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21.
Grain size and geochemical analyses have been carried out on 58 samples collected from different areas of mangrove environment of the Egyptian Red Sea coast. The texture characteristics of mangrove sediments show that the mean size decreases in sediments of coastal areas while increase in island sediments and the sediment type generally changes from sand to slightly gravelly muddy sand. The sediments are composed mainly of poorly sorted, negatively nearly symmetrical and leptokurtic fine sands. Cluster analysis showed that, distribution of gravel, sand and mud fractions is related to bottom facies and type of sediment source. Generally, sand fraction is the main category among the three constituents. Geochemically the factor controlling the carbonate content of studied sediments includes material supply of biogenic and terrigenous components. Therefore, sediments of Hamata area, km 17 south Safaga, Wadi El-Gemal Island and Abu-Minqar Island are terrigenous sediments, while sediments of km 37 north Quseir are highly carbonates. In general organic matter is higher in the mangrove sediments relative to adjacent areas. The high organic matter in the mangrove sediments is primarily due to the high supply from primary productivity, terrestrial and reworked sediments. Texture is the main controlling factor for the organic matter enrichment. Spatial variations in the phosphorus content in the different studied localities are related to the sources of phosphorus to the area. In comparison, cluster analysis indicates that phosphorus might be transported from terrestrial source to the sea through wadis draining the excavated Upper Cretaceous phosphate rocks. Also, the abundance of phosphorus content may be attributed to phosphatization of calcareous skeletons. Our observations provide knowledge on the physico-chemical effects and will be useful in the management and suitable development of the areas under study. In addition it represent database in the future.  相似文献   
22.
The breccia-hosted epithermal gold–silver deposit of Chah Zard is located within a high-K, calc-alkaline andesitic to rhyolitic volcanic complex in the central part of the Urumieh-Dokhtar Magmatic Arc (UDMA), west central Iran. The total measured resource for Chah Zard is ∼2.5 million tonnes of ore at 12.7 g/t Ag and 1.7 g/t Au (28.6 t Ag, 3.8 t Au), making it one of the largest epithermal gold deposits in Iran. Magmatic and hydrothermal activity was associated with local extensional tectonics in a strike-slip regime formed in transtensional structures of the Dehshir-Baft strike-slip fault system. The host rocks of the volcanic complex consist of Eocene sedimentary and volcanic rocks covered by Miocene sedimentary rocks. LA-ICP–MS U–Pb zircon geochronology yields a mean age of 6.2 ± 0.2 Ma for magmatic activity at Chah Zard. This age represents the maximum age of mineralization and may indicate a previously unrecognized mineralization event in the UDMA. Breccias and veins formed during and after the waning stages of explosive brecciation events due to shallow emplacement of rhyolite porphyry. Detailed systematic mapping leads to the recognition of three distinct breccia bodies: volcaniclastic breccia with a dominantly clastic matrix; gray polymict breccia with a greater proportion of hydrothermal cement; and mixed monomict to polymict breccia with clay matrix. The polymictic breccias generated bulk-mineable ore, whereas the volcaniclastic breccia is relatively impermeable and largely barren. Precious metals occur with sulfide and sulfosalt minerals as disseminations, as well as in the veins and breccia cements. There is a progression from pyrite-dominated (stage 1) to pyrite-base metal sulfide and sulfosalt-dominated (stages 2 and 3) to base metal sulfide-dominated (stage 4) breccias and veins. Hydrothermal alteration and deposition of gangue minerals progressed from illite-quartz to quartz-adularia, carbonate, and finally gypsum-dominated assemblages. Free gold occurs in stages 2 and 4, principally intergrown with pyrite, quartz, chalcopyrite, galena, sphalerite, and Ag-rich tennantite–tetrahedrite, and also as inclusions in pyrite. High Rb/Sr ratios in ore-grade zones are closely related to sericite and adularia alteration. Positive correlations of Au and Ag with Cu, As, Pb, Zn, Sb, and Cd in epithermal veins and breccias suggest that all these elements are related to the same mineralization event.  相似文献   
23.
In recent years, the need for safe and economical methods to eliminate heavy metals from contaminated waters has necessitated research on the production of low-cost alternatives to commercially available activated carbon. In the present work, in order to enhance the removal of heavy metals from contaminated water, Zizyphus vulgaris wastes were modified chemically to produce an adsorbent rich in carboxylic groups to enhance the removal of heavy metals from contaminated water. Adsorption of Zn(II) ions on the produced adsorbent was then optimized. The optimal ratio for esterification involved the treatment of Z. vulgaris wastes (1 g) with 0.0037 mmol malic acid in the presence of a very small amount of water for 2 h at 140 °C. The maximum values for adsorption capacity, q max, were 28.7 and 164.6 mg/g on native and modified Z. vulgaris wastes, respectively, at pH 5 and 30 °C with a contact time 2 h and an initial metal ion concentration of 400 mg/L. The equilibrium data were well fitted by the Langmuir and Freundlich adsorption models and demonstrated the significant capacity for Z. vulgaris wastes in the removal of Zn(II) ions from aqueous solutions.  相似文献   
24.
In order to monitor the heavy metals effect coming from both human activities and natural inputs on coral reef environments of the Egyptian Red Sea coast, metal concentrations in thirty- eight coral reef species and nearby sediment samples collected from seven studied sites were analyzed. Four sites represent impacted areas; included from south to north Hamrawein, Safaga and Hurghada Harbours and Ras El-Behar Area. Wadi El-Gemal represents natural input area while Qola'an and Kalawye Reefs are the control areas. Heavy metal contents were measured in both coral skeletons and nearby marine sediments. Both impact areas as well as natural inputs area recorded the highest values of metals compared with the control ones. However, heavy metal contents recorded high values in sediments of Hamrawein Harbour, while coral species recorded high values in Wadi El-Gemal area. Generally, metal variations in coral reef species reflect natural conditions and human activity. On the other hand, there are no clear relationships between concentrations of heavy metals in coral reef species and those in sediments.  相似文献   
25.
The Niyasar plutonic complex, one of the Cenozoic magmatic assemblages in the Urumieh‐Dokhtar magmatic belt, was the subject of detailed petrographic and mineralogical investigations. The Niyasar magmatic complex is composed of Eocene to Oligocene mafic rocks and Miocene granitoids. Eleven samples, representing the major rock units in the Niyasar magmatic complex and contact aureole were chosen for mineral chemical studies and for estimation of the pressure, temperature, and oxygen fugacity conditions of mineral crystallization during emplacement of various magmatic bodies. The analyzed samples are composed of varying proportions of quartz, plagioclase, K‐feldspar, hornblende, biotite, titanite, magnetite, apatite, zircon, garnet, and clinopyroxene. Application of the Al‐in‐hornblende barometer indicates pressures of around 0.2 to 0.4 kbar for the Eocene–Oligocene mafic bodies and around 0.5 to 1.7 kbar for the Miocene granitoids. Hornblende‐plagioclase thermometry yields relatively low temperatures (661–780 °C), which probably reflect late stage re‐equilibration of these minerals. The assemblage titanite–magnetite–quartz as well as hornblende composition were used to constrain the oxygen fugacity and H2O content during the crystallization of the parent magmas in the Miocene plutons. The results show that the Miocene granitoids crystallized from magmas with relatively high oxygen fugacity and high H2O content (~5 wt% H2O). The Miocene granitoids show similar range of oxygen fugacity, H2O contents and mineral chemical compositions, which indicate a common source for their magmas. Although the crystallization pressures of the Miocene plutons discriminate various categories of plutonic bodies emplaced at depths of about 5.7–6.5 km (Marfioun pluton), about 4.2 km (Ghalhar pluton) and 1.9–2.3 km (Poudalg pluton), they were later uplifted to the same level by vertical displacement of faults. The emplacement depths of the Niyasar plutons suggest that the central part of the Urumieh‐Dokhtar magmatic belt has experienced an uplift rate of ca. 0.25–0.4 mm/yr from the Miocene onwards.  相似文献   
26.
Global cooling: increasing world-wide urban albedos to offset CO2   总被引:2,自引:0,他引:2  
Increasing urban albedo can reduce summertime temperatures, resulting in better air quality and savings from reduced air-conditioning costs. In addition, increasing urban albedo can result in less absorption of incoming solar radiation by the surface-troposphere system, countering to some extent the global scale effects of increasing greenhouse gas concentrations. Pavements and roofs typically constitute over 60% of urban surfaces (roof 20–25%, pavements about 40%). Using reflective materials, both roof and pavement albedos can be increased by about 0.25 and 0.15, respectively, resulting in a net albedo increase for urban areas of about 0.1. On a global basis, we estimate that increasing the world-wide albedos of urban roofs and paved surfaces will induce a negative radiative forcing on the earth equivalent to offsetting about 44 Gt of CO2 emissions. At ~$25/tonne of CO2, a 44 Gt CO2 emission offset from changing the albedo of roofs and paved surfaces is worth about $1,100 billion. Furthermore, many studies have demonstrated reductions of more than 20% in cooling costs for buildings whose rooftop albedo has been increased from 10–20% to about 60% (in the US, potential savings exceed $1 billion per year). Our estimated CO2 offsets from albedo modifications are dependent on assumptions used in this study, but nevertheless demonstrate remarkable global cooling potentials that may be obtained from cooler roofs and pavements.  相似文献   
27.
The central Alborz mountain range, located in northern Iran, neighboring the Caspian Sea and where the two Persia and Eurasia plates meet, is known as a seismologically active area. In this regard, investigation of the behavior of saturated sand deposits located in this area may be of particular interest. Saturated sand deposits are subjected to instabilities owing to liquefaction or volume change due to earthquake shakings. A particular type of saturated sand deposits is Anzali sand which is abundant in Anzali port and other cities located in this area in northern Iran. This type of sand is a representative for most sands found in this area, i.e., the southern coastal line of Caspian Sea. This research is solely focused on the volume change behavior of marine deposits of Anzali area, often characterized as Anzali sand, in terms of the settlement of a model footing located on the surface of the sand by the aid of a transparent laminar shear box apparatus. Effects of a number of factors such as the frequency of the cyclic loading, the initial density of the sand, and the sample preparation method have been investigated. Observations indicated that the density index and the frequency of loading which are proportional to the energy of an earthquake have direct effects on the accumulation and amount of the final settlement of Anzali sand.  相似文献   
28.
The>2000 km Indus-Yarlung Tsangpo suture zone(IYSZ)is composed of the Neo-tethys oceanic remnants,flysch units and related continental rocks,which has been regarded as the boundary between the Eurasian and Indian terranes.Among the ophiolitic complexes,the Purang ophiolite is the biggest massif in the IYSZ,and many studies have been conducted on this ophiolite.However,previous studies have mainly focused on harzburgite,clinopyroxenite and dunite.Field observations show that mafic dykes were emplaced within the Purang ophiolite.However,petrogenetic evolutions of those mafic dykes are poorly understood.In this study,we present new LA-ICP-MS zircon U-Pb dating results,whole-rock geochemistry and Sr-Nd-Hf isotope analyses for microgabbro,gabbro and dolerite dykes from the Purang ophiolite of the southwestern IYSZ,respectively.Three samples yielded zircon U-Pb ages of144.2±2.1 Ma.127.9±2.3 Ma and 126.5±0.42 Ma,suggesting two different phases of magmatic activities distinctly.Whole-rock geochemical results suggest that the gabbro samples show alkaline features marked by enrichments of light rare earth elements(LREE)and large-ion lithophile elements(LILE),as well as Nb-Ta elements,suggesting an oceanic island basalt-like(OIB-like)geochemical affinity.However,the dolerite and microgabbro samples demonstrate sub-alkaline characteristics with normal mid-oceanic ridge basalt-like(N-MORB-like)geochemical features.Three distinct mafic dykes show significant Rb element depletion.The geochemical data and Sr-Nd-Hf isotopic features suggest that the microgabbro and gabbro rocks were derived from a depleted mantle that had been metasomatized by partial melts of sediments and enriched slab-derived fluids.The dolerite was also originated from a depleted mantle marked by significantly depleted Sr-Nd-Hf compositions,which was not influenced by enriched slab-derived fluids and sediments contamination during subsequent evolution.The isotope and geochemical data and tectonic diagrams suggest a tectonic transition from a within-plate to a midoceanic ridge basalt-like(MORB-like)setting during the period from ca.144 Ma to 127 Ma.Combined with regional background and this study,we propose that these mafic dykes were formed in an oceanic back-arc basin setting.Additionally,integrated with previous studies,we suggest that the geodynamic evolution of the southwestern and central parts of the Neo-Tethys oceanic basin is comparable in Early Cretaceous.  相似文献   
29.
The extraction of urban built-up areas is an important aspect of urban planning and understanding the complex drivers and biophysical mechanism of urban climate processes. However, built-up area extraction using Landsat data is a challenging task due to spatio-temporal dynamics and spatially intermixed nature of Land Use and Land Cover (LULC) in the cities of the developing countries, particularly in tropics. In the light of advantages and drawbacks of the Normalized Difference Built-up Index (NDBI) and Built-up Area Extraction Method (BAEM), a new and simple method i.e. Step-wise Land-class Elimination Approach (SLEA) is proposed for rapid and accurate mapping of urban built-up areas without depending exclusively on the band specific normalized indices, in order to pursue a more generalized approach. It combines the use of a single band layer, Normalized Difference Vegetation Index (NDVI) image and another binary image obtained through Logit model. Based on the spectral designation of the satellite image in use, a particular band is chosen for identification of water pixels. The Double-window Flexible Pace Search (DFPS) approach is employed for finding the optimum threshold value that segments the selected band image into water and non-water categories. The water pixels are then eliminated from the original image. The vegetation pixels are similarly identified using the NDVI image and eliminated. The residual pixels left after elimination of water and vegetation categories belong either to the built-up areas or to bare land categories. Logit model is used for separation of the built-up areas from bare lands. The effectiveness of this method was tested through the mapping of built-up areas of the Kolkata Metropolitan Area (KMA), India from Thematic Mapper (TM) images of 2000, 2005 and 2010, and Operational Land Imager (OLI) image of 2015. Results of the proposed SLEA were 95.33% accurate on the whole, while those derived by the NDBI and BAEM approaches returned an overall accuracy of 83.67% and 89.33%, respectively. Comparisons of the results obtained using this method with those obtained from NDBI and BAEM approaches demonstrate that the proposed approach is quite reliable. The SLEA generates new patterns of evidence and hypotheses for built-up areas extraction research, providing an integral link with statistical science and encouraging trans-disciplinary collaborations to build robust knowledge and problem solving capacity in urban areas. It also brings landscape architecture, urban and regional planning, landscape and ecological engineering, and other practice-oriented fields to bear together in processes for identifying problems and analyzing, synthesizng, and evaluating desirable alternatives for urban change. This method produced very accurate results in a more efficient manner compared to the earlier built-up area extraction approaches for the landscape and urban planning.  相似文献   
30.
The online Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) is used to simulate the effects of albedo enhancement on aerosol, radiation, and cloud interactions in the Greater Montreal Area during the 2011 heat wave period. We used a 2-way nested approach to capture the full impacts of meteorological and photochemical reactions in the urban atmosphere. We conducted four sets of simulations with and without aerosol estimations and convective parameterizations to explore the aerosol interactions with radiation and cloud in the urban atmosphere. The direct, semi-direct, and indirect effects of aerosols are analyzed. The meteorological performance of the model indicates that the model slightly underpredicts air temperature, overpredicts wind speed, and underpredicts relative humidity. The chemical component of the model indicates that the model tends to underpredict fine particulate matters and overpredict ozone and nitrogen dioxide concentrations. The surface reflectivity of roofs, walls, and grounds is increased from 0.2 to 0.65, 0.60, and 0.45, respectively. Albedo enhancement led to a net decrease in radiative balance at solar noon by 25 W/m2, a decrease in daily air temperature by 0.5 °C, a reduction in water mixing ratio to 0.5 g/kg, and a decline in cloud coverage by 3% in the center part of the domain. Increasing urban albedo caused a decrease in planetary boundary layer height by 25 m. Albedo enhancement affords a decrease in temperature-sensitive photochemical reaction rates and thus reduces daily ozone concentrations by 3 ppb across the entire domain. The concentration of daily fine particulate matters decreased by 3 μg/m3 in the center part of the GMA during the 2011 heat wave period.  相似文献   
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