Thaumasite from the Tschwinning mine,South Africa     

O. Grubessi  A. Mottana  E. Paris 《Mineralogy and Petrology》1986,35(3):149-156

Summary Thaumasite from the manganese mine of Tschwinning, South Africa, has the formula Ca_3.097 Si_1.062OH_6.372(CO₃)_0.994(SO₄)_1.000·11.596 H₂O. Unit cell parameters (a=11.013(2) Å,c=10.379(5) Å,V=1090.1(6) ų) and refraction indices (n_e=1.458(2),n _o=1.498(2)) compare well with the best ones available in the literature. The IR spectrum and DT-TG profiles are given. Contradictions between the IR spectrum, a recent structural refinement and the DT-TG are discussed, but cannot be explained satisfactorily.

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Thaumasit aus der Mangan-Mine von Tschwinning, Süd-Afrika

Zusammenfassung Thaumasit aus der Mangan-Mine von Tschwinning, Süd-Afrika, besitzt die Formel Ca_3.097 Si_1.062OH_6.372(CO₃)_0.994(SO₄)_1.000·11.596 H₂O. Die Parameter der Elementarzelle (a=11.013(2) Å,c=10.379(5) Å,V=1090.1(6) ų) und die Brechungsindizes (n _e=1.458(2),n _o=1.498(2)) zeigen gute Übereinstimmung mit verfügbaren Literaturdaten. Es werden ein IR-Spektrum und DT-TG-Profile präsentiert. Gegensätze zwischen dem IR-Spektrum, einer neueren Strukturverfeinerung und dem DT-TG werden diskutiert, können jedoch nicht zufriedenstellend erklärt werden.

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With 2 Figures  相似文献   

Slab dehydration and fluid migration at the base of the upper mantle: implications for deep earthquake mechanisms     

Guillaume Richard  Marc Monnereau  Michel Rabinowicz 《Geophysical Journal International》2007,168(3):1291-1304

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Une dépression piézométrique naturelle en hausse au Sahel (Sud-Ouest du Niger)A rising piezometric depression in the Sahel (southwestern Niger)     

Guillaume Favreau  Christian Leduc  Christelle Marlin  Abdou Guéro 《Comptes Rendus Geoscience》2002,334(6):395-401

In southwest Niger, the Continental Terminal water table displays a natural hollow shape about 10 m in depth over an area of 4000 km². A 10-year survey of this hollow aquifer has shown that current recharge is above $\text{20 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. The water table has risen continuously since the 1950–1960s as a result of land clearance. This shows a disequilibrium in the aquifer balance. The long-term recharge rate is estimated by radioisotopes to be around $\text{1 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. This figure fits with the only possible origin of the piezometric depression, i.e. evapotranspiration losses in its centre. To cite this article: G. Favreau et al., C. R. Geoscience 334 (2002) 395–401.  相似文献   

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献   

La ligne du Tonale (Alpes centrales et orientales): sens de décrochement et prolongements     

Andre Guillaume 《Tectonophysics》1978,48(1-2)

This work discusses the state of knowledge (mainly tectonic and geophysical data) about the Tonale line and other “peri-Adriatic” lines in the Central and Eastern Alps. The chain is here cut into a mosaic of independent blocs, separated by faults with basic injections in some places. The Tonale fault had a dextral movement in Oligo-Miocene times; it is connected with the Austrian “Thermenlinie”, and not to the Pusteria—Gail line. An attempt at chronology is presented.

Résumé

Ce travail fait le point des connassiances, principalement tectoniques et géophysiques, sur la linge du Tonale et les accidents “péri-adriatiques” récents des Alpes centrales et Orientales. Dans cette région, la chaine est découpée en une mosaïque de blocs indépendants, séparés par des accidents injectés ça et là de masses basiques. L'accident du Tonale, Qui a joué en décrochement dextre à l'Oligo-Miocéne, est relié à la Thermenlinie d'Autriche Et non à la linge Pusteria—Gail. Un essai de chronologie est présenté.  相似文献   

Do paleoclimate proxies agree? A test comparing 19 late Holocene climate and sea‐ice reconstructions from Icelandic marine and lake sediments     

Yarrow Axford  Camilla S. Andresen  John T. Andrews  Simon T. Belt  Áslaug Geirsdóttir  Guillaume Massé  Gifford H. Miller  Sædís Ólafsdóttir  Lindsay L. Vare 《第四纪科学杂志》2011,26(6):645-656

Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP₂₅, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Mobility of metals in nickel mine spoil materials     

Sophie Raous  Thierry Becquer  Jérémie Garnier  Éder de Souza Martins  Guillaume Echevarria  Thibault Sterckeman 《Applied Geochemistry》2010

An understanding of the biogeochemical behaviour of metals in mine spoil materials is a prerequisite to rehabilitate Ni mining sites. The objective of this study was to characterize the fate of metals in different Ni ore spoil materials as influenced by hydrological conditions and fertilisation practices. In tropical ultramafic complexes, the different stages of lateritic weathering lead to two types of ores, and therefore, to two spoil types. They are mainly either a clay-rich saprolite, so-called “garnierite”, enriched in phyllosilicates, or a limonitic material, enriched in Fe oxides. Lysimeter columns were designed to monitor leaching waters through both spoil materials. The garnieritic spoil released higher concentrations of Mg (mean = 2.25 mg L⁻¹), Ni (0.39 mg L⁻¹) and Cr (1.19 mg L⁻¹) than the limonitic spoil (Mg = 0.5 mg L⁻¹; Ni = 0.03 mg L⁻¹ and Cr = 0.25 mg L⁻¹). Chromium was mainly in an anionic form in leaching solutions. As exchangeable pools of Cr(VI) in limonite (980 mg kg⁻¹ of KH₂PO₄-extractable Cr) are considerable its release in water may still occur in the case of a pH increase. In mixed spoil, metal concentrations were almost as low as in the limonitic one. The effect of mineral-N fertilisation was a strong release of cations (Ni, Mg) into the leachate. Phosphate amendment did not affect the soil solution composition under experimental conditions.  相似文献   

Deep reflection seismic imaging of the internal zone of the South Armorican Hercynian belt (western France) (ARMOR 2/Géofrance 3D Program)     

Adnand Bitri  Jean-Pierre Brun  Denis Gapais  Florence Cagnard  Charles Gumiaux  Jean Chantraine  Guillaume Martelet  Catherine Truffert 《Comptes Rendus Geoscience》2010,342(6):448-452

We present results and interpretation of a 72 km long deep seismic reflection profile acquired across the internal zone of the Hercynian belt of South Brittany. The profile is of excellent quality, most of the crust being highly reflective. The “ARMOR 2 South” profile, is correlated with the “ARMOR 2 North” profile that was published in 2003. Correlation of the main subsurface reflections with surface geological and structural data provides important information about the crustal structure that resulted from thickening during Late Devonian and regional-scale extension during Late Carboniferous. In particular, seismics image shows a very high reflectivity zone, lying flat over more than 40 km at about 10–12 km depth. This zone is interpreted as a major zone of ductile crustal thinning.  相似文献   

Towards Stochastic Time-Varying Geological Modeling   总被引：3，自引：1，他引：2  

Guillaume Caumon 《Mathematical Geosciences》2010,42(5):555-569

The modeling of subsurface geometry and properties is a key element to understand Earth processes and manage natural hazards and resources. In this paper, we suggest this field should evolve beyond pure data fitting approaches by integrating geological concepts to constrain interpretations or test their consistency. This process necessarily calls for adding the time dimension to 3D modeling, both at the geological and human time scales. Also, instead of striving for one single best model, it is appropriate to generate several possible subsurface models in order to convey a quantitative sense of uncertainty. Depending on the modeling objective (e.g., quantification of natural resources, production forecast), this population of models can be ranked. Inverse theory then provides a framework to validate (or rather invalidate) models which are not compatible with certain types of observations. We review recent methods to better achieve both stochastic and time-varying geomodeling and advocate that the application of inversion should rely not only on random field models, but also on geological concepts and parameters.  相似文献   

Accounting for uncertainties and time preference in economic analysis of tackling climate change through forestry and selected policy implications for Scotland and Ukraine     

Maria Nijnik  Guillaume Pajot 《Climatic change》2014,124(3):677-690

The paper discusses the development of economic techniques for dealing with uncertainties in economic analysis of planting trees to mitigate climatic change. In consideration of uncertainty, time preference and intergenerational equity, the traditional cost-benefit analysis framework is challenged with regard to the discounting/non-discounting of carbon uptake benefits, and because it usually uses a constant and positive discount rate. We investigate the influence of various discounting protocols on the outputs of economic analysis. The idea of using the declining discount rate is also considered. Several numerical examples dealing with the analysis of afforestation for carbon sequestration in Scotland and Ukraine are provided. We show that the choice of discounting protocols have a considerable influence on the results of economic analysis, and therefore, on the decision-making processes related to climate change mitigation strategies. The paper concludes with some innovative insights on accounting for uncertainties and time preference in tackling climate change through forestry, several climate policy implications of dealing with uncertainties, and a brief discussion of what the use of different discounting protocols might imply for decision making.  相似文献