Chemical evolution of the Mt. Hekla,Iceland, groundwaters: A natural analogue for CO₂ sequestration in basaltic rocks     

Therese K. Flaathen  Sigurður R. Gislason  Eric H. Oelkers  Árný E. Sveinbjörnsdóttir 《Applied Geochemistry》2009

A detailed study of the chemical composition of the groundwater surrounding the Mt. Hekla volcano in south Iceland was performed to assess fluid evolution and toxic metal mobility during CO₂-rich fluid basalt interaction. These fluids provide a natural analogue for evaluating the consequences of CO₂ sequestration in basalt. The concentration of dissolved inorganic C in these groundwaters decreases from 3.88 to 0.746 mmol/kg with increasing basalt dissolution while the pH increases from 6.9 to 9.2. This observation provides direct evidence of the potential for basalt dissolution to sequester CO₂. Reaction path calculations suggest that dolomite and calcite precipitation is largely responsible for this drop in groundwater dissolved C concentration. The concentrations of toxic metal(loid)s in the waters are low, for example the maximum measured concentrations of Cd, As and Pb were 0.09, 22.8 and 0.06 nmol/kg, respectively. Reaction path modelling indicates that although many toxic metals may be initially liberated by the dissolution of basalt by acidic CO₂-rich solutions, these metals are reincorporated into solid phases as the groundwaters are neutralized by continued basalt dissolution. The identity of the secondary toxic metal bearing phases depends on the metal. For example, calculations suggest that Sr and Ba are incorporated into carbonates, while Pb, Zn and Cd are incorporated into Fe (oxy)hydroxide phases.  相似文献   

Evaluation of the real-time TRMM-based multi-satellite precipitation analysis for an operational flood prediction system in Nzoia Basin,Lake Victoria,Africa   总被引：3，自引：0，他引：3  

Li Li  Yang Hong  Jiahu Wang  Robert F. Adler  Frederick S. Policelli  Shahid Habib  Daniel Irwn  Tesfaye Korme  Lawrence Okello 《Natural Hazards》2009,50(1):109-123

Many researchers seek to take advantage of the recently available and virtually uninterrupted supply of satellite-based rainfall information as an alternative and supplement to the ground-based observations in order to implement a cost-effective flood prediction in many under-gauged regions around the world. Recently, NASA Applied Science Program has partnered with USAID and African-RCMRD to implement an operational water-hazard warning system, SERVIR-Africa. The ultimate goal of the project is to build up disaster management capacity in East Africa by providing local governmental officials and international aid organizations a practical decision-support tool in order to better assess emerging flood impacts and to quantify spatial extent of flood risk, as well as to respond to such flood emergencies more expediently. The objective of this article is to evaluate the applicability of integrating NASA’s standard satellite precipitation product with a flood prediction model for disaster management in Nzoia, sub-basin of Lake Victoria, Africa. This research first evaluated the TMPA real-time rainfall data against gauged rainfall data from the year 2002 through 2006. Then, the gridded Xinanjiang Model was calibrated to Nzoia basin for period of 1985–2006. Benchmark streamflow simulations were produced with the calibrated hydrological model using the rain gauge and observed streamflow data. Afterward, continuous discharge predictions forced by TMPA 3B42RT real-time data from 2002 through 2006 were simulated, and acceptable results were obtained in comparison with the benchmark performance according to the designated statistic indices such as bias ratio (20%) and NSCE (0.67). Moreover, it is identified that the flood prediction results were improved with systematically bias-corrected TMPA rainfall data with less bias (3.6%) and higher NSCE (0.71). Although the results justify to suggest to us that TMPA real-time data can be acceptably used to drive hydrological models for flood prediction purpose in Nzoia basin, continuous progress in space-borne rainfall estimation technology toward higher accuracy and higher spatial resolution is highly appreciated. Finally, it is also highly recommended that to increase flood forecasting lead time, more reliable and more accurate short- or medium-range quantitative precipitation forecasts is a must.  相似文献   

Effect of Shale Distribution on Hydrocarbon Sands Integrated with Anisotropic Rock Physics for AVA Modelling: A Case Study     

Aamir Ali  Zubair  Matloob Hussain  Khaista Rehman  Muhammad Toqeer 《Acta Geophysica》2016,64(4):1139-1163

Shales can be distributed in sand through four different ways; laminated, structural, dispersed and any combination of these aforementioned styles. A careful analysis of well log data is required for the determination of shale distribution in sand affecting its reservoir quality. The objective of this study is to characterize the effect of shale distribution on reservoir quality of sands using well log data. The correlation of well data in terms of lithology has revealed four sand and three shale layers in Lower Goru Formation acting as a major reservoir in the study area. Our results indicate that the laminated type of shale distribution prevails at the Basal sand level, which does not affect its reservoir quality greatly. The remaining layers of variable vertical extent show a variety of shale distribution models affecting their reservoir quality adversely. We also present anisotropic rock physics modelling for AVA analysis at Basal sand level.  相似文献   

Stratigraphic and geochemical study of the organic-rich black shales in the Tarcău Nappe of the Moldavidian Domain (Carpathian Chain,Romania)     

Habib Belayouni  Angelida Di Staso  Francesco Guerrera  Manuel Martín Martín  Crina Miclǎuş  Francisco Serrano  Mario Tramontana 《International Journal of Earth Sciences》2009,98(1):157-176

An integrated stratigraphic analysis has been made of the Tarcău Nappe (Moldavidian Domain, Eastern Romanian Carpathians), coupled with a geochemical study of organic-rich beds. Two Main Sequence Boundaries (Early Oligocene and near to the Oligocene–Aquitanian boundary, respectively) divide the sedimentary record into three depositional sequences. The sedimentation occurred in the central area of a basin supplied by different and opposite sources. The high amount of siliciclastics at the beginning of the Miocene marks the activation of the “foredeep stage”. The successions studied are younger than previously thought and they more accurately date the deformation of the different Miocene phases affecting the Moldavidian Basin. The intervals with black shales identified are related to two main separate anoxic episodes with an age not older than Late Rupelian and not before Late Chattian. The most important organic-rich beds correspond to the Lower Menilites, Bituminous Marls and Lower Dysodilic Shales Members (Interval 2). These constitute a good potential source rock for petroleum, with homogeneous Type II oil-prone organic matter, highly lipidic and thermally immature. The deposition of black shales has been interpreted as occurring within a deep, periodically isolated and tectonically controlled basin.  相似文献   

Analysis and farmers’ perception of climate change in the Kashmir Valley,India     

Mahdi  S. Sheraz  Dhekale  B. S.  Jan  Rukhsana  Bhat  M. Anwar  Hussain  Ashaq  Jehangir  Intikhab Aalum  Sofi  Najeebul Rehman  Ahmed  Latief  Qureshi  Asif M. Iqbal  Aezum  Aziz Mujtaba  Bangroo  Shabir A.  Wani  Owais Ali  Bahar  F. A.  Mishra  S. K. 《Theoretical and Applied Climatology》2022,149(1-2):727-741

Theoretical and Applied Climatology - Analysis of climatic variables is important for the detection and attribution of climate change trends and has received considerable attention from researchers...  相似文献   

Annual and seasonal trends of cooling, heating, and industrial degree-days in coastal regions of Saudi Arabia   总被引：1，自引：0，他引：1  

Shafiqur Rehman  Luai M. Al-Hadhrami  Shamsuddin Khan 《Theoretical and Applied Climatology》2011,103(3-4):479-488

In this study, we systematically analyze the changing properties of reference evapotranspiration (ETref) across China using Penman?CMonteith (P-M) method, exploring the major sensitive meteorological variables for ETref, and investigating influences of human activities, mainly urbanization in this study, on ETref changes in both space and time. We obtain some important conclusions: (1) decreasing annual and seasonal ETref is observed in the east, south and northwest China. However, a long strip lying between these regions is identified to be characterized by increasing ETref; (2) in the regions east to 100°E, the net total solar radiation is the main cause behind the decreasing ETref. In northwest China, however, relative humidity is recognized as the most sensitive variable for the ETref; (3) in the east and south China, urbanization greatly influences the ETref by directly decreasing net solar radiation. The increased air pollution and aerosols in the highly urbanized regions are the main driving factors causing decreasing net radiation; and (4) this study reveals accelerating hydrological cycle from south to north China. Besides, increasing ETref in the source regions of large rivers in China may pose new challenges for the basin-scale water resource management. The results of this study highlight the integrated effects of climate changes and human activities on ETref changes in different regions of China, which will be of great scientific and practical merits in in-depth understanding of hydrological cycle alterations under the changing environment in China.  相似文献   

Hydrochemical characterisation of ground and surface water at Dörtyol/Hatay/Turkey     

Maren Brehme  Traugott Scheytt  Mehmet Çelik  Uğur Erdem Dokuz 《Environmental Earth Sciences》2011,63(6):1395-1408

The degradation of ground water quality due to human activities is a widespread environmental problem. Furthermore, coastal aquifers are threatened by sea water intrusion as a result of increasing water exploitation. The investigation area near Dörtyol is located at the Mediterranean coast, southern Turkey, and dominated by agricultural land use. Drinking, domestic and agricultural purposes require different amounts of uncontaminated water. In this study the hydrogeological characteristics of the coastal plain were investigated. Discharge and ground water level measurements as well as geological investigations were undertaken in field in addition to anion and cation analyses of ground and surface water. The results show geological and anthropogenic influence on ground and surface water composition. In spite of a large number of wells in the coastal area sea water intrusion was not detected. With the goal of devising sustainable water use regulations, more emphasis and research needs to be directed to the long-term observation of ground and surface water quality as well as the detailed investigation of hydraulic characteristics of the local aquifer.  相似文献   

Biosorption of methylene blue from aqueous solutions by Typha angustata phytomass     

M. Saif Ur Rehman  J.-I. Han 《International Journal of Environmental Science and Technology》2013,10(4):865-870

The objective of this study was to investigate the biosorption of an azo dye (Methylene blue) by a wetland phytomass (Typha angustata) under post-phytoremediation scenario. Thus, the phytomass was used without any chemical modification. The batch adsorption experiments were conducted to evaluate the effects of contact time and temperatures (25–45 °C) on the adsorption of methylene blue (MB) from aqueous solution by cattail phytomass (CP). More than 80 % of MB dye was removed from the aqueous solution within first 10 min of the experiment. Langmuir isotherm was modeled to describe the monolayer adsorption of MB dye (R ² = 0.995) with the maximum adsorption capacity of 8.1 mg/g at 25 °C. Pseudo-second-order kinetic model adequately described the kinetics of absorption process (R ² = 0.999). The adsorption of MB on the cattail phytomass was a spontaneous and endothermic process that was governed by chemisorption. Hence, CP could be applied as a potential low cost biosorbent to treat dyeing wastewater.  相似文献   

Retention studies of chromium (VI) from aqueous solution on the surface of a novel carbonaceous material     

Sajjad Hussain  Saima Gul  Sabir Khan  Habib ur Rehman 《Arabian Journal of Geosciences》2013,6(11):4547-4556

In the present study, the retention capacity of carbonaceous material obtained from the diesel engine exhaust mufflers for Cr(VI) removal has been investigated. The physicochemical properties such as density, pH of aqueous slurry, pH at point of zero charge, ash content, moisture content, volatile matter, surface area, scanning electron microscopy and electron dispersive spectroscopy of the carbonaceous material were determined. The capacity of adsorbent for removal of Cr(VI) from aqueous solution was observed under different experimental condition like contact time, initial concentration of metal ions, pH and temperatures on the adsorption capacity of the adsorbent. Maximum adsorption of Cr(VI) ions was found at low pH. The adsorption process was found to follow second-order kinetics. The rate constant was evaluated at different temperatures along with other thermodynamic parameters like activation energy, Gibbs free energy change, enthalpy change and entropy change. Both Langmuir and Freundlich isotherms were used to describe the adsorption equilibrium of carbonaceous material at different temperatures. Langmuir isotherm shows better fit than Freundlich isotherm at given conditions. The result shows that low-cost carbonaceous material from diesel engine exhaust mufflers can be efficiently used for wastewater treatment containing Cr(VI) ions.  相似文献   

Characterization of parameters of sorption isotherm models of cadmium in selected semi-arid region agricultural cambisols and calcisols   总被引：1，自引：1，他引：0  

Habib Khodaverdiloo  Abbas Samadi  Mojtaba Barani Motlagh  Shoja Ghorbani Dashtaki  Fengxiang Han 《Arabian Journal of Geosciences》2013,6(9):3389-3395

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