Groundwater mixing in the discharge area of San Vittorino Plain (Central Italy): geochemical characterization and implication for drinking uses     

Maurizio Barbieri  Angela Nigro  Marco Petitta 《Environmental Earth Sciences》2017,76(11):393

Discharge areas of carbonate fractured and karstified aquifers are a sensitive system of great interest, where frequently groundwater resources are tapped for drinking water supply. In geological settings affected by recent and/or active tectonics, mixing between fresh water coming from recharge areas and groundwater from deeper circuits, influenced by raising fluids, influences hydrogeochemistry. Surveys on major ions, trace elements and stable isotopes have been performed in the San Vittorino Plain (Central Italy), where the major source of drinking water for Rome is located (Peschiera Springs, mean discharge 18 m³ s^?1, half of them tapped). Results of 21 springs revealed different contribution from recharge areas and deep flow paths, by increasing salinity and ion content, with particular references to Ca²⁺, HCO₃ ^? and SO₄ ^2?. Three main groups, respectively, related to fresh waters from recharge areas, groundwater from deep contribution and a mixing group between them, have been identified. Water stable isotopes allow to identify the common origin from rainfall and a very steady contribution with seasons and year, due to the huge extent of recharge area (>1000 km²). Saturation Indexes gave insight on the contribution of deep fluids, mainly CO₂ and H₂S, which turned groundwater to undersaturated conditions, facilitating rock dissolution. By PHREEQC software, the mixing between two considered end-members has been simulated, evaluating about 25% of deep contribution in the basal springs of San Vittorino Plain. Chemistry of Peschiera spring reveals a very limited percentage of deep flow paths (10%), which can lead to slight hydrochemistry changes even in possible drought conditions, when discharge can decrease until 15 m³ s^?1.  相似文献   

Description of Lake Lugano     

Alberto Barbieri  Bruno Polli 《Aquatic Sciences - Research Across Boundaries》1992,54(3-4):181-183

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The Digicon system of Cima Ekar observatory     

C. Barbieri  F. Bortoletto  S. Di Serego Alighieri 《Astrophysics and Space Science》1980,73(1):199-206

This paper describes the Digicon system in current operation for spectroscopic acquisition at the 182-cm telescope of Cima Ekar (Asiago). An example of observation of the emission-line galaxy VV 565 provides evidence of the quality of the system.  相似文献   

Preservation of organic matter and alteration of its carbon and nitrogen isotope composition during simulated and in situ early sedimentary diagenesis   总被引：8，自引：0，他引：8  

Moritz F Lehmann  Stefano M BernasconiAlberto Barbieri  Judith A McKenzie 《Geochimica et cosmochimica acta》2002,66(20):3573-3584

The carbon and nitrogen isotope composition of organic matter has been widely used to trace biogeochemical processes in marine and lacustrine environments. In order to reconstruct past environmental changes from sedimentary organic matter, it is crucial to consider potential alteration of the primary isotopic signal by bacterial degradation in the water column and during early diagenesis in the sediments.In a series of oxic and anoxic incubation experiments, we examined the fate of organic matter and the alteration of its carbon and nitrogen isotopic composition during microbial degradation. The decomposition rates determined with a double-exponential decay model show that the more reactive fraction of organic matter degrades at similar rates under oxic and anoxic conditions. However, under oxic conditions the proportion of organic matter resistent to degradation is much lower than under anoxic conditions. Within three months of incubation the δ¹³C of bulk organic matter decreased by 1.6‰ with respect to the initial value. The depletion can be attributed to the selective preservation of ¹³C-depleted organic compounds. During anoxic decay, the δ¹⁵N values continuously decreased to about 3‰ below the initial value. The decrease probably results from bacterial growth adding ¹⁵N-depleted biomass to the residual material. In the oxic experiment, δ¹⁵N values increased by more then 3‰ before decreasing to a value indistinguishable from the initial isotopic composition. The dissimilarity between oxic and anoxic conditions may be attributed to differences in the type, timing and degree of microbial activity and preferential degradation. In agreement with the anoxic incubation experiments, sediments from eutrophic Lake Lugano are, on average, depleted in ¹³C (−1.5‰) and ¹⁵N (−1.2‰) with respect to sinking particulate organic matter collected during a long-term sediment trap study.  相似文献   

Chemical evolution, petrogenesis, and regional chemical correlations of the flood basalt sequence in the central Deccan Traps, India     

L. Melluso  M. Barbieri  L. Beccaluva 《Journal of Earth System Science》2004,113(4):587-603

The lava sequence of the central-western Deccan Traps (from Jalgaon towards Mumbai) is formed by basalts and basaltic andesites having a significant variation in TiO₂ (from 1.2 to 3.3 wt%), Zr (from 84 to 253 ppm), Nb (from 5 to 16ppm) and Ba (from 63 to 407 ppm), at MgO ranging from 10 to 4.2 wt%. Most of these basalts follow a liquid line of descent dominated by low pressure fractionation of clinopyroxene, plagioclase and olivine, starting from the most mafic compositions, in a temperature range from 1220° to 1125°C. These rocks resemble those belonging to the lower-most formations of the Deccan Traps in the Western Ghats (Jawhar, Igatpuri and Thakurvadi) as well as those of the Poladpur formation. Samples analyzed for⁸⁷Sr/⁸⁶Sr give a range of initial ratios from 0.70558 to 0.70621. A group of flows of the Dhule area has low TiO₂ (1.2–1.5 wt%) and Zr (84–105 ppm) at moderate MgO (5.2–6.2 wt%), matching the composition of low-Ti basalts of Gujarat, low-Ti dykes of the Tapti swarm and Toranmal basalts, just north of the study area. This allows chemical correlations between the lavas of central Deccan, the Tapti dykes and the north-western outcrops. The mildly enriched high field strength element contents of the samples with TiO₂ > 1.5 wt% make them products of mantle sources broadly similar to those which generated the Ambenali basalts, but their high La/Nb and Ba/Nb, negative Nb anomalies in the mantle normalized diagrams, and relatively high⁸⁷Sr/⁸⁶Sr, make evident a crustal input with crustally derived materials at less differentiated stages than those represented in this sample set, or even within the sub-Indian lithospheric mantle.  相似文献   

Unified structural classification of AB2 molecules and solids from valence electron orbital radii     

Wanda Andreoni  Giulia Galli 《Physics and Chemistry of Minerals》1987,14(5):389-395

We present structural plots for AB₂ molecules and solids with sp-bonding based on parameters derived from valence electron orbital radii. We show that the same schemes that allow one to classify crystals with different structures, are also able to distinguish molecular shapes into linear and bent. Our picture is consistent with the existence of a critical numberN _c =16of valence electrons, in agreement with the Mulliken-Walsh rule, and accounts for many exceptions to the latter in the caseN≤16. We discuss critically our findings and announce new results on AB₃ molecules. We also discuss preliminary results of model calculations on AB₂ molecules.  相似文献   

Natural subsidence of the Venice area during the last 60 Myr     

C. Barbieri  A. Di Giulio  F. Massari†  A. Asioli‡  M. Bonato†  N. Mancin 《Basin Research》2007,19(1):105-123

Integrated geohistory analysis performed on high‐resolution stratigraphy of Venezia 1 and Lido 1 wells (Quaternary–Pliocene interval) and low‐resolution stratigraphy of a simulated well extending Lido 1 down to the base of Cenozoic (Palaeocene–Miocene interval) is used to reconstruct the interplay between subsidence and sedimentation that occurred in the Venice area (eastern Po Plain) during the last 60 Myr, and to discuss the relationships between calculated subsidence rates and time resolution of stratigraphic data. Both subsidence and sedimentation are mostly related to the tectonic evolution of the belts that surround the Venice basin, influencing the lithosphere vertical motions and the input of clastic sediments through time. In particular, two subsidence phases are recorded between 40–33.5 and 32.5–24 Myr (0.13 and 0.14 mm year^?1, respectively), coeval with tectonic phases in the Dinaric belt. Vice versa, during the main South‐Alpine orogenic phase (middle–late Miocene), quiescence or little uplift (?0.03 mm year^?1) reflects the location of the Venice area close to the peripheral bulge of the South‐Alpine foreland system. Early Pliocene evolution is characterised by a number of subsidence/uplift events, among which two uplifts occurred between 5–4.5 and 3–2.2 Myr (at ?0.4 and ?0.2 mm year^?1, respectively) and can be correlated with tectonic motions in the Apennines. During the last million years, the Venice area was initially characterised by uplift (?0.6 mm year^?1 rising to ?1.5 mm year^?1 between 0.4 and 0.38 Myr), eventually replaced by subsidence at a rate ranging between 1.6 and 1.0 mm year^?1 up to 0.12 Myr and then decreased to 0.4 mm year^?1, as an average, up to present. Our results highlight that time resolution of the stratigraphic dataset deeply influences the order of magnitude obtained for the calculated subsidence rate. This is because subsidence seems to have worked through short‐lived peaks (in the order of 10⁵ years), alternating with long relatively quiescent intervals. This suggests caution when components of subsidence are deduced by subtracting long‐term to short‐term subsidence rate.  相似文献   

Endolithic microorganisms from spring mound evaporite deposits (southern Tunisia)     

N. Stivaletta  R. Barbieri 《Journal of Arid Environments》2009,73(1):33-39

This paper investigates endolithic microorganisms in modern gypsum crusts located in arid and saline areas of southern Tunisia. In arid regions, the endolithic mode of life facilitates the survival of the microorganisms and protects them from extreme environmental conditions. The gypsum crusts are the product of evaporite precipitation atop spring mounds developed at the margins of the Chott el Jerid, a saline lake close to the Algerian border. The early mineral precipitation has prevented the complete degradation of these microorganisms and their metabolic products because of the rapid sealing provided by the gypsum crusts. The spring mound structures of the Chott el Jerid offer an opportunity to study the endolithic communities in evaporite and arid environments. An understanding of where and how life survives in such extreme conditions, and how life signal prints in the rocks may help in search for life in the geological record and for astrobiological purposes.  相似文献   

Evaluating the effects of protection on two benthic habitats at Tavolara-Punta Coda Cavallo MPA (North-East Sardinia, Italy)     

Ceccherelli G  Casu D  Pala D  Pinna S  Sechi N 《Marine environmental research》2006,61(2):171-185

In this paper, two benthic habitats have been investigated in a fully protected site and two control sites at the Tavolara-Punta Coda Cavallo marine protected area (MPA) (NE Sardinia). Overall, a protection effect on the benthic assemblages was highlighted in the shallow subtidal (5 m deep) rather than at intertidal algal turf habitat. Structure of assemblages at the shallow subtidal habitat is different in the fully protected site vs. controls, while this was not true for the intertidal habitat. At the subtidal, this finding is probably linked to indirect effects due to an increase of consumers in the protected site (e.g., sea urchins), while the lack of direct impacts in the intertidal at control sites is indicative of very similar assemblages. Cover of encrusting algae was significantly higher at the subtidal protected site suggesting a possible higher grazing pressure. Possible causes underlying the inconsistency of results obtained between habitats include the possibility that trophic cascade effects have a different influence at different heights on the shore. The need to estimate the interconnection among benthic habitats through trophic links is also highlighted to provide an estimate of the vulnerability to protection of various habitats.  相似文献   

Climate variability and pelagic fisheries in northern Chile   总被引：5，自引：0，他引：5  

E. Yez  M. A. Barbieri  C. Silva  K. Nieto  F. Espíndola 《Progress in Oceanography》2001,49(1-4)

A time series analysis of long-term climate variability in northern Chile (18°21′–24°00′S) shows anomalies associated with the El Niño events and the longer warm period observed since 1976, followed by a cooling trend since mid 1980s. The succession of pelagic fisheries, anchovy (Engraulis ringens) and sardine (Sardinops sagax), occurring in this fishing zone was analyzed taking into account the landings, the CPUE abundance index, the fishing effort, and the environmental variables. The anchovy production model is a negative linear function of fishing effort and turbulence. For sardine, the production model is a negative linear function of fishing effort and a quadratic function of the sea surface temperature.An analysis of the relationship between recruitment, adult biomass and the environment shows that the annual recruitment of anchovy increases with turbulence intensity until wind speed reaches a value of 5.46 m s⁻¹, decreasing for higher values. For sardine, the recruitment increases with turbulence intensity until 5.63 m s⁻¹, stabilizing thereafter.It is deduced that the climatic variations associated to the El Niño events affect the abundance of coastal pelagic fishes, without forgetting the most likely effects upon its distribution and the fishing effort. However, it is the long-term variability that mainly affects the fishing activity.  相似文献