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Interatomic potential parameters have been derived at simulated temperatures of 0 K and 300 K to model pyrite FeS2. The predicted pyrite structures are within 1% of those determined experimentally, while the calculated bulk modulus is within 7%. The model is also able to simulate the properties of marcasite, even though no data for this phase were included in the fitting procedure. There is almost no difference in results obtained for pyrite using the two potential sets; however, when used to model FeS2 marcasite, the potential fitted at 0 K performs better. The potentials have also been used to study the high-pressure behaviour of pyrite up to 44 GPa. The calculated equation of state gives good agreement with experiment and shows that the Fe–S bonds shorten more rapidly that the S–S dimer bonds. The behaviour of marcasite at high pressure is found to be similar to that of pyrite. 相似文献
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The inference of fault geometry from suprajacent fold shape relies on consistent and verified forward models of fault-cored folds, e.g. suites of models with differing fault boundary conditions demonstrate the range of possible folding. Results of kinematic (fault-parallel flow) and mechanical (boundary element method) models are compared to ascertain differences in the way the two methods simulate flexure associated with slip along flat-ramp-flat geometry. These differences are assessed by systematically altering fault parameters in each model and observing subsequent changes in the suprajacent fold shapes. Differences between the kinematic and mechanical fault-fold relationships highlight the differences between the methods. Additionally, a laboratory fold is simulated to determine which method might best predict fault parameters from fold shape. Although kinematic folds do not fully capture the three-dimensional nature of geologic folds, mechanical models have non-unique fold-fault relationships. Predicting fault geometry from fold shape is best accomplished by a combination of the two methods. 相似文献
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Tsuyoshi Watanabe Michael K. Gagan Heather Scott-Gagan Wahyoe S. Hantoro 《Geochimica et cosmochimica acta》2003,67(7):1349-1358
Diploastrea heliopora forms dense, robust, dome-shaped coral colonies throughout the reef ecosystems of the tropical Pacific and Indian Oceans. This slow-growing (2 to 6 mm/yr) coral has the potential to yield continuous paleoclimate records spanning up to 1000 yr for the warmest waters on Earth, the Indo-Pacific Warm Pool, and has a long fossil history as a single recognizable species. Despite the potential of Diploastrea to be an important new paleoclimate archive, little is known about the systematics of geochemical tracers incorporated into its skeleton. To fill this knowledge gap, we compared skeletal δ18O signatures in live Diploastrea and Porites colonies from Southwest Lagoon, near Amédée Lighthouse, New Caledonia (at the southern latitudinal limit for Diploastrea) and Alor, Indonesia (in the core area of the Indo-Pacific Warm Pool). We designed a new microsampling technique to minimize smoothing and distortion of the isotopic records due to the complex calyx architecture and slow growth of Diploastrea. High-resolution isotope profiles from the septal portion of the Diploastrea corallite are attenuated, whereas those restricted to the central columella are similar in quality to those extracted from the well-established Porites coral archive. The δ18O-temperature relationship for the columellar portion of Diploastrea (−0.18‰/°C) is in good agreement with that derived for a nearby Porites (−0.19‰/°C; Quinn et al., 1996), on the basis of comparison with an in situ sea surface temperature record from Amédée Lighthouse. There is a measurable difference of 0.3 ± 0.1‰ between the kinetic/biological disequilibrium offsets from seawater δ18O composition for Diploastrea and Porites. Despite this offset in mean δ18O, Diploastrea accurately records the regional differences in mean temperature and salinity between New Caledonia and the Indo-Pacific Warm Pool. Additional tests show that Diploastrea records El Niño-Southern Oscillation (ENSO) interannual variability in sea surface temperature and salinity across the southwestern Pacific, indicating that it should yield dependable paleo-ENSO records. Based on these results, we propose that D. heliopora has the potential to provide an important new coral archive of tropical paleoclimate. 相似文献
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T. K. Yeoman D. M. Wright T. R. Robinson J. A. Davies M. Rietveld 《Annales Geophysicae》1997,15(6):634-644
The CUTLASS Finland HF radar has been operated in conjunction with the EISCAT Tromsø RF ionospheric heater facility to examine a ULF wave characteristic of the development of a field line resonance (FLR) driven by a cavity mode caused by a magnetospheric impulse. When the heater is on, striating the ionosphere with field-aligned ionospheric electron density irregularities, a large enough radar target is generated to allow post-integration over only 1 second. When combined with 15 km range gates, this gives radar measurements of a naturally occurring ULF wave at a far better temporal and spatial resolution than has been achieved previously. The time-dependent signature of the ULF wave has been examined as it evolves from a large-scale cavity resonance, through a transient where the wave period was latitude-dependent and the oscillation had the characteristics of freely ringing field lines, and finally to a very narrow, small-scale local field line resonance. The resonance width of the FLR is only 60 km and this is compared with previous observations and theory. The FLR wave signature is strongly attenuated in the ground magnetometer data. The characterisation of the impulse driven FLR was only achieved very crudely with the ground magnetometer data and, in fact, an accurate determination of the properties of the cavity and field line resonant systems challenges the currently available limitations of ionospheric radar techniques. The combination of the latest ionospheric radars and facilities such as the Tromsø ionospheric heater can result in a powerful new tool for geophysical research. 相似文献
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