Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river          下载免费PDF全文

P. Byrne  H. Zhang  S. Ullah  A. Binley  A.L. Heathwaite  C.M. Heppell  K. Lansdown  M. Trimmer 《水文研究》2015,29(6):1385-1396

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

Prediction of nearshore wave heights using a refraction programme     

N.P. Kurian  M. Baba  T.S.Shahul Hameed 《Coastal Engineering》1985,9(4):347-356

The Dobson wave refraction programme, modified to incorporate bottom frictional attenuation, is being tested for its universal applicability for prediction of nearshore wave heights. An investigation has been undertaken to test the applicability of this programme for the prediction of wave heights over a gently sloping, wide continental shelf. The study has been carried out in the shelf waters off Alleppey, situated along the southwest coast of India. The measured wave height at a nearshore point and the computed wave height at the same point are compared. The application of Spearman's rank correlation and Wilcoxon's matched-pairs signed-ranks test has indicated that there is a high degree of correlation between the measured and predicted heights. Since similar results have been obtained by Bryant (1979) for steep shelf waters of Australia, it may be concluded that the programme can be used in different coastal waters irrespective of the nature of the shelf gradient, but subject to other limitations of the programme.  相似文献   

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia     

Asim Jilani  Syed Zajif Hussain  Mohd Hafiz Dzarfan Othman  Usama Zulfiqar  Muhammad Bilal Shakoor  Imran Ullah Khan  Javed Iqbal  Attieh A. Al-Ghamdi  Ahmed Alshahrie 《Journal of Atmospheric Chemistry》2018,75(3):271-283

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.  相似文献   

The North Pacific Oscillation: observations compared with simulations in a general circulation model     

Sultan Hameed  Iqbal Pittalwala 《Climate Dynamics》1991,6(2):113-122

The study of the sea level pressure and the surface air temperatures in the North Pacific region in a 23-year integration of the Oregon State University coupled ocean-atmosphere general circulation model has shown that there is a signature of the North Pacific Oscillation in the model, comparable to that recorded in observations. In the model, the NPO index was defined in terms of an opposition in sign of mean temperature anomaly between two regions in the North Pacific region, close to those found in observations (viz. Dutch Harbor, Alaska, and Edmonton, Canada). Fluctuations of this index prompted the grouping of some of the 23 model years as those when the temperature at the model equivalent of Dutch Harbor was above normal and that at the model equivalent of Edmonton below normal (analogous to Aleutian above in observations), while other years displayed the opposite scenario (Aleutian below). Composites of sea level pressure, surface air temperatures, precipitation and sea surface temperatures in the Northern Hemisphere were found to be at times strikingly similar to those documented in observations by Rogers.  相似文献   

Cotton production under risk: a simultaneous adoption of risk coping tools     

Farhad Zulfiqar  Raza Ullah  Muhammad Abid  Abid Hussain 《Natural Hazards》2016,84(2):959-974

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Wave height distribution in shallow water     

T.S. Shahul Hameed  M. Baba 《Ocean Engineering》1985,12(4):309-319

Probability distribution of shallow water wave heights, obtained from a pressure type recorder, are examined. It is tested with the theoretical distributions of (a) Rayleigh, (b) Weibull, (c) Gluhovski, (d) Ibrageemov and (e) Goda. The best fit is shown by the Gluhovski probability density function with a correlation coefficient greater than 0.8. The functions of Weibull, Ibrageemov and Goda fit only half of the tested cases. The role of wave steepness in the wave height distribution is found to be negligible.  相似文献   

Rock Physics Modeling and Reservoir Characterization to Estimate Hydrocarbon Zone of Cretaceous and Paleocene Strata and Subsurface Stratigraphic Correlation of Sulaiman Fold Belt to Sulaiman Depression     

Rehman  Saif ur  Umar  Muhammad  Ehsan  Muhammad Irfan  Munawar  Muhammad Jawad  Miraj  Muhammad Armaghan Faisal  Ullah  Muhammad Fahad 《Doklady Earth Sciences》2023,507(3):S446-S456

Doklady Earth Sciences - The research work involves rock physics modeling and reservoir characterization of Suliman fold belt to sulamain fold depression. This area is a brighter zone for...  相似文献   

Mid-latitude Southern Indian Ocean response to Northern Hemisphere Heinrich events     

Marie Alexandrine Sicre  Laurent Labeyrie  Ullah Ezat  Josette Duprat  Jean Louis Turon  Sabine Schmidt  Elisabeth Michel  Alain Mazaud 《Earth and Planetary Science Letters》2005,240(3-4):724-731

The lack of temporal resolution and accurate chronology of Southern Ocean marine cores has hampered comparison of glacial millennial-scale oscillations between the Southern Ocean, Antarctic ice and other records from both hemispheres. In this study, glacial climate variability is investigated over the last 50 ka using a multi-proxy approach. A precise chrono-stratigraphy was developed on the high-sedimentation rate core MD94-103 (Indian Southern Ocean, 45°35′S 86°31′E, 3560 m water depth) by geomagnetic synchronization between the later core and NAPIS75, and ¹⁴C dates. High-resolution time-series of δ¹⁸O in planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma, and sea surface temperatures (SSTs) estimated from the alkenone U^K′₃₇ index and foraminifera assemblages have been generated. Temporal evolution of the two temperature proxy records is notably different during the last glacial period. While foraminifera data indicate a consistent cooling towards the last glacial maximum, anomalous warm glacial alkenone temperatures suggest a strong advection of warm “detrital” alkenones by surface waters of the Agulhas current. Superimposed to this general trend, during Heinrich events, foraminiferal SSTs point to warmer surface waters, while concurrent alkenone SSTs exhibit apparent coolings probably caused by enhanced local alkenone production. By analogy to modern observations, possible influence of ENSO-like conditions on the subantarctic Southern Ocean SSTs is discussed.  相似文献   

A model investigation of the impact of increases in anthropogenic NO x emissions between 1967 and 1980 on tropospheric ozone     

Jane Dignon  Sultan Hameed 《Journal of Atmospheric Chemistry》1985,3(4):491-506

Recent observations suggest that the abundance of ozone between 2 and 8 km in the Northern Hemisphere mid-latitudes has increased by about 12% during the period from 1970 to 1981. Earlier estimates were somewhat more conservative suggesting increases at the rate of 7% per decade since the start of regular observations in 1967. Previous photochemical model studies have indicated that tropospheric ozone concentrations would increase with increases in emissions of CO, CH₄ and NO _x . This paper presents an analysis of tropospheric ozone which suggests that a significant portion of its increase may be attributed to the increase in global anthropogenic NO _x emissions during this period while the contribution of CH₄ to the increase is quite small. Two statistical models are presented for estimating annual global anthropogenic emissions of NO _x and are used to derive the trend in the emissions for the years 1966–1980. These show steady increase in the emissions during this interval except for brief periods of leveling off after 1973 and 1978. The impact of this increase in emissions on ozone is estimated by calculations with a onedimensional (latitudinal) model which includes coupled tropospheric photochemistry and diffusive meridional transport. Steady-state photochemical calculations with prescribed NO _x emissions appropriate for 1966 and 1980 indicate an ozone increase of 8–11% in the Northern Hemisphere, a result which is compatible with the rise in ozone suggested by the observations.  相似文献   

High-resolution records of the response of coastal wetland systems to long-term and short-term sea-level variability     

Alexander S. Kolker  Steven L. Goodbred Jr.  Sultan Hameed  J. Kirk Cochran   《Estuarine, Coastal and Shelf Science》2009,84(4):493-508

While it is well known that coastal systems respond to long-term sea-level changes, the importance of short-term sea-level dynamics is often overlooked. Year-to-year variability in annual mean sea level along the North American Atlantic coast is part of a regionally consistent pattern that is coupled to low atmospheric pressure and high wind field anomalies persisting over 100s to 1000s of km. These short-term sea-level dynamics, along with long-term sea-level changes are shown to be closely coupled to a set of high resolution excess ²¹⁰Pb geochronologies from four physiographically distinct salt marsh estuaries surrounding Long Island, NY, USA. However, the degree to which a marsh responds to either forcing depends on its physiographic setting. Accretion and mineral deposition rates in marshes situated in embayments with long fetches and low-tidal ranges are shown to respond most to the short-term dynamically driven changes in sea level. On the other hand, accretion and mineral deposition in a marsh in an embayment with a high-tidal range and reduced fetch best track the long-term changes in mean sea level, presumably because the physiography limited the meteorological drivers of short-term sea-level change. The close coupling between marsh accretion, physiographic setting and indices of sea-level change indicates that these coastal system respond both differently and rapidly (2–5 yr) to climate variability.  相似文献