Correlations and sequence stratigraphic model for Messinian carbonate platforms of the western and central Mediterranean   总被引：1，自引：0，他引：1  

Jean-Jacques?CornéeEmail author  Jean-Paul?Saint Martin  Gilles?Conesa  Philippe?Münch  Jean-Pierre?André  Simona?Saint Martin  Stefan?Roger 《International Journal of Earth Sciences》2004,93(4):621-633

Distance correlations of Late Tortonian–Messinian littoral carbonate complexes are proposed from the study of eight platforms in the western and central Mediterranean. Correlations are based on the identification of two major biological sedimentary cycles and of two index surfaces. Surface A is a maximum flooding surface during cycle 1 at around 6.7 Ma. Surface B is a regional marine planation surface at around 5.95 Ma, at the base of cycle 2 (Terminal Carbonate Complex). A general sedimentary model is proposed for the 7–5.6-Ma time-span. The boundary between cycles 1 and 2 is coincident with the onset of the Messinian Salinity Crisis, and appears to be related to major environmental–paleo-oceanographic changes in the Mediterranean, rather than to a major sea-level drop or to climatic change.  相似文献   

Architecture interne d'une vallée incisée sur une côte à forte énergie de houle et de marée (vallée de la Leyre,côte aquitaine,France)     

Hugues Féniès  Gilles Lericolais 《Comptes Rendus Geoscience》2005,337(14):1257-1266

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Spatial Variability of Trends in the Rainfall-Runoff Relationship: A Mesoscale Study in the Mosel Basin     

Laurent Pfister  Gilles Drogue  Abdelkhalak El Idrissi  Jean-François Iffly  Christelle Poirier  Lucien Hoffmann 《Climatic change》2004,66(1-2):67-87

The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area.  相似文献   

The Upper Rhône Delta Sedimentary Record in the Arles-Piton Core: Analysis of Delta-Plain Subenvironments, Avulsion Frequency, Aggradation Rate and Origin of Sediment Yield     

Gilles Arnaud-Fassetta 《Geografiska Annaler: Series A, Physical Geography》2004,86(4):367-383

Results from analyses of the Arles‐Piton sediment core, retrieved from the apex of the Rhône Delta, highlight processes of Holocene deltaic construction controlled mainly by hydrosedimentary variability and channel avulsions. The alluvial suite was investigated for grain size, sedimentary structures, CaCO₃, organic matter, heavy minerals and chrono‐stratigraphy (¹⁴C and archaeological/historical dates). The study shows the succession of six facies associations: a distributary channel (before 6157‐5843 BC), a swamp (5719‐5530/4796‐4463 BC), a distal flood plain (5719‐5530/4796‐4463 BC), a distributary channel (4796‐4463/2900‐2503 BC), a proximal flood plain (2900‐2503 BC/AD 270‐290), and a crevasse splay (after AD 270‐290). Substantial changes in hydrodynamics are strongly linked to three channel avulsions (before 6157‐5843 BC, after 4796‐4463 BC and after 2900‐2503 BC). A correlation with the whole channel avulsion history of the Rhône Delta allowed us to propose an average rhythm of channel avulsion of c. 1450 years. From 5719‐5530 BC to AD 270‐290, the flood plain aggraded at the average rate of 2.5 mm/a. The aggradation rates were higher both in the proximal and distal flood plains, where sedimentation process is continuous. They were lower both in the active distributary channels, because of frequent truncation of the alluvial suite, and the abandoned channels where detritic inputs are minimum. The sediment supply arriving to the upper Rhône Delta was derived mainly from proximal source areas (Massif Central, Southern Alps) during the last 8000 years, except during the hydrological changes of Roman antiquity during which detritic inputs were derived firstly from the Northern Alps and Southern Alps, and secondly from the Massif Central.  相似文献   

Speciation and characterization of arsenic in gold ores and cyanidation tailings using X-ray absorption spectroscopy     

Dogan Paktunc  Andrea Foster  Gilles Laflamme 《Geochimica et cosmochimica acta》2004,68(5):969-983

The knowledge of mineralogy and molecular structure of As is needed to better understand the stability of As in wastes resulting from processing of gold ores. In this study, optical microscopy, scanning electron microscopy, electron microprobe, X-ray diffraction and X-ray absorption fine structure (XAFS) spectroscopy (including both XANES and EXAFS regimes) were employed to determine the mineralogical composition and local coordination environment of As in gold ores and process tailings from bench-scale tests designed to mimic a common plant practice. Arsenic-bearing minerals identified in the ores and tailings include iron (III) oxyhydroxides, scorodite (FeAsO₄·2H₂O), ferric arsenates, arseniosiderite (Ca₂Fe₃(AsO₄)₃O₂·3H₂O), Ca-Fe arsenates, pharmacosiderite (KFe₄(AsO₄)₃(OH)₄·6-7H₂O), jarosite (K₂Fe₆(SO₄)₄(OH)₁₂) and arsenopyrite (FeAsS). Iron (III) oxyhydroxides contain variable levels of As from trace to about 22 wt% and Ca up to approximately 9 wt%.Finely ground ore and tailings samples were examined by bulk XAFS and selected mineral grains were analyzed by microfocused XAFS (micro-EXAFS) spectroscopy to reconcile the ambiguities of multiple As sources in the complex bulk EXAFS spectra. XANES spectra indicated that As occurs as As⁵⁺in all the samples. Micro-EXAFS spectra of individual iron (III) oxyhydroxide grains with varying As concentrations point to inner-sphere bidentate-binuclear arsenate complexes as the predominant form of As. There are indications for the presence of a second Fe shell corresponding to bidentate-mononuclear arrangement. Iron (III) oxyhydroxides with high As concentrations corresponding to maximum adsorption densities probably occur as nanoparticles. The discovery of Ca atoms around As in iron (III) oxyhydroxides at interatomic distances of 4.14-4.17 Å and the coordination numbers suggest the formation of arseniosiderite-like nanoclusters by coprecipitation rather than simple adsorption of Ca onto iron (III) oxyhydroxides. Correlation of Ca with As in iron (III) oxyhydroxides as determined by electron microprobe analysis supports the coprecipitate origin for the presence of Ca in iron (III) oxyhydroxides.The samples containing higher abundances of ferric arsenates released higher As concentrations during the cyanidation tests. The presence of highly soluble ferric arsenates and Ca-Fe arsenates, and relatively unstable iron (III) oxyhydroxides with Fe/As molar ratios of less than 4 in the ore and process tailings suggests that not only the tailings in the impoundment will continue to release As, but also there is the potential for mobilization of As from the natural sources such as the unmined ore.  相似文献   

Hydrous ferric oxide precipitation in the presence of nonmetabolizing bacteria: Constraints on the mechanism of a biotic effect     

Denis G. Rancourt  Pierre-Jean Thibault  Denis Mavrocordatos  Gilles Lamarche 《Geochimica et cosmochimica acta》2005,69(3):553-577

We have used room temperature and cryogenic ⁵⁷Fe Mössbauer spectroscopy, powder X-ray diffraction (pXRD), mineral magnetometry, and transmission electron microscopy (TEM), to study the synthetic precipitation of hydrous ferric oxides (HFOs) prepared either in the absence (abiotic, a-HFO) or presence (biotic, b-HFO) of nonmetabolizing bacterial cells (Bacillus subtilis or Bacillus licheniformis, ∼10⁸ cells/mL) and under otherwise identical chemical conditions, starting from Fe(II) (10⁻², 10⁻³, or 10⁻⁴ mol/L) under open oxic conditions and at different pH (6-9). We have also performed the first Mössbauer spectroscopy measurements of bacterial cell wall (Bacillus subtilis) surface complexed Fe, where Fe(III) (10^−3.5-10^−4.5 mol/L) was added to a fixed concentration of cells (∼10⁸ cells/mL) under open oxic conditions and at various pH (2.5-4.3). We find that non-metabolic bacterial cell wall surface complexation of Fe is not passive in that it affects Fe speciation in at least two ways: (1) it can reduce Fe(III) to sorbed-Fe²⁺ by a proposed steric and charge transfer effect and (2) it stabilizes Fe(II) as sorbed-Fe²⁺ against ambient oxidation. The cell wall sorption of Fe occurs in a manner that is not compatible with incorporation into the HFO structure (different coordination environment and stabilization of the ferrous state) and the cell wall-sorbed Fe is not chemically bonded to the HFO particle when they coexist (the sorbed Fe is not magnetically polarized by the HFO particle in its magnetically ordered state). This invalidates the concept that sorption is the first step in a heterogeneous nucleation of HFO onto bacterial cell walls. Both the a-HFOs and the b-HFOs are predominantly varieties of ferrihydrite (Fh), often containing admixtures of nanophase lepidocrocite (nLp), yet they show significant abiotic/biotic differences: Biotic Fh has less intraparticle (including surface region) atomic order (Mössbauer quadrupole splitting), smaller primary particle size (magnetometry blocking temperature), weaker Fe to particle bond strength (Mössbauer center shift), and no six-line Fh (6L-Fh) admixture (pXRD, magnetometry). Contrary to current belief, we find that 6L-Fh appears to be precipitated directly, under a-HFO conditions, from either Fe(II) or Fe(III), and depending on Fe concentration and pH, whereas the presence of bacteria disables all such 6L-Fh precipitation and produces two-line Fh (2L-Fh)-like biotic coprecipitates. Given the nature of the differences between a-HFO and b-HFO and their synthesis condition dependences, several biotic precipitation mechanisms (template effect, near-cell environment effect, catalyzed nucleation and/or growth effect, and substrate-based coprecipitation) are ruled out. The prevailing present view of a template or heterogeneous nucleation barrier reduction effect, in particular, is shown not to be the cause of the large observed biotic effects on the resulting HFOs. The only proposed mechanism (relevant to Fh) that is consistent with all our observations is coprecipitation with and possible surface poisoning by ancillary bacteriagenic compounds. That bacterial cell wall functional groups are redox active and the characteristics of biotic (i.e., natural) HFOs compared to those of abiotic (i.e., synthetic) HFOs have several possible biogeochemical implications regarding Fe cycling, in the photic zones of water columns in particular.  相似文献   

Comments on “(U–Th)/He dating of fluorite: application to the La Azul fluorspar deposit in the Taxco mining district, Mexico” by Pi et al. (Mineralium Deposita 39: 976–982)     

Jordi Tritlla  Gilles Levresse 《Mineralium Deposita》2006,41(3):296-299

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The recent fault scarps of the Western Alps (France): Tectonic surface ruptures or gravitational sackung scarps? A combined mapping, geomorphic, levelling, and Be dating approach     

Jean-Claude Hippolyte  Gilles Brocard  Marc Tardy  Grard Nicoud  Didier Bourls  Rgis Braucher  Gilles Mnard  Blaise Souffach 《Tectonophysics》2006,418(3-4):255-276

In the Western Alps, some recent scarps were previously interpreted as surface ruptures of tectonic reverse and normal faults that agree with microseismicity and GPS measurements. Our analysis shows that in fact there are hundreds of recent scarps, up to 30 m high and 2.1 km long, with only pure normal motions. They share the same characteristics as typical sackung scarps. The scarps are mainly uphill facing, parallel to the ridge crests and the contour lines. They are relatively short (less than 2.1 km) with respect to tectonic fault ruptures, and organized in swarms. They cut screes and relict rock glaciers with a slow (commonly 1 mm/year) average slip rate. In the Aiguilles Grives massif these sackung scarps clearly express the gravitational toppling of sub-vertical bedding planes in hard rocks. In contrast, the Belledonne Outer Crystalline Massif exhibits scarps that stem from the gravitational reactivation of conjugate tectonic faults. The recent faults extend to about 1600 m beneath the Rognier ridge crest, but are always above the valley floor. The main scarp swarm is 9.2 km long and constitutes the largest sackung ever described in the Western Alps. ¹⁰Be dating of a scarp and offset surfaces shows that > 4 m slip may have occurred rapidly (in less than 3800 years) sometimes between the end of the glaciation and 8800 ± 1900 years ago. This dating, together with the location of some faults far from the deep glacial valleys, suggests that sagging might have been triggered by strong earthquakes during a post-glacial period of probably enhanced seismicity. The Belledonne and Synclinal Median faults (just beneath the Rognier sackung) could have been the sources of this seismicity.  相似文献   

Speciation and role of iron in cloud droplets at the puy de Dôme station     

Marius Parazols  Angela Marinoni  Pierre Amato  Otman Abida  Paolo Laj  Gilles Mailhot 《Journal of Atmospheric Chemistry》2006,54(3):267-281

Iron is the most abundant transition metal in the atmosphere and can play a significant role in cloudwater chemistry where its reactivity is closely related to the partitioning between Fe(II) and Fe(III). The objective of this work is to determine the total iron content and the iron speciation in a free tropospheric site, and to understand which factors influence these parameters. We collected 147 samples of cloudwater during 34 cloud events over a period of four years at the puy de Dôme summit. Besides iron we measured other chemical compounds, solar radiation, physico-chemical and meteorological parameters potentially connected with iron reactivity. The total iron concentrations ranged from 0.1 to 9.1 μM with the major frequency occurring at low levels. The pH and presence of organic complexants seem to be the most significant factors connected with total dissolved iron; while the iron oxidation state seems to be an independent factor. Light intensity, presence of complexants or oxidants (H₂O₂) do not influence the Fe(II)/Fe(Total) ratio, that was quite constant at about 0.75. This could be due to the potential redox that forces the Fe(II)-Fe(III) couple to the reduced form or, more probably to the complexation by Natural Organic Matter, that can stabilize iron in its reduced form and prevent further oxidation. Our field measurements did not show the diurnal cycle observed in surface water and predicted by models of atmospheric chemistry. This result prompts a more careful review of the role of iron and, by analogy, all the transition metals in atmospheric liquid phase, often over-estimated in the literature.  相似文献   

Ptolemaic Transformation in Keplerian Problem     

Sławomir Breiter  Gilles Métris 《Celestial Mechanics and Dynamical Astronomy》2002,84(4):319-330

We propose the Ptolemaic transformation: a canonical change of variables reducing the Keplerian motion to the form of a perturbed Hamiltonian problem. As a solution of the unperturbed case, the Ptolemaic variables define an intermediary orbit, accurate up to the first power of eccentricity, like in the kinematic model of Claudius Ptolemy. In order to normalize the perturbed Hamiltonian we modify the recurrent Lie series algorithm of HoriuuMersman. The modified algorithm accounts for the loss of a term's order during the evaluation of a Poisson bracket, and thus can be also applied in resonance problems. The normalized Hamiltonian consists of a single Keplerian term; the mean Ptolemaic variables occur to be trivial, linear functions of the Delaunay actions and angles. The generator of the transformation may serve to expand various functions in Poisson series of eccentricity and mean anomaly.  相似文献