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71.
The purpose of the present study was to assess the in vitro effect of some imidazole (prochloraz, imazalil) and triazole (epoxiconazole) agricultural fungicides on gonadotropin-induced oocyte maturation in rainbow trout. Results show that prochloraz, epoxiconazole and imazalil strongly potentiated the induction of oocyte maturation by gonadotropin in a dose-dependent manner. Furthermore, 10−5 M prochloraz and epoxiconazole alone induced oocyte maturation. The mRNA biosynthesis inhibitor, actinomycin , completely inhibited oocyte maturation induced by fungicides, suggesting that the gonadotropin-like effect of these chemicals is at least dependent on de novo gene expression.  相似文献   
72.
The multivariate variogram and the multivariate covariogram are used as spatial weighting functions for forming spatially homogeneous groups automatically. The groups are created after either deflating similarities between distant samples with the multivariate covariogram or by inflating dissimilarities between distant samples with the multivariate variogram. These approaches can be seen as generalization of the Oliver and Webster proposal. Two data sets show the efficiency of the two weighting functions when compared to the classical approach which does not take spatial information into account. In one case study, the weighting of similarities by the multivariate covariogram showed more interpretable results than the weighting of dissimilarities by the multivariate variogram.  相似文献   
73.
This paper presents a lake‐level record for the Holocene at Lake Cerin (Jura Mountains, eastern France). It is based on a range of sedimentological techniques validated in previous studies, with a combination of systematic lithostratigraphic investigations of the infillings accumulated in the lacustrine basin, and sediment analyses of two selected cores. The chronology is based on 10 radiocarbon dates and pollen stratigraphy. On a millennial scale, the Cerin lake‐level record shows three distinct successive phases characterised by higher lake‐level conditions until ca. 9000 cal. a BP, followed by a maximal lowering at ca. 9000–8500 cal. a BP, and a progressive rise until the present. This rise was punctuated by centennial‐scale fluctuations, with major events around 4000, 2800 and after 1500 cal. a BP. Considered on a multimillennial scale, the general pattern of palaeohydrological changes reconstructed at Cerin reflects the impact of orbitally driven summer insolation. This is in agreement with other regional and extra‐regional palaeoclimatic records, although every record shows peculiarities in timing and shape depending on the proxy used for reconstruction. In this general context, centennial to multicentennial oscillations appear to have been second‐order events in comparison with the major influence of the orbital factor. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
74.
The transfer of fatty acids (FAs) in the food web of a Mediterranean lagoon was studied using FA compositional patterns across several trophic levels. The structure of the food web was inferred from C and N stable isotopes values and an isotope mixing model was used in order to estimate the relative contribution of the different potential food sources to the biomass of consumers. Bidimensional plots of FA composition of food web components against their δ15N values indicated a general trend of increasing proportions of highly unsaturated fatty acids (HUFAs) with increasing trophic levels while the proportions of saturated fatty acids (SAFAs) and 18-carbon polyunsaturated fatty acids (PUFAs) decreased. Using the relative contributions of food sources to consumers and their FA compositions, a model was built in order to estimate the PUFA composition of consumer mixed diets which was compared to consumer PUFA profiles. The latter allowed the identification of the PUFAs which were mostly enriched/retained in consumer lipids. There was a surprisingly high retention of arachidonic acid (ARA), a trend which challenges the idea of low ARA needs in marine fish and suggests the important physiological role of this essential FA for fish in estuarine environments.  相似文献   
75.
76.
Distance correlations of Late Tortonian–Messinian littoral carbonate complexes are proposed from the study of eight platforms in the western and central Mediterranean. Correlations are based on the identification of two major biological sedimentary cycles and of two index surfaces. Surface A is a maximum flooding surface during cycle 1 at around 6.7 Ma. Surface B is a regional marine planation surface at around 5.95 Ma, at the base of cycle 2 (Terminal Carbonate Complex). A general sedimentary model is proposed for the 7–5.6-Ma time-span. The boundary between cycles 1 and 2 is coincident with the onset of the Messinian Salinity Crisis, and appears to be related to major environmental–paleo-oceanographic changes in the Mediterranean, rather than to a major sea-level drop or to climatic change.  相似文献   
77.
78.
The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area.  相似文献   
79.
Results from analyses of the Arles‐Piton sediment core, retrieved from the apex of the Rhône Delta, highlight processes of Holocene deltaic construction controlled mainly by hydrosedimentary variability and channel avulsions. The alluvial suite was investigated for grain size, sedimentary structures, CaCO3, organic matter, heavy minerals and chrono‐stratigraphy (14C and archaeological/historical dates). The study shows the succession of six facies associations: a distributary channel (before 6157‐5843 BC), a swamp (5719‐5530/4796‐4463 BC), a distal flood plain (5719‐5530/4796‐4463 BC), a distributary channel (4796‐4463/2900‐2503 BC), a proximal flood plain (2900‐2503 BC/AD 270‐290), and a crevasse splay (after AD 270‐290). Substantial changes in hydrodynamics are strongly linked to three channel avulsions (before 6157‐5843 BC, after 4796‐4463 BC and after 2900‐2503 BC). A correlation with the whole channel avulsion history of the Rhône Delta allowed us to propose an average rhythm of channel avulsion of c. 1450 years. From 5719‐5530 BC to AD 270‐290, the flood plain aggraded at the average rate of 2.5 mm/a. The aggradation rates were higher both in the proximal and distal flood plains, where sedimentation process is continuous. They were lower both in the active distributary channels, because of frequent truncation of the alluvial suite, and the abandoned channels where detritic inputs are minimum. The sediment supply arriving to the upper Rhône Delta was derived mainly from proximal source areas (Massif Central, Southern Alps) during the last 8000 years, except during the hydrological changes of Roman antiquity during which detritic inputs were derived firstly from the Northern Alps and Southern Alps, and secondly from the Massif Central.  相似文献   
80.
The knowledge of mineralogy and molecular structure of As is needed to better understand the stability of As in wastes resulting from processing of gold ores. In this study, optical microscopy, scanning electron microscopy, electron microprobe, X-ray diffraction and X-ray absorption fine structure (XAFS) spectroscopy (including both XANES and EXAFS regimes) were employed to determine the mineralogical composition and local coordination environment of As in gold ores and process tailings from bench-scale tests designed to mimic a common plant practice. Arsenic-bearing minerals identified in the ores and tailings include iron (III) oxyhydroxides, scorodite (FeAsO4·2H2O), ferric arsenates, arseniosiderite (Ca2Fe3(AsO4)3O2·3H2O), Ca-Fe arsenates, pharmacosiderite (KFe4(AsO4)3(OH)4·6-7H2O), jarosite (K2Fe6(SO4)4(OH)12) and arsenopyrite (FeAsS). Iron (III) oxyhydroxides contain variable levels of As from trace to about 22 wt% and Ca up to approximately 9 wt%.Finely ground ore and tailings samples were examined by bulk XAFS and selected mineral grains were analyzed by microfocused XAFS (micro-EXAFS) spectroscopy to reconcile the ambiguities of multiple As sources in the complex bulk EXAFS spectra. XANES spectra indicated that As occurs as As5+in all the samples. Micro-EXAFS spectra of individual iron (III) oxyhydroxide grains with varying As concentrations point to inner-sphere bidentate-binuclear arsenate complexes as the predominant form of As. There are indications for the presence of a second Fe shell corresponding to bidentate-mononuclear arrangement. Iron (III) oxyhydroxides with high As concentrations corresponding to maximum adsorption densities probably occur as nanoparticles. The discovery of Ca atoms around As in iron (III) oxyhydroxides at interatomic distances of 4.14-4.17 Å and the coordination numbers suggest the formation of arseniosiderite-like nanoclusters by coprecipitation rather than simple adsorption of Ca onto iron (III) oxyhydroxides. Correlation of Ca with As in iron (III) oxyhydroxides as determined by electron microprobe analysis supports the coprecipitate origin for the presence of Ca in iron (III) oxyhydroxides.The samples containing higher abundances of ferric arsenates released higher As concentrations during the cyanidation tests. The presence of highly soluble ferric arsenates and Ca-Fe arsenates, and relatively unstable iron (III) oxyhydroxides with Fe/As molar ratios of less than 4 in the ore and process tailings suggests that not only the tailings in the impoundment will continue to release As, but also there is the potential for mobilization of As from the natural sources such as the unmined ore.  相似文献   
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