):302-312

The compositional variation of clinopyroxene and the partitioning of major elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from 1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H₂O = 1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca, Mg, Fe²⁺ and Si and enriched in Na, Fe³⁺, Al (mainly Al^IV), and Ti. Di and Hd versus CaTs and CaFeTs form a continuous binary solid solution characterized by higher amounts of tschermakitic components with increasing cooling rate. Two parameters (DH = Di + Hd and TE = CaTs + CaFeTs + En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions.Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of ^cpx–meltKd_Fe–Mg remain almost constant. Therefore, the Fe²–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic cooling magmas, giving rise to possible mismatches in the application of thermobarometers. The results of our study are consistent with that observed at the margin of dikes or in the exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.  相似文献   

The dynamics of central Main Ethiopian Rift waters: Evidence from δD, δO and Sr/Sr ratios     

Tewodros Rango  Riccardo Petrini  Barbara Stenni  Gianluca Bianchini  Francesca Slejko  Luigi Beccaluva  Tenalem Ayenew 《Applied Geochemistry》2010,25(12):1860-1871

Water samples from cold and geothermal boreholes, hot springs, lakes and rivers were analyzed for δD, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr compositions in order to investigate lake water–groundwater mixing processes, water–rock interactions, and to evaluate groundwater flow paths in the central Main Ethiopian Rift (MER) of the Ziway–Shala basin. Different ranges of isotopic values were recorded for different water types: hot springs show δ¹⁸O −3.36 to +3.69 and δD −15.85 to +24.23, deep Aluto-Langano geothermal wells show δ¹⁸O −4.65 to −1.24 and δD −12.39 to −9.31, groundwater wells show δ¹⁸O −3.99 to +5.14 and δD −19.69 to +32.27, whereas the lakes show δ¹⁸O and δD in the range +3.98 to +7.92 and +26.19 to +45.71, respectively. The intersection of the Local Meteoric Water Line (LMWL: δD = 7 δ¹⁸O + 11.2, R² = 0.94, n = 42) and the Local Evaporation Line (LEL: δD = 5.63δ¹⁸O + 8, n = 14, R² = 0.82) was used to estimate the average isotopic composition of recharge water into the basin (δD = −5.15 and δ¹⁸O = −2.34). These values are depleted if compared with the modern-day average precipitation, presumably indicating paleo-groundwater components recharged during previous humid climatic phases. The measured stable isotope values indicate that the geothermal wells, some of the hot springs and groundwater wells mainly consist of meteoric water. The Sr isotopic signatures in all waters are within the range of the Sr isotopic composition of the rift basalts and rhyolites. The variability of Sr isotopic data also pinpoints complex water–rock interaction and mixing processes in groundwater and surface water. The ⁸⁷Sr/⁸⁶Sr ratio ranges from 0.70445 to 0.70756 in the hot springs, from 0.70426 to 0.70537 in two deep geothermal wells, and from 0.70673 to 0.70721 in the rift lakes Ziway, Langano, Shala and Awasa. The radiogenic composition recorded by the lakes indicates that the input water was predominantly affected by progressive interaction with rhyolitic volcanics and lacustrine sediments.  相似文献   

Biogenic stalactites in submarine caves at the Cape of Otranto (SE Italy): dating and hypothesis on their formation     

Genuario Belmonte  Gianmarco Ingrosso  Marco Poto  Gianluca Quarta  Marisa D'Elia  Raffaele Onorato  & Lucio Calcagnile 《Marine Ecology》2009,30(3):376-382

Submarine caves at the Cape of Otranto (SE, Italy) host pseudostalactites. Only recently have they been recognised as originating mainly from the marine tube worm Protula tubularia (Serpulidae, Polychaeta). Their formation depends on the adaptability, life history and behaviour of that species in the cave habitat. The dating of calcareous tubes in the pseudostalactite core represents the first attempt to describe the formation of such bio-construction, and the gregarious behaviour of the species. Calcareous tubes along the core axis of three pseudostalactites removed from the cave lu Lampiùne (Otranto, South East Italy) have been dated using the ¹⁴C method. Measures established ages from 2600 to 5000 years for the three structures. This extremely long period (when compared with the life span of each worm) suggests that each tube aggregation is the result of punctuated growth periods alternated with long standstill phases. At the end of a growth period, each tube aggregation was covered with a brownish concretion, completing the pseudostalactite.  相似文献   

Sonification of geophysical data through time–frequency analysis: theory and applications          下载免费PDF全文

Paolo Dell'Aversana  Gianluca Gabbriellini  Alfonso Amendola 《Geophysical Prospecting》2017,65(1):146-157

In this paper, we introduce a new method of geophysical data interpretation based on simultaneous analysis of images and sounds. The final objective is to expand the interpretation workflow through multimodal (visual–audio) perception of the same information. We show how seismic data can be effectively converted into standard formats commonly used in digital music. This conversion of geophysical data into the musical domain can be done by applying appropriate time–frequency transforms. Using real data, we demonstrate that the Stockwell transform provides a very accurate and reliable conversion. Once converted into musical files, geophysical datasets can be played and interpreted by using modern computer music tools, such as sequencers. This approach is complementary and not substitutive of interpretation methods based on imaging. It can be applied not only to seismic data but also to well logs and any type of geophysical time/depth series. To show the practical implications of our integrated visual–audio method of interpretation, we discuss an application to a real seismic dataset in correspondence of an important hydrocarbon discovery.  相似文献