Ultramafic Xenoliths from the Bearpaw Mountains, Montana, USA: Evidence for Multiple Metasomatic Events in the Lithospheric Mantle beneath the Wyoming Craton   总被引：6，自引：1，他引：6  

DOWNES  HILARY; MACDONALD  RAY; UPTON  BRIAN G. J.; COX  KEITH G.; BODINIER  JEAN-LOUIS; MASON  PAUL R. D.; JAMES  DODIE; HILL  PETER G.; HEARN  B. CARTER  JR 《Journal of Petrology》2004,45(8):1631-1662

Ultramafic xenoliths in Eocene minettes of the Bearpaw Mountainsvolcanic field (Montana, USA), derived from the lower lithosphereof the Wyoming craton, can be divided based on textural criteriainto tectonite and cumulate groups. The tectonites consist ofstrongly depleted spinel lherzolites, harzburgites and dunites.Although their mineralogical compositions are generally similarto those of spinel peridotites in off-craton settings, somecontain pyroxenes and spinels that have unusually low Al₂O₃contents more akin to those found in cratonic spinel peridotites.Furthermore, the tectonite peridotites have whole-rock majorelement compositions that tend to be significantly more depletedthan non-cratonic mantle spinel peridotites (high MgO, low CaO,Al₂O₃ and TiO₂) and resemble those of cratonic mantle. Thesecompositions could have been generated by up to 30% partialmelting of an undepleted mantle source. Petrographic evidencesuggests that the mantle beneath the Wyoming craton was re-enrichedin three ways: (1) by silicate melts that formed mica websteriteand clinopyroxenite veins; (2) by growth of phlogopite fromK-rich hydrous fluids; (3) by interaction with aqueous fluidsto form orthopyroxene porphyroblasts and orthopyroxenite veins.In contrast to their depleted major element compositions, thetectonite peridotites are mostly light rare earth element (LREE)-enrichedand show enrichment in fluid-mobile elements such as Cs, Rb,U and Pb on mantle-normalized diagrams. Lack of enrichment inhigh field strength elements (HFSE; e.g. Nb, Ta, Zr and Hf)suggests that the tectonite peridotites have been metasomatizedby a subduction-related fluid. Clinopyroxenes from the tectoniteperidotites have distinct U-shaped REE patterns with strongLREE enrichment. They have ¹⁴³Nd/¹⁴⁴Nd values that range from0·5121 (close to the host minette values) to 0·5107,similar to those of xenoliths from the nearby Highwood Mountains.Foliated mica websterites also have low ¹⁴³Nd/¹⁴⁴Nd values (0·5113)and extremely high ⁸⁷Sr/⁸⁶Sr ratios in their constituent phlogopite,indicating an ancient (probably mid-Proterozoic) enrichment.This enriched mantle lithosphere later contributed to the formationof the high-K Eocene host magmas. The cumulate group rangesfrom clinopyroxene-rich mica peridotites (including abundantmica wehrlites) to mica clinopyroxenites. Most contain >30%phlogopite. Their mineral compositions are similar to thoseof phenocrysts in the host minettes. Their whole-rock compositionsare generally poorer in MgO but richer in incompatible traceelements than those of the tectonite peridotites. Whole-rocktrace element patterns are enriched in large ion lithophileelements (LILE; Rb, Cs, U and Pb) and depleted in HFSE (Nb,Ta Zr and Hf) as in the host minettes, and their Sr–Ndisotopic compositions are also identical to those of the minettes.Their clinopyroxenes are LREE-enriched and formed in equilibriumwith a LREE-enriched melt closely resembling the minettes. Thecumulates therefore represent a much younger magmatic event,related to crystallization at mantle depths of minette magmasin Eocene times, that caused further metasomatic enrichmentof the lithosphere. KEY WORDS: ultramafic xenoliths; Montana; Wyoming craton; metasomatism; cumulates; minette  相似文献   

Early diagenetic carbonate precipitation and pore fluid migration in the Kimmeridge Clay of Dorset, England     

HILARY IRWIN 《Sedimentology》1980,27(5):577-591

In the argillaceous sequence of Kimmeridge Clay a carbonate rich bed is composed of ferroan dolomite cement with varying amounts of excess CaCO³, and Fe²⁺ substitution in the Mg²⁺ sites. The isotopic and chemical compositions change symmetrically about the centre of the band proving that it grew by vertical accretion during diagenesis. Textural and isotopic evidence shows that growth centred on a horizon rich in primary carbonate which became dolomitized and assimilated during production of diagenetic carbonate. This accounts for the lateral extent of the concretion. Early central diagenetic carbonate was produced from organic matter by bacterial fermentation (δ¹³C =+0.59‰) and later marginal carbonate by abiotic breakdown, (δ¹³C tending towards — 2.73‰). δ¹⁸O values range from — 1.56 to — 4.46‰ because the dolomite precipitated during progressive burial. As burial increased, magnesium, whose dominant source was trapped seawater, became depleted while the relative availability of Fe²⁺, whose source was dominantly reduced detrital oxides, increased. Dolomitization and the source of diagenetic components for dolomite formation are discussed. Diffusion and pore fluid migration transported ions to the site of precipitation. Early cementation of the band served to influence pore fluid migration, but thereafter pore fluid migration controlled carbonate precipitation.  相似文献   

Contrasting Fractionation Trends in Coexisting Continental Alkaline Magma Series; Cantal, Massif Central, France   总被引：4，自引：3，他引：1  

WILSON  MARJORIE; DOWNES  HILARY; CEBRIA  JOSE-MARIA 《Journal of Petrology》1995,36(6):1729-1753

Two coexisting series of strongly alkaline (basanite-tephritephonolite)and weakly alkaline (alkali basalt-trachyandesite-trachyte-rhyolite)lavas occur in the Cantal volcano (French Massif Central). Theparental magmas appear to be derived by variable degrees ofpartial melting of a common asthenospheric mantle source. Derivativetrachyandesites and feldspathoidbearing tephrites show depletionsand enrichments in trace elements which indicate that they havebeen generated by broadly similar fractionation processes, relatedto the removal of a mineral extract, from the parental alkalibasalts and basanites respectively, dominated by olivine, clinopyroxene,amphibole, apatite and titaniferous magnetite±plagioclase.In the most extreme differentiates (trachytes, rhyolites andphonolites) fractionation of zircon, sphene and alkali feldsparexerts a major control on the trace element characteristicsof the magmas. Sr-Nd-Pb isotopic data for the two magma series suggest theimportance of combined assimilation-fractional crystallizationprocesses (AFC) within the lower crust in their evolution. Modellingdemonstrates that the AFC process amplifies the original compositionaldifferences between the parent magmas. After 55% crystallizationin the strongly alkaline series and 65% in the weakly alkalineseries crustal contamination ceases, although fractional crystallizationcontinues beyond this point to produce the most evolved differentiates(phonolites and rhyolites). This may reflect progressive sealingof the lowercrustal magma reservoirs. The tendency of the magmasto follow over- or under-saturated evolutionary trends, producingrhyolitic and phonolitic residua respectively, appears to beestablished at the early stages of magmatic differentiation,reflecting inherent differences in the compositions of the parentalmagmas. KEY WORDS: alkaline magmas; Massif Central; Cantal; AFC; magmatic differentiation  相似文献