Molecular H₂O in armenite, BaCa₂Al₆Si₉O₃₀·2H₂O, and epididymite, Na₂Be₂Si₆O₁₅·H₂O: Heat capacity, entropy and local-bonding behavior of confined H₂O in microporous silicates     

Charles A. Geiger  Edgar Dachs  Gilberto Artioli 《Geochimica et cosmochimica acta》2010,74(18):5202-5215

Armenite, ideal formula BaCa₂Al₆Si₉O₃₀·2H₂O, and its dehydrated analog BaCa₂Al₆Si₉O₃₀ and epididymite, ideal formula Na₂Be₂Si₆O₁₅·H₂O, and its dehydrated analog Na₂Be₂Si₆O₁₅ were studied by low-temperature relaxation calorimetry between 5 and 300 K to determine the heat capacity, C_p, behavior of their confined H₂O. Differential thermal analysis and thermogravimetry measurements, FTIR spectroscopy, electron microprobe analysis and powder Rietveld refinements were undertaken to characterize the phases and the local environment around the H₂O molecule.The determined structural formula for armenite is Ba_0.88(0.01)Ca_1.99(0.02)Na_0.04(0.01)Al_5.89(0.03)Si_9.12(0.02)O₃₀·2H₂O and for epididymite Na_1.88(0.03)K_0.05(0.004)Na_0.01(0.004)Be_2.02(0.008)Si_6.00(0.01)O₁₅·H₂O. The infrared (IR) spectra give information on the nature of the H₂O molecules in the natural phases via their H₂O stretching and bending vibrations, which in the case of epididymite only could be assigned. The powder X-ray diffraction data show that armenite and its dehydrated analog have similar structures, whereas in the case of epididymite there are structural differences between the natural and dehydrated phases. This is also reflected in the lattice IR mode behavior, as observed for the natural phases and the H₂O-free phases. The standard entropy at 298 K for armenite is S° = 795.7 ± 6.2 J/mol K and its dehydrated analog is S° = 737.0 ± 6.2 J/mol K. For epididymite S° = 425.7 ± 4.1 J/mol K was obtained and its dehydrated analog has S° = 372.5 ± 5.0 J/mol K. The heat capacity and entropy of dehydration at 298 K are Δ = 3.4 J/mol K and ΔS^rxn = 319.1 J/mol K and Δ = −14.3 J/mol K and ΔS^rxn = 135.7 J/mol K for armenite and epididymite, respectively. The H₂O molecules in both phases appear to be ordered. They are held in place via an ion-dipole interaction between the H₂O molecule and a Ca cation in the case of armenite and a Na cation in epididymite and through hydrogen-bonding between the H₂O molecule and oxygen atoms of the respective silicate frameworks. Of the three different H₂O phases ice, liquid water and steam, the C_p behavior of confined H₂O in both armenite and epididymite is most similar to that of ice, but there are differences between the two silicates and from the C_p behavior of ice. Hydrogen-bonding behavior and its relation to the entropy of confined H₂O at 298 K is analyzed for various microporous silicates.The entropy of confined H₂O at 298 K in various silicates increases approximately linearly with increasing average wavenumber of the OH-stretching vibrations. The interpretation is that decreased hydrogen-bonding strength between a H₂O molecule and the silicate framework, as well as weak ion-dipole interactions, results in increased entropy of H₂O. This results in increased amplitudes of external H₂O vibrations, especially translations of the molecule, and they contribute strongly to the entropy of confined H₂O at T < 298 K.  相似文献   

The Cretaceous–Tertiary boundary in southern low-latitude regions: preliminary study in Pernambuco, northeastern Brazil     

Gilberto A. Albertão  Eduardo A.M. Koutsoukos  Marília P.S. Regali  Moses Attrep Jr  Paulo P. Martins Jr 《地学学报》1994,6(4):366-375

A preliminary integrated study of a Cretaceous-Tertiary (K/T) boundary section in Pernambuco, northeastern Brazil, provides evidence for an extraterrestrial bolide impact in the earliest Danian. A non-graded, nodular carbonate mudstone/wackestone bed is interpreted as a slump or a mud Flow deposit, induced by a tsunami event or by a gravity mass movement during a sea-level lowstand, the former possibly generated by the K/T boundary Yucatán impact. This bed overlies marlstones deposited in an upper bathyal environment and marks the top of the Cretaceous. Nearly all known latest Maastrichtian planktonic foraminifera are recovered from the Cretaceous strata. Iridium shows a marked peak in a thin hemipelagic claystone layer, about 75 cm above the K/T boundary, deposited in a middle to deep neritic environment. The claystone overlies alternating beds of finegrained limestones and marlstones and a 50 cm-thick graded bioclastic packstone, which rests upon a marly limestone breccia of the lowermost Danian. Abundant reworked Cretaceous and rare lowermost Danian microfossils (e.g. E. edita, E. eobulloides, E. fringa, G. irregularis, P. eugubina, P. cf. pseudobulloides, W. claytonensis and W. hornerstownensis ) have been recovered from these strata. These lowermost Danian beds record the sudden appearance of abundant shock-metamorphosed quartz grains, with several sets of intersecting deformation lamellae and microtektite-like microspherules. This suggests that these deposits were formed by an additional tsunami caused by a second impact event in the earliest Danian, near or at the boundary between the Palaeocene P α and P 1a foraminiferal zones. Impact-derived material has not been found in the uppermost Cretaceous beds.  相似文献   

A New Sensitivity Analysis and Solution Method for Scintillometer Measurements of Area-Averaged Turbulent Fluxes   总被引：1，自引：1，他引：0  

Matthew Gruber  Gilberto J. Fochesatto 《Boundary-Layer Meteorology》2013,149(1):65-83

Scintillometer measurements of the turbulence inner-scale length $l_\mathrm{o }$ l o and refractive index structure function $C_n^2$ C n 2 allow for the retrieval of large-scale area-averaged turbulent fluxes in the atmospheric surface layer. This retrieval involves the solution of the non-linear set of equations defined by the Monin–Obukhov similarity hypothesis. A new method that uses an analytic solution to the set of equations is presented, which leads to a stable and efficient numerical method of computation that has the potential of eliminating computational error. Mathematical expressions are derived that map out the sensitivity of the turbulent flux measurements to uncertainties in source measurements such as $l_\mathrm{o }$ l o . These sensitivity functions differ from results in the previous literature; the reasons for the differences are explored.  相似文献   

Concentration and subcellular distribution of trace elements in liver of small cetaceans incidentally caught along the Brazilian coast     

Kunito T  Nakamura S  Ikemoto T  Anan Y  Kubota R  Tanabe S  Rosas FC  Fillmann G  Readman JW 《Marine pollution bulletin》2004,49(7-8):574-587

Concentrations of trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, T-Hg, Org-Hg, Tl and Pb) were determined in liver samples of estuarine dolphin (Sotalia guianensis; n = 20), Franciscana dolphin (Pontoporia blainvillei; n = 23), Atlantic spotted dolphin (Stenella frontalis; n = 2), common dolphin (Delphinus capensis; n = 1) and striped dolphin (Stenella coeruleoalba; n = 1) incidentally caught along the coast of Sao Paulo State and Parana State, Brazil, from 1997 to 1999. The hepatic concentrations of trace elements in the Brazilian cetaceans were comparable to the data available in literature on marine mammals from Northern Hemisphere. Concentrations of V, Se, Mo, Cd, T-Hg and Org-Hg increased with increasing age in liver of both estuarine and Franciscana dolphins. Very high concentrations of Cu (range, 262-1970 microg/g dry wt.) and Zn (range, 242-369 microg/g dry wt.) were observed in liver of sucklings of estuarine dolphin. Hepatic concentrations of V, Se, T-Hg, Org-Hg and Pb were significantly higher in estuarine dolphin, whereas Franciscana dolphin showed higher concentrations of Mn, Co, As and Rb. Ratio of Org-Hg to T-Hg in liver was significantly higher in Franciscana dolphin than estuarine dolphin, suggesting that demethylation ability of methyl Hg might be lower in liver of Franciscana than estuarine dolphins. High hepatic concentrations of Ag were found in some specimens of Franciscana dolphin (maximum, 20 microg/g dry wt.), and 17% of Franciscana showed higher concentrations of Ag than Hg. These samples with high Ag concentration also exhibited elevated hepatic Se concentration, implying that Ag might be detoxified by Se in the liver. Higher correlation coefficient between (Hg+0.5 Ag) and Se than between Hg and Se and the large distribution of Ag in non-soluble fraction in nuclear and mitochondrial fraction of the liver also suggests that Ag might be detoxified by Se via formation of Ag2Se in the liver of Franciscana dolphin.  相似文献   

Agricultural land use dynamics in the Brazilian Amazon based on remote sensing and census data     

Giovana M. de Espindola  Ana Paula D. de AguiarEdzer Pebesma  Gilberto CâmaraLeila Fonseca 《Applied geography (Sevenoaks, England)》2012,32(2):240-252

The potential impact of deforestation in the Brazilian Amazon on greenhouse gas emissions to the atmosphere calls for policies that take account of changes in forest cover. Although much research has focused on the location and effects of deforestation, little is known about the distribution and reasons for the agricultural uses that replace forest cover. We used Landsat TM-based deforestation and agricultural census data to generate maps of the distribution and proportion of four major agricultural land uses throughout the Brazilian Amazon in 1997 and 2007. We built linear and spatial regression models to assess the determinant factors of deforestation and those major agricultural land uses - pasture, temporary agriculture and permanent agriculture - for the states of Pará, Rondônia, and Mato Grosso. The data include 30 determinant factors that were grouped into two years (1996 and 2006) and in four categories: accessibility to markets, public policies, agrarian structure, and environment. We found an overall expansion of the total agricultural area between 1997 and 2007, and notable differences between the states of Pará, Rondônia, and Mato Grosso in land use changes during this period. Regression models for deforestation and pasture indicated that determinant factors such as distance to roads were more influential in 1997 than in 2007. The number of settled families played an important role in the deforestation and pasture, the effect was stronger in 2007 than 1997. Indigenous lands were significant in preventing deforestation in high-pressure areas in 2007. For temporary and permanent agricultures, our results show that in 1997 the effect of small farms was stronger than in 2007. The mapped land use time series and the models explain empirically the effects of land use changes across the region over one decade.  相似文献   

Multivariate geostatistical application for climate characterization of Minas Gerais State, Brazil     

Luiz G. de Carvalho  Marcelo de Carvalho Alves  Marcelo S. de Oliveira  Rubens L. Vianello  Gilberto C. Sediyama  Luis M. T. de Carvalho 《Theoretical and Applied Climatology》2010,102(3-4):417-428

The objective of the present study was to assess for Minas Gerais the cokriging methodology, in order to characterize the spatial variability of Thornthwaite annual moisture index, annual rainfall, and average annual air temperature, based on geographical coordinates, altitude, latitude, and longitude. The climatic element data referred to 39 INMET climatic stations located in the state of Minas Gerais and in nearby areas and the covariables altitude, latitude, and longitude to the SRTM digital elevation model. Spatial dependence of data was observed through spherical cross semivariograms and cross covariance models. Box–Cox and log transformation were applied to the positive variables. In these situations, kriged predictions were back-transformed and returned to the same scale as the original data. Trend was removed using global polynomial interpolation. Universal simple cokriging best characterized the climate variables without tendentiousness and with high accuracy and precision when compared to simple cokriging. Considering the satisfactory implementation of universal simple cokriging for the monitoring of climatic elements, this methodology presents enormous potential for the characterization of climate change impact in Minas Gerais state.  相似文献   

Micro-seismic monitoring after the shipwreck of the Costa Concordia at Giglio Island (Italy)     

Andrea Fiaschi  Luca Matassoni  Alessia Lotti  Gilberto Saccorotti 《Acta Geophysica》2017,65(5):1019-1027

A micro-seismic network was used for monitoring the wreck of the Costa Concordia cruise ship, wrecked and run agrounded along the Giglio Island coasts during the night of 13 January 2012, until its removal. The seismic traces were processed by means of real-time and “a posteriori” procedures to detect transients that could be ascribed to wreck movements on the sea bed to integrate this information in an early warning system for assessing the wreck stability. After a first discrimination of the transients using amplitude criteria we proceeded to the localization of the detected signals to focus the attention only on the transients originated in the shipwreck resting area. The results showed that most of the events localized on the wreck were likely related to human work activities or sudden internal brittle failure but not to displacements on the seafloor. Instead, the displacements are associated to the impact on the vessel of great sea storms which approach were well correlated with the increasing seismic noise at low frequency. The carried out procedures based on this unique dataset represent an opportunity to test seismic monitoring techniques also in not usual engineering context to support emergency management activities.  相似文献   

Implementation of online model updating in hybrid simulation          下载免费PDF全文

M. Javad Hashemi  Armin Masroor  Gilberto Mosqueda 《地震工程与结构动力学》2014,43(3):395-412

Hybrid simulation combines numerical and experimental methods for cost‐effective, large‐scale testing of structures under simulated earthquake loading. Structural system level response can be obtained by expressing the equation of motion for the combined experimental and numerical substructures, and solved using time‐stepping integration similar to pure numerical simulations. It is often assumed that a reliable model exists for the numerical substructures while the experimental substructures correspond to parts of the structure that are difficult to model. A wealth of data becomes available during the simulation from the measured experiment response that can be used to improve upon the numerical models, particularly if a component with similar structural configuration and material properties is being tested and subjected to a comparable load pattern. To take advantage of experimental measurements, a new hybrid test framework is proposed with an updating scheme to update the initial modeling parameters of the numerical model based on the instantaneously‐measured response of the experimental substructures as the test progresses. Numerical simulations are first conducted to evaluate key algorithms for the selection and calibration of modeling parameters that can be updated. The framework is then expanded to conduct actual hybrid simulations of a structural frame model including a physical substructure in the laboratory and a numerical substructure that is updated during the tests. The effectiveness of the proposed framework is demonstrated for a simple frame structure but is extendable to more complex structural behavior and models. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Innovative substructuring technique for hybrid simulation of multistory buildings through collapse          下载免费PDF全文

M. Javad Hashemi  Gilberto Mosqueda 《地震工程与结构动力学》2014,43(14):2059-2074

Hybrid simulation combines numerical and experimental methods for cost‐effective, large‐scale testing of structures under simulated dynamic earthquake loads. Particularly for experimental seismic collapse simulation of structures, hybrid testing can be an attractive alternative to earthquake simulators due to the limited capacity of most facilities and the difficulties and risks associated with a collapsing structure on a shaking table. The benefits of hybrid simulation through collapse can be further enhanced through accurate and practical substructuring techniques that do not require testing the entire structure. An innovative substructuring technique for hybrid simulation of structures subjected to large deformations is proposed to simplify the boundary conditions by overlapping the domains between the numerical and experimental subassemblies. The advantages of this substructuring technique are the following: it requires only critical components of the structure to be tested experimentally; it reduces the number of actuators at the interface of the experimental subassemblies; and it can be implemented using typically available equipment in laboratories. Compared with previous overlapping methods that have been applied in hybrid simulation, this approach requires additional sensing in the hybrid simulation feedback loop to obtain internal member forces, but provides significantly better accuracy in the highly nonlinear range. The proposed substructuring technique is verified numerically and validated experimentally, using the response of a four‐story moment‐resisting frame that was previously tested to collapse on an earthquake simulator. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Detrital zircon U–Pb ages and whole-rock geochemistry of the Neoproterozoic Paulistana and Santa Filomena complexes,Borborema Province,northeastern Brazil: implications for source area composition,provenance, and tectonic setting     

Felipe H. Santos  Wagner S. Amaral  Evilarde C. Uchôa Filho  Douglas T. Martins 《International Geology Review》2017,59(15):1861-1884

The Paulistana and Santa Filomena Complexes are situated in the southern part of the Borborema Province (northeastern Brazil), in the Riacho do Pontal Orogen, and represent meta-volcano-sedimentary sequences. We present compositional variations in the metasedimentary rocks and new U–Pb detrital zircon data. Major and trace elements indicate that the metasedimentary rocks from the Paulistana and Santa Filomena Complexes are composed mostly of immature to mature sediments derived from felsic-intermediate sources with moderate to slightly high chemical weathering. The geochemical signatures of the sediment protoliths for both complexes are characteristic of continental magmatic arc settings with minor contribution from recycled sediment sources. The source area for the Paulistana Complex rocks follow the compositional trend between calc-alkaline granites and granodiorites, whereas the Santa Filomena Complex rocks have a more restricted composition trending to more granodioritic sources. For the Paulistana Complex, two main source ages were identified: (1) Tonian (ca. 950 Ma – sample RPE-58) and Tonian–Stenian (ca. 1.0 Ga – sample RPE-103). These data coupled with geochemical information suggest that the Cariris Velhos arc system was the main source area for the Paulistana Complex. Regarding the Santa Filomena metasedimentary rocks, potential source-areas include: (1) Neoarchaean rocks (~2.6 Ga) represented by the adjacent basement rocks of the Riacho do Pontal Orogen; (2) Rhyacian–Orosirian rocks (2.2–2.0 Ga) of the Riacho do Pontal Orogen and the Pernambuco–Alagoas terrain, which include an augen-gneiss with arc-related geochemical signature; (3) Statherian granites (1.7–1.6 Ga); and (4) Cariris Velhos crust (1000–920 Ma). The metasedimentary rocks of the Paulistana Complex were deposited in a rift stage (ca. 900 Ma), which is related to the break-up of the Rodinia supercontinent. The metasedimentary rocks of the Santa Filomena Complex most probably were deposited in another rift stage (ca. 750–700 Ma) and could be correlatives of the rift formation of the Canindé Domain (Sergipano Orogen).  相似文献