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121.
Previously published dispersion fields on ternary diagrams have been constructed variously, and their derivations have not been well-specified. Here an explanation of their bases is provided through an algebraic method for calculating two related forms, designated thesilhouette dispersion field and thegirth dispersion field. Such dispersion estimates can be made more precise by specifying the percentage of samples that fall within the field. Because such fields represent a mechanistic rather than a probabilistic approach, their use in comparison of sample sets must be viewed with caution.  相似文献   
122.
Abstract— Lewis Cliff 85332 (LEW85332) is a highly unequilibrated (type 3.0–3.1) unique carbonaceous chondrite. It resembles CI and “CR” chondrites in its abundance ratios of refractory lithophiles and refractory siderophiles, but differs significantly from these groups in important ways: relative to CI chondrites, LEW85332 has low abundances of Mn, Se, Zn and most volatile siderophiles; relative to “CR” chondrites, LEW85332 has high abundance ratios of Mn and most volatile siderophiles. Although several petrologic characteristics of LEW85332 resemble those of CO chondrites, LEW85332 differs from this group in having lower abundance ratios of refractory lithophiles and higher abundance ratios of common and volatile siderophiles. Chondrules (mean diameter of 170 μm) are smaller than those in CV and CM chondrites and bigger than those in most CO chondrites. Two melilite-rich (Åk 22) fluffy type-A refractory inclusions were observed. Weathering of LEW85332 has resulted in the formation of 6.2 vol.% limonite; 3.9 vol.% metallic Fe-Ni remains. The inferred original metallic Fe-Ni abundance (13–15 wt.%) is very high for a carbonaceous chondrite and is most similar to those of Kainsaz and Colony (both CO3). LEW85332 is a breccia: the one thin section we examined contains (a) ≥ 10 primitive carbonaceous chondrite clasts (with both C1 and C2 affinities) that contain magnetite framboids and platelets, (b) two clasts containing numerous 10-μm-size clusters of troilite grains, and (c) one clast containing small needles of schreibersite embedded in fine-grained silicate matrix. The unique nature of LEW85332 underscores the wide diversity of materials produced in the solar nebula.  相似文献   
123.
A survey of depression and uplift features on Europa, based on Galileo regional mapping images, shows that these features come in a wide range of sizes, with numbers increasing greatly with decreasing size, down to the limits of resolution. Size distributions are similar in the northern leading and southern trailing hemispheres, where they are distinctly different from the southern leading and northern trailing hemispheres, suggesting an oblique, antipodal symmetry pattern, similar to that of chaotic and tectonic terrain. This pattern is suggestive of polar wander. Uplifts are usually polygonal or irregular in shape and rarely are cracked. Patches of chaotic terrain, which we had surveyed earlier, are not included in the current study because their topography is generally unclear, and because there is no a priori known genetic linkage with the pits and uplifts.These results contradict generalizations based on the earlier “pits, spots, and domes” (PSD) taxonomy. Most of the type examples for PSDs were simply patches of chaotic terrain selected from a limited portion of their full size range. The use of the term lenticula to collectively describe PSDs is inconsistent with the IAU definition of lenticula: a small dark spot seen at low resolution. Pits and uplifts do not correlate with lenticulae, although chaos often does. Properties of PSDs that have been widely cited as primary evidence for convective upwelling in thick ice (e.g., that uplifts are generally dome-shaped and often cracked; that pits and domes are regularly spaced; that there is a typical diameter of ∼10 km) were premature and not supported by subsequent data. Most pits and uplifts are less than 10 km across so, if they formed by diapirism or convective upwelling, the sources must have been very shallow, less than 5 km deep. How they actually formed remains unknown.  相似文献   
124.
Abstract— For most elements, polymict ureilite EET83309 shows no significant compositional difference from other ureilites, including ordinary (“monomict”) ureilites. Polymict ureilites appear to be mixtures of a wide variety of ordinary ureilites, with little dilution by “foreign” extra-ureilitic materials. Thus, they apparently were mixed (i.e., the ureilites in general formed) on a very small number of parent bodies. In one respect, polymict ureilites do stand out. Along with the only other polymict ureilite that has been analyzed for REE (Nilpena), EET83309 has much higher concentrations of light-middle REE than most ordinary ureilites. Despite these relative enrichments in LREE, polymict ureilites are nearly devoid of basaltic (Al-rich) material. A basaltic component should have formed along with (and presumably above) the ultramafic ureilites, in any closed-system differentiation of an originally chondritic asteroid. This scarcity of complementary basaltic materials may be an important clue to ureilite origins. We suggest that ureilites originated as paracumulates (mushy, cumulate-like, partial melt residues) deep within a primordially-heated asteroid or asteroids. While still largely molten, the asteroid was severely disrupted, and most of its external basaltic portion was permanently blown away, by impact of a large, C-rich projectile. This partially-disruptive impact tended to permeate the paracumulates with C-rich, noble-gas-rich, and 16O-rich magma derived mainly from shock-melting of the projectile. After reaccumulation and cooling, the resultant mixtures of cumulus mafic silicates with essentially “foreign” C-matrix became “monomict” ureilites. Further small impacts produced polymict ureilites as components of a newly-developed, basalt-poor megaregolith. The consistently moderate pyroxene/olivine ratios of the ureilites are as expected for partial melt residues, but not for cumulate (sensu stricto) rocks. The final projectile/target mixing ratio tended to be greatest among the more magnesian and pyroxene-rich portions of the paracumulate, because these portions were lowest in density, and thus concentrated toward the upper surface of the paracumulate layer. As a result, ureilites show correlations among C, Δ17O, and silicate-core mg. This model appears to reconcile many paradoxical aspects of ureilite composition (primitive, near-chondritic, except depleted in basalt, diverse Δ17O) and petrography (igneous, cumulate-like).  相似文献   
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127.
The concentration of selected trace metals (Cu, Pb and Zn) in salt-marsh sediments from within the Erme Estuary have been measured in order to assess possible historical sources of pollution. The Erme Estuary, south Devon, UK is an Area of Outstanding Natural Beauty and has remained largely unaffected by industrialisation, although a number of small silver–lead mines were in operation in the 1800s. Five cores reveal comparable geochemical profiles. An increase of lead at 40 cm depth is observed, reaching maximum values of 427 ppm. Less distinct trends are revealed by zinc and copper, probably reflecting the lack of widespread mining for ores of these elements within the catchment and possible post-depositional mobility rendering the metal concentrations non-contemporaneous with the chemostratigraphy of lead. The geochemical analysis of the salt-marsh sediments provides a fairly robust chemostratigraphic scheme and the likely sources of mine waste can be pinpointed within the catchment. Based upon reference to the historical mining record of these mines chemostratigraphic dating of the sediments can be achieved in order to provide an estimate of salt-marsh accretion rates and sea-level rise.  相似文献   
128.
Flach GP  Crisman SA  Molz FJ 《Ground water》2004,42(6-7):815-828
Subgrid modeling of some type is typically used to account for heterogeneity at scales below the grid scale. The single-domain model (SDM), employing field-scale dispersion, and the dual-domain model (DDM), employing local hydrodynamic dispersion and exchange between domains having large hydraulic conductivity contrasts, are well-known examples. In this paper, the two modeling approaches are applied to tritium migration from the H-area seepage basins to a nearby stream--Fourmile Branch--at the Savannah River Site. This location has been monitored since 1955, so an extensive dataset exists for formulating realistic simulations and comparing the results to data. It is concluded that the main parameters of both models are scale-dependent, and methods are discussed for making initial estimates of the DDM parameters, which include mobile/immobile porosities and the mass exchange coefficient. Both models were calibrated to produce the best fit to recorded tritium data. When various attributes of the dataset were considered, including cumulative tritium activity discharged to Fourmile Branch, plume arrival time, and plume attenuation due to closure of the seepage basins in 1988, the DDM produced results superior to the SDM, while causing no unrealistic upgradient dispersion. A sensitivity analysis showed that only the DDM was able to accurately produce both the instantaneous activity discharge and cumulative activity with a single parameter set. This is thought to be due to the advection-dominated nature of transport in natural porous media and the more realistic treatment of this type of transport in the DDM relative to the SDM.  相似文献   
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130.
In this study we explore the idea that coronae have formed on Venus as a result of gravitational (Rayleigh-Taylor) instability of the lithosphere. The lithosphere is represented by a system of stratified homogeneous viscous layers (low-density crust over high density mantle, over lower density layer beneath the lithosphere). A small harmonic perturbation imposed on the base of the lithosphere is observed to result in gravitational instability under the constraint of assumed axisymmetry. Topography develops with time under the influence of dynamic stress associated with downwelling or upwelling, and spatially variable crustal thickening or thinning. Topography may therefore be elevated or depressed above a mantle downwelling, but the computed gravity anomaly is always negative above a mantle downwelling in a homogeneous asthenosphere. The ratio of peak gravity to topography anomaly depends primarily on the ratio of crust to lithospheric viscosity. Average observed ratios are well resolved for two groups of coronae (∼40 mgal km−1), consistent with models in which the crust is perhaps 5 times stronger than the lithosphere. Group 3a (rim surrounding elevated central region) coronae are inferred to arise from a central upwelling model, whereas Group 8 (depression) coronae are inferred to arise from central downwelling. Observed average coronae radii are consistent with a lithospheric thickness of only 50 km. An upper low-density crustal layer is 10-20 km thick, as inferred from the amplitude of gravity and topography anomalies.  相似文献   
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