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141.
142.
Artur?BenisekEmail authorView author&#;s OrcID profile Edgar?Dachs 《Contributions to Mineralogy and Petrology》2018,173(11):90
The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO3–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al2SiO5 polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods. 相似文献
143.
Bartosz J. Płachno Agata Jurkowska Grzegorz Pacyna Elżbieta Worobiec Przemysław Gedl Ewa Świerczewska-Gładysz 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):159-170
This paper presents the results of studies on plant macroremains found in the upper Turonian of the Folwark Quarry, Opole, Poland, associated with palynological studies of the host rocks. In addition to a few macrofossils (gymnosperm wood, conifer Geinitzia reichenbachii and fern ?Didymosorus) rich sporomorphs (bryophyte, lycopod and fern spores, conifer and angiosperm pollen grains) and marine palynomorphs (mainly dinoflagellate cysts) were recorded. The palynological analysis revealed that the vegetation on the neighbouring land (the East Sudetic Island) in the late Turonian was much more diverse than could be reconstructed based on only macrofossil remains. The latter are taxonomically restricted and dominated by one gymnosperm species (Geinitzia reichenbachii), which make them similar to most neighbouring, coeval Central European assemblages. Its over representation is, thus, a result of taphonomy. 相似文献
144.
Salaheddine El Adlouni 《Natural Hazards》2018,94(1):299-317
A spatial quantile regression model is proposed to estimate the quantile curve for a given probability of non-exceedance, as function of locations and covariates. Canonical vines copulas are considered to represent the spatial dependence structure. The marginal at each location is an asymmetric Laplace distribution where the parameters are functions of the covariates. The full conditional quantile distribution is given using the Joe–Clayton copula. Simulations show the flexibility of the proposed model to estimate the quantiles with special dependence structures. A case study illustrates its applicability to estimate quantiles for spatial temperature anomalies. 相似文献
145.
Yong Chen Jing Duan Junling An Huizhi Liu Ulrich G?rsdorf Franz H.Berger 《大气和海洋科学快报》2021,14(5):24-29
卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨. 相似文献
146.
Aude?ValadeEmail authorView author&#;s OrcID profile Sebastiaan?Luyssaert Patrick?Vallet Sylvestre?Njakou Djomo Ingride?Jesus Van Der Kellen Valentin?Bellassen 《Carbon balance and management》2018,13(1):26
Background
Concern about climate change has motivated France to reduce its reliance on fossil fuel by setting targets for increased biomass-based renewable energy production. This study quantifies the carbon costs and benefits for the French forestry sector in meeting these targets. A forest growth and harvest simulator was developed for French forests using recent forest inventory data, and the wood-use chain was reconstructed from national wood product statistics. We then projected wood production, bioenergy production, and carbon balance for three realistic intensification scenarios and a business-as-usual scenario. These intensification scenarios targeted either overstocked, harvest-delayed or currently actively managed stands.Results
All three intensification strategies produced 11.6–12.4 million tonnes of oil equivalent per year of wood-based energy by 2026, which corresponds to the target assigned to French wood-energy to meet the EU 2020 renewable energy target. Sustaining this level past 2026 will be challenging, let alone further increasing it. Although energy production targets can be reached, the management intensification required will degrade the near-term carbon balance of the forestry sector, compared to continuing present-day management. Even for the best-performing intensification strategy, i.e., reducing the harvest diameter of actively managed stands, the carbon benefits would only become apparent after 2040. The carbon balance of a strategy putting abandoned forests back into production would only break even by 2055; the carbon balance from increasing thinning in managed but untended stands would not break even within the studied time periods, i.e. 2015–2045 and 2046–2100. Owing to the temporal dynamics in the components of the carbon balance, i.e., the biomass stock in the forest, the carbon stock in wood products, and substitution benefits, the merit order of the examined strategies varies over time.Conclusions
No single solution was found to improve the carbon balance of the forestry sector by 2040 in a way that also met energy targets. We therefore searched for the intensification scenario that produces energy at the lowest carbon cost. Reducing rotation time of actively managed stands is slightly more efficient than targeting harvest-delayed stands, but in both cases, each unit of energy produced has a carbon cost that only turns into a benefit between 2060 and 2080.147.
Salim Lamine Sudhir Kumar Singh Szilárd Szabó Nour El Islam Bachari Prashant K. Srivastava 《国际地球制图》2018,33(8):862-878
This study aims to quantify the landscape spatio-temporal dynamics including Land Use/Land Cover (LULC) changes occurred in a typical Mediterranean ecosystem of high ecological and cultural significance in central Greece covering a period of 9 years (2001–2009). Herein, we examined the synergistic operation among Hyperion hyperspectral satellite imagery with Support Vector Machines, the FRAGSTATS® landscape spatial analysis programme and Principal Component Analysis (PCA) for this purpose. The change analysis showed that notable changes reported in the experimental region during the studied period, particularly for certain LULC classes. The analysis of accuracy indices suggested that all the three classification techniques are performing satisfactorily with overall accuracy of 86.62, 91.67 and 89.26% in years 2001, 2004 and 2009, respectively. Results evidenced the requirement for taking measures to conserve this forest-dominated natural ecosystem from human-induced pressures and/or natural hazards occurred in the area. To our knowledge, this is the first study of its kind, demonstrating the Hyperion capability in quantifying LULC changes with landscape metrics using FRAGSTATS® programme and PCA for understanding the land surface fragmentation characteristics and their changes. The suggested approach is robust and flexible enough to be expanded further to other regions. Findings of this research can be of special importance in the context of the launch of spaceborne hyperspectral sensors that are already planned to be placed in orbit as the NASA’s HyspIRI sensor and EnMAP. 相似文献
148.
Bouaida Jihad Witam Omar Ibnoussina Mounsif Delmaki Abd El Fettah Benkirane Myriam 《Natural Hazards》2021,105(2):1835-1859
Natural Hazards - Despite the controversy regarding their use, school buildings are often assigned as emergency evacuation shelters, temporary accommodation and aid distribution hubs following... 相似文献
149.
Zhou Jia-jin Yu Jian-lin Gong Xiao-nan El Naggar M. Hesham Zhang Ri-hong 《Acta Geotechnica》2021,16(10):3327-3338
This paper presents the results of field tests performed to investigate the compressive bearing capacity of pre-bored grouted planted (PGP) pile with enlarged grout base focusing on its base bearing capacity. The bi-directional O-cell load test was conducted to evaluate the behavior of full scale PGP piles. The test results show that the pile head displacements needed to fully mobilize the shaft resistance were 5.9% and 6.4% D (D is pile diameter), respectively, of two test piles, owing to the large elastic shortening of pile shaft. Furthermore, the results demonstrated that the PHC nodular pile base and grout body at the enlarged base could act as a unit in the loading process, and the enlarged grout base could effectively promote the base bearing capacity of PGP pile through increasing the base area. The normalized base resistances (unit base resistance/average cone base resistance) of two test piles were 0.17 and 0.19, respectively, when the base displacement reached 5% Db (Db is pile base diameter). The permeation of grout into the silty sand layer under pile base increased the elastic modulus of silty sand, which could help to decrease pile head displacement under working load.
相似文献150.
Chang?-Woong?ShinEmail author Cheolsoo?Kim Sang?-Kyung?Byun Dongchull?Jeon Sang?-Chull?Hwang 《Ocean Science Journal》2006,41(4):291-299
Hydrographic surveys were carried out four times in the western channel of the Korea Strait in March and August 2003 and in
June and November 2004. The bottom cold water, which was lower than 10°C, appeared in the channel trough except in March 2003.
It flowed southwestward along the shelf of Korean coasts in August 2003 and in November 2004. The width and the maximum speed
of the intrusion current were about 20 km and approximately 25 cm s-1, respectively, off Ulsan, Korea. The volume transport of the bottom cold water was estimated 0.019 Sv (Sv≡106 m3 s-1) in August 2003 and 0.026 Sv in November 2004. 相似文献