Particulate matter geochemistry of a highly industrialized region in the Caribbean:Basis for future toxicological studies     

Luis F.O.Silva  Ismael L.Schneider  Paulo Artaxo  Yuleisy Núñez-Blanco  Diana Pinto  Érico M.M.Flores  Leandro Gómez-Plata  Omar Ramírez  Guilherme L.Dotto 《地学前缘(英文版)》2022,(1):376-387

Air pollution has become an important issue,especially in Caribbean urban areas,and,particulate matter(PM)emitted by different natural and anthropogenic sources causes environmental and health issues.In this work,we studied the concentrations of PM₁₀ and PM_2.5 sources in an industrial and port urban area in the Caribbean region of Colombia.PM samples were collected within 48-h periods between April and October 2018 by using a Partisol 2000 i-D sampler.Elemental geochemical characterization was performed by X-ray fluorescence(XRF)analysis.Further,ionic species and black carbon(BC)were quantified by ion chromatography and reflectance spectroscopy,respectively.Using the Positive Matrix Factorization(PMF)receptor model,the contributions of PM sources were quantified.The average concentration of PM₁₀ was 46.6±16.2μg/m³,with high concentrations of Cl and Ca.For PM_2.5,the average concentration was 12.0±3.2μg/m³,and the most abundant components were BC,S,and Cl.The receptor model identified five sources for PM₁₀ and PM_2.5.For both fractions,the contributions of marine sea spray,re-suspended soil,and vehicular traffic were observed.In addition,PM_2.5 included two mixed sources were found to be fuel oil combustion with fertilizer industry emissions,and secondary aerosol sources with building construction emissions.Further,PM₁₀ was found to also include building construction emissions with re-suspended soil,and metallurgical industry emissions.These obtained geochemical atmospheric results are important for the implementation of strategies for the continuous improvement of the air quality of the Caribbean region.  相似文献   

Antioxidant and biotransformation responses in Liza aurata under environmental mercury exposure - relationship with mercury accumulation and implications for public health     

Guilherme S  Válega M  Pereira ME  Santos MA  Pacheco M 《Marine pollution bulletin》2008,56(5):845-859

This study was carried out in the Laranjo basin (Ria de Aveiro, Portugal), an area impacted by mercury discharges. Liza aurata oxidative stress and biotransformation responses were assessed in the liver and related to total mercury (Hg_t) concentrations. A seasonal fish survey revealed a sporadic increase in total glutathione (GSH_t) and elevated muscle Hg_t levels, although Hg levels did not exceed the EU regulatory limit. As a complement study, fish were caged for three days both close to the bottom and on the water surface at three locations, and displayed higher Hg_t levels accompanied by increased GSH_t content and catalase activity as well as EROD activity inhibition. The bottom group displayed higher hepatic Hg_t and GSH_t contents compared with the surface group. Globally, both wild and caged fish revealed that the liver accumulates higher Hg_t concentrations than muscle and, thus, better reflects environmental contamination levels. The absence of peroxidative damage in the liver can be attributed to effective detoxification and antioxidant defense.  相似文献   

Layered clouds in the Indian monsoon region     

M. K. Rama Varma Raja  G. C. Asnani  P. S. Salvekar  A. R. Jain  D. Narayana Rao  S. Venkoba Rao  P. Kishore  M. Hareesh 《Journal of Earth System Science》1999,108(4):287-295

Contrary to the prevalent belief that tropical region is characterized by convective clouds rather than by layer clouds, we have suggested that deep convective clouds occur on meso-scale, but layer clouds occur on larger synoptic-scale with a relatively small region of deep convective clouds. Sustenance of deep convective clouds is inhibited by the presence of inertio-gravity waves, which have alternating layers of upward and downward motion in the vertical. We have also shown that inertio-gravity waves generate regions of relatively strong horizontal velocity, vertically separated by layers of relatively weak horizontal velocity. Layers of strong horizontal velocity are created by inertio-gravity wave system through convergence of vertical flux of horizontal momentum. We have also suggested that horizontal convergence/divergence of moisture flux is generated by inertio-gravity waves, giving rise to vertically alternating layers of high/low humidity, and visible or sub-visible clouds. Layers of high humidity become layers of strong radar reflectivity at frequency of 53 MHz at which MST Radar at Gadanki, near Tirupati, India, operates. These observations, more than 2,50,000 in number, for vertical grid points, spread over all the months of the year, have helped us, among other observations, to arrive at these conclusions. Further, the analysis suggests that the main source of strong MST radar reflectivity is not mechanical turbulence as is commonly believed.  相似文献   

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 1: Principles,procedures, and evaluation of the method     

Guilherme?A.?R.?GualdaEmail author  Mark?S.?Ghiorso 《Contributions to Mineralogy and Petrology》2014,168(1):1033

Constraining the pressure of crystallization of magmas is an important but elusive task. In this work, we present a method to derive crystallization pressures for rocks that preserve glass compositions (either glass inclusions or matrix glass) representative of equilibration between melt, quartz, and 1 or 2 feldspars. The method relies on the well-known shift of the quartz–feldspar saturation surface toward higher normative quartz melt compositions with decreasing pressure. The critical realization for development of the method is the fact that melt, quartz and feldspars need to be in equilibrium at the liquidus for the melt composition. The method thus consists of calculating the saturation surfaces for quartz and feldspars using rhyolite-MELTS over a range of pressures, and searching for the pressure at which the expected assemblage (quartz+1 feldspar or quartz+2 feldspars) is found at the liquidus. We evaluate errors resulting from uncertainties in glass composition using a series of Monte Carlo simulations for a quartz-hosted glass inclusion composition from the Bishop Tuff, which reveal errors on the order of 20–45 MPa for the quartz+2 feldspars constraint and on the order of 25–100 MPa for the quartz+1 feldspar constraint; we suggest actual errors are closer to the lower bounds of these ranges. We investigate the effect of fluid saturation in two ways: (1) By applying our procedure over a range of water contents for three glass compositions; we show that the effect of fluid saturation is more important at higher pressures (~300 MPa) than at lower pressures (~100 MPa), but reasonable pressure estimates can be derived irrespective of fluid saturation for geologically relevant H₂O concentrations >3 wt% and (2) by performing the same type of pressure determinations with a preliminary version of rhyolite-MELTS that includes a H₂O–CO₂ mixed fluid phase; we use a range of H₂O and CO₂ concentrations for two compositions characteristic of early-erupted and late-erupted Bishop Tuff glass inclusions and demonstrate that calculated pressures are largely independent of CO₂ concentration (for CO₂ <1,000 ppm), at least for relatively high H₂O contents, as expected in most natural magmas, such that CO₂ concentration can be effectively neglected for application of our method. Finally, we demonstrate that pressures calculated using the rhyolite-MELTS geobarometer compare well with those resulting from H₂O–CO₂ glass inclusion barometry and Al-in-hornblende barometry for an array of natural systems for which data have been compiled from the literature; the agreement is best for quartz-hosted glass inclusions, while matrix glass yields systematically lower rhyolite-MELTS pressures, suggestive of melt evolution during eruptive decompression.  相似文献   

Controls on carbon cycling in two contrasting temperate zone estuaries: The Tyne and Tweed, UK     

Jason M.E. Ahad  Johannes A.C. Barth  Raja S. Ganeshram  Robert G.M. Spencer  Günther Uher 《Estuarine, Coastal and Shelf Science》2008,78(4):685-693

In order to evaluate the respiration–photosynthesis dynamics in two contrasting North Sea estuaries, pH, temperature, alkalinity, chlorophyll-a (chl-a), and isotopic ratios of dissolved inorganic carbon (δ¹³C_DIC) and dissolved oxygen (δ¹⁸O_DO) were measured in the Tyne (July 2003) and Tweed (July 2003 and December 2003) estuaries. Using a concentration-dependent isotope mixing line, δ¹³C_DIC values in the Tweed (July 2003) demonstrated mostly conservative behaviour across the estuary, reflecting mixing between riverine and marine sources, although some samples were slightly more ¹³C-enriched than predicted δ¹³C_DIC values. Low pCO₂ (less than 2 times atmospheric pressure) and ¹⁸O-depleted δ¹⁸O_DO signatures below equilibrium with the atmosphere provided further evidence for net autotrophy in the Tweed estuary in summer 2003. Conversely, in the Tyne during the summer and in the Tweed during the winter higher pCO₂ (up to 6.5 and 14.4 times atmospheric partial pressure in the Tweed and Tyne, respectively), slightly ¹³C-depleted δ¹³C_DIC and ¹⁸O-enriched δ¹⁸O_DO values indicated heterotrophy as the dominant process. The relatively large releases of CO₂ observed during these two estuarine surveys can be attributed to significant oxidation of terrigenous organic matter (OM). This study therefore demonstrates the usefulness of combined δ¹⁸O_DO and δ¹³C_DIC isotopes in examining the relationship between respiration–photosynthesis dynamics and the fate of terrestrially derived OM during estuarine mixing.  相似文献   

Anthropogenic impact on Andaman coast monitoring with benthic foraminifera,Andaman Sea,India     

N. Jayaraju  B. C. Sundara Raja Reddy  K. R. Reddy 《Environmental Earth Sciences》2011,62(4):821-829

The concept of anthropogenic impact is extremely important to be considered while analysing the ecology of coast and shelf zones. For centuries, these zones have been the epicentres for various human activities, including urbanisation, construction of sea ports and harbours, development of natural reservoirs (including oil production and fishing), marine aquaculture, shipping, recreation and many others. Many of the activities in progress on both sides of the shoreline provide 50% or more of the gross State/UT (Union Tertiary) product for surrounding states. The data shows that land-based and atmospheric sources account for about two-thirds of the total contamination found in the marine environment, constituting 44 and 33%, respectively. The greatest anthropogenic pollution pressure undoubtedly falls on the shelf zones and coastal areas. To prove this theory, a total of 25 bottom sediment samples were collected within the depth zone of 5 fathoms from the South Andaman coastal fringe for sediment geochemistry studies and foraminiferal analysis. The samples were further analysed for heavy metal pollutants like Co, Cu, Mn, Pb and Zn. The study yielded 20 benthic foraminiferal species. Of these, five benthic species were living including Ammonia beccarii, Calcarine calcar, Elphidium crispum, Operculina complanata and Nonion deppresula. The presence of deformed specimens and the domination of Ammonia spp. are indications of a polluted environment. Sampled coral reefs had high abundances of Operculina spp. The highest counts of benthic microbiota were found in finer sediment. Species diversity is very limited along the coastal fringe of South Andaman Island in comparison with fauna from the coast of India. This first report of benthic foraminifera from South Andaman Island will allow us to assess future impacts of marine pollution because foraminiferal deformations are positively correlated to the concentrations of heavy metals (Cr, Cu, Mn, Pb and Zn).  相似文献   

Hyperspectral satellite data (Hyperion) preprocessing—a case study on banded magnetite quartzite in Godumalai Hill, Salem, Tamil Nadu, India     

B. Poovalinga Ganesh  S. Aravindan  S. Raja  A. Thirunavukkarasu 《Arabian Journal of Geosciences》2013,6(9):3249-3256

This paper deals with many calibration methods involved in preprocessing of hyperspectral remote sensing data, while radiation calibration with respect to magnetite minerals without altering image reflectance. Radiometric calibration is the basis and important for both hyperspectral data applications and quantitative remote sensing. While at present there are many methods available for radiometric calibration in the spaceborne hyperspectral data, here, we used the highest spectral resolution Hyperion EO-1 satellite data using a variety of calibration models, which include the calibration model based on atmospheric radiation theory, conversion model as scene dependent such as flat field model, internal average reflectance model, logs residual modified model, and linear model based on the experience of the ground calibration, and so on, and hyperspectral data calibration study was implemented with magnetite mineral. After the above three models contrast, we have arrived at the conclusion that calibration model based on atmospheric radiation theory is the finest radiation calibration method for Hyperion satellite data preprocessing.  相似文献   

Wavelet Based Post Classification Change Detection Technique for Urban Growth Monitoring     

R. A. Alagu Raja  V. Anand  A. Senthil Kumar  Sandeep Maithani  V. Abhai Kumar 《Journal of the Indian Society of Remote Sensing》2013,41(1):35-43

Urban areas are the most dynamic region on earth. Their size has been constantly increased during the past and this process will go on in the future. Since there is no standard policy and guidelines for construction of buildings and urban planning, cities tend to have irregular growth. Many cities in the world face the problem of urban sprawl in its suburbs. So issues of urban sprawl need to be settled with the help of technologies such as satellite remote sensing and automated change detection. This paper presents a wavelet based post classification change detection technique that is applied to 1996 and 2004 MSS images of Madurai City, South India to determine the urban growth. The classification stage of the technique uses coilflet wavelet filter to correlate with the MSS land cover images of Madurai city to derive texture feature vector and this feature vector is inputted to a fuzzy-c means classifier, an unsupervised classification procedure. The post classification change detection technique is employed for identifying the newly developed urban fringe of the study area. The error matrix analysis is used to assess the accuracy of the change map. The performance of the presented technique is found superior than that of classical change detection methods such as image differencing, change vector analysis and principal component analysis.  相似文献   

Why do certain species dominate? What we can learn from a rare case of Microdictyon dominance on a Caribbean reef     

Claire L. A. Dell  Guilherme O. Longo  Carrie Manfrino  Deron E. Burkepile 《Marine Ecology》2020,41(5):e12613

Many Caribbean reefs have shifted from coral dominance to macroalgal dominance, often by brown algae such as Dictyota and Lobophora. However, the north side of Cayman Brac in the Cayman Islands is dominated seasonally by the green macroalga Microdictyon (percent cover of Microdictyon is 4% in the winter and ~40% of the reef in the summer), although it is absent from the south side of the island and the remainder of the country. Indeed, Microdictyon is rare in much of the Caribbean, so this situation on Cayman Brac provides an opportunity to investigate the conditions that facilitate its distribution and dominance. The impact of herbivory, competition, nutrient input and other abiotic conditions were examined as factors that could influence the distribution and dominance of Microdictyon. While herbivory or nutrient input are frequently found to be key drivers of benthic community composition on coral reefs, here consumption of Microdictyon by herbivores was low, and thus, the alga was not subject to strong top-down control by herbivory. So, in this case, neither herbivore abundance nor feeding preference appeared to influence the distribution of Microdictyon. Nutrient input was also similar to both sides of the island suggesting nutrients played little role in differential distribution. But, in a controlled transplant experiment where Microdictyon was protected from herbivory and competition, it experienced almost complete mortality (93.3%) when transplanted to the south side, compared to only 11.8% mortality on the north. The south side was exposed to the strongest wave action 92% of the days in our study and was on average a slight, but significant 0.2°C warmer. Thus, these data suggest physical forcing (i.e. wave exposure) is the most likely factor dictating Microdictyon distribution. Conversely, a combination of reduced herbivory and increased competitive strength may explain the seasonal dominance of Microdictyon on the north side of Cayman Brac. Microdictyon was a competitive inferior to the other common algae in winter but increased in competitive strength to equal other species in summer. These results add to the literature on Microdictyon and on the forces impacting benthic community structure of coral reefs.  相似文献   

Mitigation of Iron Toxicity and Iron,Zinc, and Manganese Nutrition of Wetland Rice Cultivars (Oryza sativa L.) Grown in Iron‐Toxic Soil          下载免费PDF全文

Mohammad Shahid  Amaresh Kumar Nayak  Arvind Kumar Shukla  Rahul Tripathi  Anjani Kumar  Rajagounder Raja  Bipin Bihari Panda  Jitendriya Meher  Pratap Bhattacharyya  Debiprasad Dash 《洁净——土壤、空气、水》2014,42(11):1604-1609

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