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11.
12.
Thomas Backhaus Rolf Altenburger sa Arrhenius Hans Blanck Michael Faust Antonio Finizio Paola Gramatica Matthias Grote Marion Junghans Wiebke Meyer Manuela Pavan Tobias Porsbring Martin Scholze Roberto Todeschini Marco Vighi Helge Walter L. Horst Grimme 《Continental Shelf Research》2003,23(17-19):1757
Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined. 相似文献
13.
We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite
to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol)
has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical
signals on the amount of substance undergoing the reduction process.
Received December 21, 1995/Revised, accepted June 29, 1996 相似文献
14.
Georges Aouad Valérie Geoffroy Jean-Marie Meyer Jean-Louis Crovisier Denis Damidot Peter Stille 《Comptes Rendus Geoscience》2005,337(15):1340-1347
The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005). 相似文献
15.
Gold mineralization at Hutti is confined to a series of nine parallel, N–S to NNW–SSE trending, steeply dipping shear zones.
The host rocks are amphibolites and meta-rhyolites metamorphosed at peak conditions of 660±40°C and 4±1 kbar. They are weakly
foliated (S1) and contain barren quartz extension veins. The auriferous shear zones (reefs) are typically characterized by four alteration
assemblages and laminated quartz veins, which, in places, occupy the entire reef width of 2–10 m, and contain the bulk of
gold mineralization. A <1.5 m wide distal chlorite-sericite (+biotite, calcite, plagioclase) alteration zone can be distinguished
from a 3–5 m wide proximal biotite-plagioclase (+quartz, muscovite, calcite) alteration zone. Gold is both spatially and temporally
associated with disseminated arsenopyrite and pyrite mineralization. An inner chlorite-K-feldspar (+quartz, calcite, scheelite,
tourmaline, sphene, epidote, sericite) alteration halo, which rims the laminated quartz veins, is characterized by a pyrrhotite,
chalcopyrite, sphalerite, ilmenite, rutile, and gold paragenesis. The distal chlorite-sericite and proximal biotite-plagioclase
alteration assemblages are developed in microlithons of the S2–S3 crenulation cleavage and are replaced along S3 by the inner chlorite-K-feldspar alteration, indicating a two-stage evolution for gold mineralization. Ductile D2 shearing, alteration, and gold mineralization formed the reefs during retrograde evolution and fluid infiltration under upper
greenschist to lower amphibolite facies conditions (560±60°C, 2±1 kbar). The reefs were reactivated in the D3 dextral strike-slip to oblique-slip environment by fault-valve behavior at lower greenschist facies conditions (ca. 300–350°C),
which formed the auriferous laminated quartz veins. Later D4 crosscutting veins and D5 faults overprint the gold mineralization. The alteration mineralogy and the structural control of the deposit clearly points
to an orogenic style of gold mineralization, which took place either during isobaric cooling or at different levels of the
Archean crust. From overlaps in the tectono-metamorphic history, it is concluded that gold mineralization occurred during
two tectonic events, affecting the eastern Dharwar craton in south India between ca. 2550 – 2530 Ma: (1) The assemblage of
various terranes of the eastern block, and (2) a tectono-magmatic event, which caused late- to posttectonic plutonism and
a thermal perturbation. It differs, however, from the pre-peak metamorphic gold mineralization at Kolar and the single-stage
mineralization at Ramagiri. Notably, greenschist facies gold mineralization occurred at Hutti 35–90 million years later than
in the western Dharwar craton.
Editorial handling: G. Beaudoin 相似文献
16.
Well-preserved Holocene terraces along the South Fork Payette River in central Idaho provide a record of fluvial system behavior in a steep mountain watershed characterized by weathered and erodible Idaho Batholith granitic rocks. Terrace deposit ages were provided by 14C dating of charcoal fragments and optically stimulated luminescence (OSL) dating of sandy sediments. Along with pairing of many terrace tread heights, these data indicate episodic downcutting during the Holocene, with a mean incision rate of ~0.9 m/ka from ~7 ka to present. Prior to 7 ka, the river incised to within~3 m of current bankfull, but then aggraded by ~5 m over at least a ~10 km-long reach in an episode centered ~7–6 ka. Aggradation may relate to (1) increased hillslope sediment input from landslides and debris flows in steep tributary basins with abundant grussified granitic bedrock, (2) possible local landslide-damming of the channel, (3) decreased peak discharge, or (4) a combination of these factors. Middle Holocene channel aggradation ca. 7–6 ka corresponds with a period of prolonged and widespread aridity in the northern Rocky Mountains. Between ~5 and 1.3 ka, the river aggraded slightly and then remained stable, forming a prominent terrace tread at ~3 m above current bankfull. Modest aggradation to vertical stability of the South Fork Payette River at the 1.5 m terrace level ~1.0–0.7 ka corresponds with large fire-related debris flows in tributaries during Medieval droughts. Three intervals of incision (~5.5–5 ka, 1.3–1.0 ka and 0.5 ka) correspond with frequent but small fire-related sedimentation events and generally cooler, wetter conditions suggesting increased snowmelt runoff discharges. Other possible drivers of channel incision include an increase in stochastic or climate-modulated large storms and floods and a reduction in delivery of hillslope sediment to the channel. Aggradation is more confidently tied to climate through increases in hillslope sediment delivery and (or) decreased stream power, both likely related to warmer, drier conditions (including high-severity fires) that reduce snowmelt and decrease vegetation cover on steep slopes. Thus, the Holocene terraces of the South Fork Payette River do not reflect simple stepwise incision with periods of vertical stability and lateral migration, but record substantial episodes of aggradation as well. We infer that increases in hillslope erosion and mass movements combined with reduced discharges during prolonged droughts episodically reverse the post-glacial trend of downcutting, in particular during the middle Holocene. The present bedrock-dominated channel implies a strong tendency toward incision in the late Holocene. 相似文献
17.
Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola 下载免费PDF全文
Sylvie Leroy Nadine Ellouz‐Zimmermann Jordane Corbeau Frédérique Rolandone Bernard Mercier de Lépinay Bertrand Meyer Roberte Momplaisir José‐Luis Granja Bruña Anne Battani Céline Baurion Evgueni Burov Valérie Clouard Rémy Deschamps Christian Gorini Youri Hamon Manfred Lafosse Jottin Leonel Laetitia Le Pourhiet Pilar Llanes Estrada Nicolas Loget Francis Lucazeau Daniel Pillot Jeffrey Poort Kevin R. Tankoo José‐Luis Cuevas José‐Fernando Alcaide Claude Jean Poix Alfonso Muñoz‐Martin Serge Mitton Yamil Rodriguez Julien Schmitz Leonardo Seeber Andres Carbo‐Gorosabel Santiago Muñoz 《地学学报》2015,27(6):467-478
We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary. 相似文献
18.
Prof. Dr. K. Hinz Dr. J. Fritsch Dr. E. H. K. Kempter Mr. A. Manaf Mohammad Dr. J. Meyer Mr. D. Mohamed Dipl. Geophys. H. Vosberg Dipl. Ing. J. Weber Mr. J. Benavidez 《International Journal of Earth Sciences》1989,78(3):705-730
Widely accepted plate tectonic models suggest that an inactive subduction zone lies along the north-west continental margin of Sabah. In contrast, interpretation of reflection seismic data acquired by BGR shows an autochthonous continental terrane comprising an Oligocene to Early Miocene carbonate platform being progressively overthrust by an allochthonous rock complex. Progressive compression resulted in the development of four structural zones: Imbricated thrust sheets (Zone III); two thrust sheet systems one on top of the other (Zone IV); a complex zone with multiphase deformation (Zone V); and piercement ridges (Zone VI).
Zusammenfassung Nach herkömmlichen plattentektonischen Vorstellungen soll eine inaktive Subduktionszone am nordwestlichen Kontinentalrand von Sabah liegen. Reflexionsseismische Meßdaten der BGR zeigen jedoch, daß hier autochthone kontinentale Kruste mit einer oligozänen-frühmiozänen Karbonatplattform progressiv von einem allochthonen Gesteinsverband überschoben wird. Fortschreitender Zusammenschub seit dem frühen Miozän führte zur Anlage von vier Deformationszonen: Tekonische Schuppen (Zone III); zwei übereinander geschobene Verschuppungssysteme (Zone IV); Gürtel mit mehrphasiger Deformation (Zone V) und Durchspießungsstrukturen (Zone VI).
Résumé Les modèles géodynamiques que l'on admet habituellement comportent une zone de subduction inactive le long de la marge continentale nord-occidentale de Sabah. Toutefois, des mesures de sismique-réflexion exécutées par le BGR font apparaître qu'à cet endroit, une croûte continentale autochtone, comportant une plateforme carbonatée oligocène à éomiocène, est chevauchée progressivement par un complexe allochtone. La compression, qui s'est manifestée progressivement depuis le Miocène inférieur, a engendré quatre zones structurales: un ensemble d'écailles tectoniques (zone III); deux systèmes de lames tectoniques charriés l'un sur l'autre (zone IV); une zone complexe à déformation multiphasée (zone V); des structures d'extrusion tectonique (zone VI).
, - Sabah'a. , - . 4-? : ( 3), ( 4) ( 5) ( 6).相似文献
19.
Peter S. Meyer Henry J. B. Dick Geoffrey Thompson 《Contributions to Mineralogy and Petrology》1989,103(1):44-63
A diverse volcanic and plutonic rock suite was recovered from the center of the 80 km long ridge segment of the Southwest Indian Ridge (54°S, 7°16 E) between the Islas Orcadas and Shaka Fracture Zones. The cumulus nature of the gabbroic rocks in the suite is indicated by phase, modal and cryptic layering, igneous lamination, and low incompatible element abundances. We present a mass-balance model for calculating the proportions and compositions of cumulus phases and crystallized intercumulus liquid from bulk-rock major element compositions. The model is based on the ability to define a compositional array of basaltic liquids and on the assumption that cumulus minerals are initially in equilibrium with trapped liquid. Calculated proportions of trapped liquid range from 3%–15%; values that are characteristic of adcumulates to mesocumulates. Models of postcumulus crystallization indicate significant enrichments of incompatible elements and buffering of compatible elements in residual trapped liquids, thus explaining the high TiO2 contents observed in magnesian clinopyroxenes. Cumulus phase assemblages and compositions suggest solidification in shallow level magma chambers, but disequilibrium plagioclase compositions suggest some crystallization at greater depth. Furthermore, basalt compositions projected onto the olivine-clinopyroxenequartz pseudoternary suggest magma generation over a range of pressures (from less than 10 to greater than 20 kb) as well as polybaric fractional crystallization. We suggest that the Southwest Indian Ridge is characterized by low magma supply with small batches of melt that either ascend directly to the surface having undergone limited polybaric crystallization or are trapped in shallow crustal magma chambers where they evolve and solidify to form cumulate gabbros. The adcumulus nature of the gabbros investigated here suggests slow cooling rates typical of large intrusions implying relatively large, but ephemeral magma chambers below segments of the Southwest Indian Ridge. 相似文献
20.
David L. Meyer 《Estuaries and Coasts》1994,17(3):674-679
The abundances of the xanthid crabsPanopeus herbstii andEurypanopeus depressus were examined relative to surface oyster shell cover, surface oyster cluster volume, subsurface shell content, substrate sand and silt composition, and oyster reef elevation. During August 1986 through July 1987, xanthid crabs were collected monthly from twelve 0.25 m2×15 cm deep quadrats, during low tide, from intertidal oyster reefs in Mill Creek, Pender County, North Carolina, USA, with respective quadrat details recorded. The abundance ofP. herbstii, and to a lesser degreeE. depressus, was positively correlated with surface shell cover. The abundance ofE. depressus, and to a lesser degreeP. herbstii, was positively correlated with surface cluster volume. The majority ofP. herbstii inhabited the subsurface stratum of the oyster reef, whereas the majority ofE. depressus inhabited the cluster stratum. Seasonality (i.e., temperature) appeared to influence the strata habitation of both species, with a higher incidence of cluster habitation during warmer months and a lower incidence during colder months. Crab abundance was not related to other factors examined, such as subsurface shell, substrate sand and silt composition, or elevation within the oyster reef. The analyses show thatP. herbstii andE. depressus have partitioned the intertidal oyster reef habitat, withE. depressus exploiting surface shell clusters andP. herbstii the subsurface stratum. 相似文献