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The use of macrofossil soil charcoal as a palaeoecological tool to reconstruct past vegetation, climate or fire history has gained much interest in recent years. Yet little is known about taphonomy of charcoal in soils. Here we assessed the putative loss of palaeoecological information due to charcoal fragmentation after burial. We found no significant loss of charcoal mass with time. Instead, we found a significant positive relationship between the mass of charcoal particles and their age. Permineralization of charcoal particles older than ca. 5200 a explained the increased charcoal mass with time in mineral soils. The permineralization process increased the density of charcoal particles (resulting in a twofold particles mass increase) and thus offers a protection against subsequent degradation. Our results suggest high stability of palaeoecological information from charcoal macrofossils buried in mineral soils at least over the Holocene timescale. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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The present study is to explore the feasibility of GRACE-based estimation of a groundwater storage change in a data-poor region using a case study of the Ngadda catchment in the Lake Chad Basin. Although the Ngadda catchment has only one set of in situ time series data of groundwater from 2006 to 2009 and a limited number of groundwater measurements in 2005 and 2009, GRACE-based groundwater storage change can be evaluated against the in situ groundwater measurements combined with specific yield data. The cross-correlation analysis in the Ngadda catchment shows that maximum rainfall reached in July and August, whereas both the maximum total water storage anomaly and the maximum groundwater storage anomaly occurred 2months later. Whereas the mean annual amplitude of total water storage anomaly is about 17cm from both the average total water storage anomaly from three mascon products and the one from three spherical harmonic products, the mean annual amplitude of soil moisture storage anomaly is substantially varied from 5.58cm for CLM to about 14cm for NOAH and Mosaic. The goodness-of-fit tests show that CLM soil moisture produces the closest estimation of groundwater storage anomaly to the in situ groundwater measurements. The present study shows that GRACE-based estimation for groundwater storage anomaly can be a cost-effective and alternative tool to observe how groundwater changes in a basin scale under the limitation of modelling and in situ data availability.  相似文献   
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Sediment detention basins are implemented on mountain rivers to trap solid material that may aggravate the flooding of downstream settlements.However,retention structures built in the past may unnecessarily retain sediment during non-hazardous flood events,resulting in high maintenance costs and sediment deficit downstream.In addition,the so-called spontaneous self-flushing of previously retained sediment during floods has occasionally been observed.Recent research suggests to design sediment detention basins for controlling sediment passage with a guiding channel across the deposition area upstream of a hybrid barrier.Such barriers consist of a check dam with a slot orifice and an upstream bar screen with a bottom clearance in order to benefit from a combined mechanical-hydraulic retention control.The present paper enhances this pioneering research with the help of new experimental data,including a wide range of sediment mixtures and large wood,as well as variable barrier heights.Improved design criteria are provided regarding the bar screen and the basin storage capacity.The functionality of the enhanced concept for sediment detention is illustrated by a case study on a physical model:the protection of the Villard-Bonnot village(France)against torrential hazards.  相似文献   
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A series of hematite structures containing various amounts of aluminum and hydroxyl groups was modeled using first-principles methods based on the density functional theory. Evolution of the lattice parameters was quantified as a function of Al and H concentrations. The a and c lattice parameters decrease with the aluminum content and increase with the water content. This allows explaining experimental data reported for synthetic hematites, in particular the observed deviation from the Vegard’s rule. Investigation of several hydroxyl configurations associated with cationic vacancies suggests that the speciation of water also significantly affects the hematite structure. The 57Fe and 18O reduced partition functions (β-factor) were determined. Results show a linear dependence of the iron and oxygen β-factors on the aluminum content. An incorporation of 18 mole % Al2O3 in hematite would increase the iron β-factor of about 0.6‰ and the oxygen β-factor of about 5.5‰ at 0 °C. This effect is sufficiently large to be measurable and to affect the interpretation of natural isotopic compositions. On the other hand, the effect of water is found to be negligible for the hydroxyl configuration investigated.  相似文献   
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The Central Plateau Member rhyolites have been erupted between 173 and 70 ka and are the youngest Yellowstone intracaldera rhyolites. They mostly comprise very voluminous lava flows totaling ~600 km3 in volume. Their eruptive vents define two NNW-trending lineaments which are aligned with regional faults. We present new whole rock, glass, and mineral analyses and propose a petrogenetic and volcano-tectonic model for these rhyolites. At a caldera-wide scale, there is a temporal enrichment in elements such as Nb, Y and HREE, and a depletion in Sr, Ba, and Ce/Yb. Simultaneously, clinopyroxene becomes less magnesian while Ti contents in quartz decrease. By contrast, quartz in all rhyolites is rounded and bears long glass re-entrants, suggesting heating. Based on these data and observations, we propose that the Central Plateau Member rhyolites have been generated as follows. A hydrothermally altered low-δ18O rhyolitic protolith beneath the Mallard Lake Resurgent Dome in the southwestern part of the caldera started to melt at ~250 ka. Repeated heating pulses caused the melting front to expand radially, and a large crystal mush formed beneath much of the caldera. The mush was able to differentiate but not erupt due to its high crystallinity and viscosity. Further inputs of heat and silicic magma in this mush increased the degree of melting, forming crystal-poor magma batches which erupted a few hundred to a few thousand years later through regional faults to form the Central Plateau Member rhyolites.  相似文献   
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3D structural modeling is a major instrument in geosciences, e.g. for the assessment of groundwater and energy resources or nuclear waste underground storage. Fault network modeling is a particularly crucial step during this task, for faults compartmentalize rock units and plays a key role in subsurface flow, whether faults are sealing barriers or drains. Whereas most structural uncertainty modeling techniques only allow for geometrical changes and keep the topology fixed, we propose a new method for creating realistic stochastic fault networks with different topologies. The idea is to combine an implicit representation of geological surfaces which provides new perspectives for handling topological changes with a stochastic binary tree to represent the spatial regions. Each node of the tree is a fault, separating the space in two fault blocks. Changes in this binary tree modify the fault relations and therefore the topology of the model.  相似文献   
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The geometry of extensional structures is described for the first time in the active setting of the Venezuelan Andes using remote sensing imagery. We favored the use of a mosaic of Synthetic Aperture Radar (SAR) scenes of the Japanese Earth Resources Satellite-1 (JERS-1) assisted by complementary remote sensing devices (Landsat TM, digital elevation models) and field observations to make a structural analysis at regional scale. Radar images are particularly efficient in the Venezuelan Andes where dense vegetation and frequent cloud covering earlier lent difficulties to remote sensing studies. We focused our analysis in the Valera–Rio Momboy and Bocono faults corner and in the Mucujun area. We show that, in an area where ongoing compression and strike–slip deformations occur, brittle extension can be detected independently from previous knowledge. Extensional structures correspond to elongated tilted blocks with dimension less than 10 km in width. Blocks are bounded by curved faults in plan view, the concavity being turned towards the axial part of the belt. The geometry and kinematics of such structures suggest that syn-orogenic extension started together with initiation of right-lateral strike–slip motion along the Bocono Fault in the Plio-Quaternary.  相似文献   
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