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81.
High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk 26Al‐26Mg isochron with an inferred initial 26Al/27Al ratio of approximately 5.25 × 10?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal 26Al‐26Mg isochrons consistent with the canonical value. These observations indicate that the canonical 26Al/27Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial 26Al/27Al ratios, (4.2–5.2) × 10?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial 26Al/27Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in 26Al. At least some of these refractory objects may have formed prior to injection of 26Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of 26Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial 26Al/27Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical 26Al/27Al ratio.  相似文献   
82.
The extent of the Barents-Kara Sea ice sheet (northern Europe and Russia) during the Last Glacial Maximum (LGM), in Marine Isotope Stage (MIS) 2 is controversial, especially along the southern and northeastern (Russian High Arctic) margins. We conducted a multi-disciplinary study of various organic and mineral fractions, obtaining chronologies with 14C and luminescence dating methods on a 10.5 m long core from Changeable Lake (4 km from the Vavilov Ice Cap) on Severnaya Zemlya. The numeric ages indicate that the last glaciation at this site occurred during or prior to MIS 5d-4 (Early Middle Weichselian). Deglaciation was followed by a marine transgression which affected the Changeable Lake basin. After the regression the basin dried up. In late Middle Weichselian time (ca 25–40 ka), reworked marine sediments were deposited in a saline water body. During the Late Weichselian (MIS 2), the basin was not affected by glaciation, and lacustrine sediments were formed which reflect cold and arid climate conditions. During the termination of the Pleistocene and into the Holocene, warmer and wetter climate conditions than before led to a higher sediment input. Thus, our chronology demonstrates that the northeastern margin of the LGM Barents-Kara Sea ice sheet did not reach the Changeable Lake basin. This result supports a modest model of the LGM ice sheet in northern Europe determined from numeric ice sheet modelling and geological investigations.  相似文献   
83.
84.
Wind erosion of soil is an appreciable but unstudied event following fires in cold desert. We examined aeolian transport of sediment for 1 year following fire in semi-arid shrub steppe on loess soils in southern Idaho, USA. Sediment collectors were used to determine horizontal mass transport of soil and saltation sensors and anemometers were used to determine saltation activity (fraction of time having saltation) and threshold wind speed in an area burned in August and an unburned control site. Horizontal mass transport (per 30-day period) was negligible in the unburned area, but in the burned area was 5.40 kg m?1 in October and decreased to 2.80 kg m?1 in November and 0.32 kg m?1 in December. Saltation activity was high enough to determine threshold wind speeds only in the burn site during fall, when values ranged from 10.0 to 10.6 m s?1. Sediment flux and saltation activity in the burned site became much less pronounced following the emergence of herbaceous vegetation in the spring. Post-fire sediment flux in the shrub steppe we examined was of greater magnitude but shorter duration than post-fire fluxes in warm deserts or sandier regions that experience more frequent wind erosion.  相似文献   
85.
Several methods for characterizing the occurrence and rate of nitrate attenuation were tested at a field site near Monument Valley, Arizona. Spatial and temporal nitrate concentration data collected from a transect of monitoring wells located along the plume centerline were analyzed to evaluate the overall rates of natural attenuation. The occurrence and rate of denitrification was evaluated through microcosm experiments, nitrogen isotopic fractionation analysis, and solute-transport modeling. First-order denitrification-rate coefficients calculated with each method were comparable. In addition, the composite natural attenuation rate coefficient was similar to the denitrification-rate coefficients, which suggests that microbially induced decay primarily controls nitrate attenuation at the site. This research highlights the benefits associated with a multiple-method approach for the characterization of natural attenuation.  相似文献   
86.
Abstract— Magombedze is a light-dark structured H-chondrite breccia that fell in Zimbabwe on 1990 July 2 at 15:30 GMT. White clasts are moderately shocked and have equilibrated mafic silicates (pyroxene Fs16–18, olivine Fa18–19) together with clear optically-recognizable plagioclase of variable composition (An9–13 found); chondrules are distinct but contain no trace of preserved glass. The darker surrounding material contains a higher proportion of fine-grained metal and sulfide than the white clasts, and many of its constituent grains show little evidence of shock. Mafic silicates in the dark lithology are distinctly less-equilibrated (pyroxene Fs5–21, olivine Fa11–20) than those in the white clasts, and many chondrules preserve brown devitrified glass; some metamorphic plagioclase of variable composition (An11–22, found) is present. Some monoclinic pyroxene occurs in both fractions, but it is relatively common in the dark fraction. The white clasts are classified as H5, and the enclosing dark material is H3–5.  相似文献   
87.
Abstract— Metal nodules are one of the major textural components of Kaidun sample #01.3.06 EH3-4. In terms of structure, the nodules are of three types: (1) globular, (2) zoned with a massive core and globular mantle, and (3) nodules with no internal structure. The size and composition of the globules in the nodules and grains of metal of the matrix are almost identical: no greater than 20 μm and Ni, 5.95; Si, 3.33 wt%. The nodules contain small (usually <5 μm) inclusions of SiO2; albitic glass; enstatite; roedderite; and a mixture of SiO2 and Na2S2. This is the first reported occurrence of a simple sulfide of an alkaline metal in nature. The formation of the inclusions appears to be related to condensation of material onto the surfaces of metal grains. The nodules appear to have formed by aggregation of separate grains (globules) of metal, with conservation of condensates on the grain surfaces as inclusions. The inclusions probably condensed over a significant temperature range from 1400 to 600 K. The aggregation of metal grains and formation of the nodules probably occurred simultaneously with condensation.  相似文献   
88.
89.
Hydrocarbon mixtures too complex to resolve by traditional capillary gas chromatography display gas chromatograms with dramatically rising baselines or “humps” of coeluting compounds that are termed unresolved complex mixtures (UCMs). Because the constituents of UCMs are not ordinarily identified, a large amount of geochemical information is never explored. Gas chromatograms of saturated/unsaturated hydrocarbons extracted from Late Archean argillites and greywackes of the southern Abitibi Province of Ontario, Canada contain UCMs with different appearances or “topologies” relating to the intensity and retention time of the compounds comprising the UCMs. These topologies appear to have some level of stratigraphic organization, such that samples collected at any stratigraphic formation collectively are dominated by UCMs that either elute early- (within a window of C15–C20 n-alkanes), early- to mid- (C15–C30 n-alkanes), or have a broad UCM that extends through the entire retention time of the sample (from C15–C42 n-alkanes). Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC–MS) was used to resolve the constituents forming these various UCMs. Early- to mid-eluting UCMs are dominated by configurational isomers of alkyl-substituted and non-substituted polycyclic compounds that contain up to six rings. Late eluting UCMs are composed of C36–C40 mono-, bi-, and tricyclic archaeal isoprenoid diastereomers. Broad UCMs spanning the retention time of compound elution contain nearly the same compounds observed in the early-, mid-, and late-retention time UCMs. Although the origin of the polycyclic compounds is unclear, the variations in the UCM topology appear to depend on the concentration of initial compound classes that have the potential to become isomerized. Isomerization of these constituents may have resulted from hydrothermal alteration of organic matter.  相似文献   
90.
Computational Movement Analysis focuses on the characterization of the trajectory of individuals across space and time. Various analytic techniques, including but not limited to random walks, Brownian motion models, and step selection functions have been used for modeling movement. These fall under the rubric of signal models which are divided into deterministic and stochastic models. The difficulty of applying these models to the movement of dynamic objects (e.g. animals, humans, vehicles) is that the spatiotemporal signal produced by their trajectories a complex composite that is influenced by the Geography through which they move (i.e. the network or the physiography of the terrain), their behavioral state (i.e. hungry, going to work, shopping, tourism, etc.), and their interactions with other individuals. This signal reflects multiple scales of behavior from the local choices to the global objectives that drive movement. In this research, we propose a stochastic simulation model that incorporates contextual factors (i.e. environmental conditions) that affect local choices along its movement trajectory. We show how actual global positioning systems observations can be used to parameterize movement and validate movement models and argue that incorporating context is essential in modeling movement.  相似文献   
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