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91.
High-temperature carbonate minerals have been observed in association with sulfide minerals below the platiniferous Johns-Manville (J-M) reef of the Stillwater Complex in a stratigraphic section that has been previously shown to be characterized by unusually Cl-rich apatite. The carbonate assemblage consists of dolomite with exsolved calcite in contact with sulfide minerals: chalcopyrite and pyrrhotite in the Peridotite Zone; and pyrrhotite with pentlandite, pyrite and chalcopyrite in Gabbronorite Zone I of the Lower Banded Series. A reaction rim surrounds the carbonate–sulfide assemblages, showing an alteration of the host orthopyroxene to a more calcium-enriched, Fe-depleted pyroxene. The calcite–dolomite geothermometer yields a minimum formation temperature as high as 950 °C for the unmixed assemblages. Iron and manganese concentrations exceed the range seen in carbonatite and mantle xenolith carbonates and are distinctly different from the nearly pure end-member carbonates associated with greenschist-grade (and lower) assemblages (e.g., carbonate veins in serpentinite) that occur locally throughout the complex. The association of high-temperature carbonates with sulfides beneath the J-M reef supports the hydromagmatic theory which involves a late-stage chloride–carbonate fluid percolating upwards, dissolving PGE and sulfides and redepositing them at a higher stratigraphic level. Characterization of the processes which form strategically important metal deposits, such as the J-M reef of the Stillwater Complex and the analogous Merensky reef of the Bushveld Complex in South Africa, could potentially lead to better exploration models and, more broadly, a deeper understanding of the cooling and compositional evolution of large bodies of ultramafic and mafic magma and of carbonatites, on both a local and a regional scale. 相似文献
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Increasing river temperatures are a threat to cold water species including ecologically and economically important freshwater fish, such as Atlantic salmon. In 2018, ca. 70% of Scottish rivers experienced temperatures which cause thermal stress in juvenile salmon, a situation expected to become increasingly common under climate change. Management of riparian woodlands is proven to protect cold water habitats. However, creation of new riparian woodlands can be costly and logistically challenging. It is therefore important that planting can be prioritized to areas where it is most needed and can be most effective in reducing river temperatures. The effects of riparian woodland on channel shading depend on complex interactions between channel width, orientation, aspect, gradient, tree height and solar geometry. Subsequent effects on river temperature are influenced by water volume and residence time. This study developed a deterministic river temperature model, driven by energy gains from solar radiation that are modified by water volume and residence time. The resulting output is a planting prioritization metric that compares potential warming between scenarios with and without riparian woodland. The prioritization metric has a reach scale spatial resolution, but can be mapped at large spatial scales using information obtained from a digital river network. The results indicate that water volume and residence time, as represented by river order, are a dominant control on the effectiveness of riparian woodland in reducing river temperature. Ignoring these effects could result in a sub-optimal prioritization process and inappropriate resource allocation. Within river order, effectiveness of riparian shading depends on interactions between channel and landscape characteristics. Given the complexity and interacting nature of controls, the use of simple universal planting criteria is not appropriate. Instead, managers should be provided with maps that translate complex models into readily useable tools to prioritize riparian tree planting to mitigate the impacts of high river temperatures. 相似文献
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Stephen J. Dugdale Christa A. Kelleher Iain A. Malcolm Samuel Caldwell David M. Hannah 《水文研究》2019,33(7):1152-1163
Climate change is altering river temperature regimes, modifying the dynamics of temperature‐sensitive fishes. The ability to map river temperature is therefore important for understanding the impacts of future warming. Thermal infrared (TIR) remote sensing has proven effective for river temperature mapping, but TIR surveys of rivers remain expensive. Recent drone‐based TIR systems present a potential solution to this problem. However, information regarding the utility of these miniaturised systems for surveying rivers is limited. Here, we present the results of several drone‐based TIR surveys conducted with a view to understanding their suitability for characterising river temperature heterogeneity. We find that drone‐based TIR data are able to clearly reveal the location and extent of discrete thermal inputs to rivers, but thermal imagery suffers from temperature drift‐induced bias, which prevents the extraction of accurate temperature data. Statistical analysis of the causes of this drift reveals that drone flight characteristics and environmental conditions at the time of acquisition explain ~66% of the variance in TIR sensor drift. These results shed important light on the factors influencing drone‐based TIR data quality and suggest that further technological development is required to enable the extraction of robust river temperature data. Nonetheless, this technology represents a promising approach for augmenting in situ sensor capabilities and improved quantification of advective inputs to rivers at intermediate spatial scales between point measurements and “conventional” airborne or satellite remote sensing. 相似文献
96.
Benjamin W. Abbott Kevin Bishop Jay P. Zarnetske David M. Hannah Rebecca J. Frei Camille Minaudo F.Stuart Chapin Stefan Krause Lafe Conner David Ellison Sarah E. Godsey Stephen Plont Jean Marais Tamara Kolbe Amanda Huebner Tyler Hampton Sen Gu Madeline Buhman Sayedeh Sara Sayedi Ovidiu Ursache Melissa Chapin Kathryn D. Henderson Gilles Pinay 《水文研究》2019,33(23):3046-3052
97.
Because of the importance of snow for river discharge in mountain regions, hydrological research often focuses on seasonally snow-covered zones. However, in many basins the majority of the land surface area is intermittently snow-covered. Discharge monitoring in these areas is less common, so their contributions to downstream rivers remain largely unknown. We evaluated hydrological differences between three intermittently snow-covered (mean annual Jan 1–Jul 3 snow persistence <60%) and two seasonally snow-covered headwater catchments in the Colorado Front Range. We compared water balance variables to evaluate how and why discharge differs between the snow zones and estimated the relative contributions from each snow zone to regional river discharge. We focused on water years 2016–2019 and used a combination of in situ sensors and regional climate datasets. Annual discharge from the intermittent snow zone was low for all three catchments (10–77 mm), despite covering a wide range in annual snow persistence (25%–64%), whereas annual discharge from the seasonal snow zone was up to 73 times higher. Soil moisture in the seasonal snow zone was above field capacity for longer periods of time than in the intermittent snow zone, and the intermittent snow zone was uniquely subject to soil freezing (up to 102 days per year). For most of the year, potential evapotranspiration exceeded rainfall and snowmelt inputs in the intermittent snow zone, but was lower than rainfall and snowmelt inputs in the seasonal snow zone. This is likely a primary driver of the differences in soil moisture and discharge for catchments with a seasonal versus intermittent snow cover. Despite the large difference in discharge between these two snow zones, the intermittent snow zone contributed about a quarter of the discharge in the regional river, highlighting the importance of studying discharge generation across all elevations. 相似文献
98.
Jos C. Aponte Hannah L. McLain Danielle N. Simkus Jamie E. Elsila Daniel P. Glavin Eric T. Parker Jason P. Dworkin Dolores H. Hill Harold C. Connolly Dante S. Lauretta 《Meteoritics & planetary science》2020,55(7):1509-1524
Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration. 相似文献
99.
Interest in groundwater (GW)-surface water (SW) interactions has grown steadily over the last two decades. New regulations such as the EU Water Framework Directive (WFD) now call for a sustainable management of coupled ground- and surface water resources and linked ecosystems. Embracing this mandate requires new interdisciplinary research on GW-SW systems that addresses the linkages between hydrology, biogeochemistry and ecology at nested scales and specifically accounts for small-scale spatial and temporal patterns of GW-SW exchange. Methods to assess these patterns such as the use of natural tracers (e.g. heat) and integrated surface-subsurface numerical models have been refined and enhanced significantly in recent years and have improved our understanding of processes and dynamics. Numerical models are increasingly used to explore hypotheses and to develop new conceptual models of GW-SW interactions. New technologies like distributed temperature sensing (DTS) allow an assessment of process dynamics at unprecedented spatial and temporal resolution. These developments are reflected in the contributions to this Special Issue on GW-SW interactions. However, challenges remain in transferring process understanding across scales. 相似文献
100.