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11.
We present here in situ measurements obtained between 1991 and 2011 in outer-vortex conditions by the ELHYSA balloon-borne frost-point hygrometer. The frost-point hygrometer profiles are used for comparisons with the satellite data from version 19 (v19) and version 3.3 (v3.3) of the HALogen Occultation Experiment (HALOE) and the Microwave Limb Sounder (MLS) respectively. Potential Vorticity mapping is applied to all data sets to remove contributions of transient tropical intrusions and polar vortex air masses and hence ensure consistent comparisons between the balloon and satellite observations. Our selected balloon in situ observations are too sparse to directly infer mid-latitude stratospheric time series for continuous comparisons with HALOE and MLS records or derive water vapour trends but can be used to validate the satellite data. A mean difference of ?0.83?±?1.58 % (?0.04?±?0.07 ppmv) is obtained between HALOE v19 data and the balloon frost-point observations (with respect to HALOE) over the 30–80 hPa altitude range. The hygrometer-HALOE differences appear time-dependent as already presented in the literature. The mean difference reaches 2.80?±?0.96 % (0.13?±?0.04 ppmv) for MLS v3.3, with MLS systematically wetter than the balloon data reflecting a systematic bias between both datasets. We use our balloon data as reference to provide some information about the HALOE-MLS difference. From post-2000 ELHYSA-HALOE and ELHYSA-MLS comparisons, we find a HALOE-MLS difference matching the expected bias, with MLS v3.3 6.60?±?2.80 % (0.27?±?0.11 ppmv) wetter than HALOE v19. From the results obtained from our balloon-satellite data comparisons, we finally discuss the issue about merging the HALOE and MLS data sets to provide stratospheric water vapour trends.  相似文献   
12.
We revisit the rotation dynamics of a rigid satellite with either a liquid core or a global subsurface ocean. In both problems, the flow of the fluid component is assumed inviscid. The study of a hollow satellite with a liquid core is based on the Poincaré–Hough model which provides exact equations of motion. We introduce an approximation when the ellipticity of the cavity is low. This simplification allows to model both types of satellite in the same manner. The analysis of their rotation is done in a non-canonical Hamiltonian formalism closely related to Poincaré’s “forme nouvelle des équations de la mécanique”. In the case of a satellite with a global ocean, we obtain a seven-degree-of-freedom system. Six of them account for the motion of the two rigid components, and the last one is associated with the fluid layer. We apply our model to Titan for which the origin of the obliquity is still a debated question. We show that the observed value is compatible with Titan slightly departing from the hydrostatic equilibrium and being in a Cassini equilibrium state.  相似文献   
13.
The main objective of this study is to investigate the distribution of rare earth elements (REEs) in Lolium perenne L. plant species which has been grown on vineyard soils treated with pesticide commonly used in the study area. These plants have been grown on two types of soils: (1) brown calcareous soils developed on loess and (2) brown to calcic brown soils developed on conglomerates. The significant correlation observed between the concentrations of phosphorus and the total amount of REEs, in addition to the enrichment in middle REEs (MREEs), suggests the complexation of REEs with phosphates and organic matter. The soils were enriched in REEs due to pesticide application but the plants were depleted. The ratio of REEs in plant over REEs in soil before application of pesticides is higher than that after application of pesticides. Application of pesticides to crops did not affect the fractionation of REEs neither in leaves nor in roots. No selectivity in uptake of REEs occurred because of pesticides except for Ce and Eu which show a negative anomaly relative to the other REEs.  相似文献   
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