Diffusion-controlled growth of wollastonite rims between quartz and calcite: comparison between nature and experiment   总被引：2，自引：2，他引：2  

R. Milke  W. Heinrich 《Journal of Metamorphic Geology》2002,20(5):467-480

Growth rates of wollastonite reaction rims between quartz and calcite were experimentally determined at 0.1 and 1 GPa and temperatures from 850 to 1200 °C. Rim growth follows a parabolic rate law indicating that this reaction is diffusion‐controlled. From the rate constants, the D′δ‐values of the rate‐limiting species were derived, i.e. the product of grain boundary diffusion coefficient D′ and the effective grain boundary width, δ. In dry runs at 0.1 GPa, wollastonite grew exclusively on quartz surfaces. From volume considerations it is inferred that (D′_CaOδ)/(D′_SiO2δ)≥1.33, and that SiO₂ diffusion controls rim growth. D′_SiO2δ increases from about 10^?25 to 10^?23 m³ s^?1 as temperature increases from 850 to 1000 °C, yielding an apparent activation energy of 330±36 kJ mol^?1. In runs at 1 GPa, performed in a piston‐cylinder apparatus, there were always small amounts of water present. Here, wollastonite rims always overgrew calcite. Rims around calcite grains in quartz matrix are porous and their growth rates are controlled by a complex diffusion‐advection mechanism. Rim growth on matrix calcite around quartz grains is controlled by grain boundary diffusion, but it is not clear whether CaO or SiO₂ diffusion is rate‐limiting. D′δ increases from about 10^?21 to 10^?20 m³ s^?1 as temperature increases from 1100 to 1200 °C. D′_SiO2δ or D′_CaOδ in rims on calcite is c. 10 times larger than D′_SiO2δ in dry rims at the same temperature. Growth structures of the experimentally produced rims are very similar to contact‐metamorphic wollastonite rims between metachert bands and limestone in the Bufa del Diente aureole, Mexico, whereby noninfiltrated metacherts correspond to dry and brine‐infiltrated metacherts to water‐bearing experiments. However, the observed diffusivities were 4 to 5 orders of magnitude larger during contact‐metamorphism as compared to our experimental results.  相似文献   

Metamorphic reactions between fluid inclusions and mineral hosts. I. Progress of the reaction calcite+quartz=wollastonite+CO2 in natural wollastonite-hosted fluid inclusions     

W. Heinrich  Matthias Gottschalk 《Contributions to Mineralogy and Petrology》1995,122(1-2):51-61

 At the Bufa del Diente contact-metamorphic aureole, brine infiltration through metachert layers embedded in limestones produced thick wollastonite rims, according to Cc+Qz=Wo+CO₂. Fluid inclusions trapped in recrystallized quartz hosts include: (1) high salinity four phase inclusions [Th(V-L)=460–573° C; Td(salts)=350–400° C; (Na+K)_Cleq=64–73 wt%; X _{CO 2}≤0.02]; (2) low density vapour-rich CO₂-bearing inclusions [Th(L-V)≈500±100° C; X _{CO 2}=0.22–0.44; X _NaCl≤0.01], corresponding to densities of 0.27± 0.05 gcm⁻³. Petrographical observations, phase compositions and densities show that the two fluids were simultaneously trapped in the solvus of the H₂O-CO₂-salts system at 500–600° C and 700±200 bars. The low density fluid was generated during brine infiltration at the solvus via the wollastonite producing reaction. Identical fluid types were also trapped as inclusion populations in wollastonite hosts 3 cm adjacent to quartz crystals. At room temperature, both fluid types additionally contain one quartz and one calcite crystal, generated by the back-reaction Wo+CO₂=Cc+Qz of the host with the CO₂-proportion of the fluid during retrogression. All of the CO₂ was removed from the fluid. On heating in the microstage, the reaction progress of the prograde reaction was estimated via volume loss of the calcites. In vapour-rich fluids, 50% progress is reached at 490–530° C; 80% at 520–560° C; and 100% at 540–590° C, the latter representing the trapping temperatures of the original fluid at the two fluid solvus. The progress is volume controlled. With knowledge of compositions and densities from unmodified inclusions in quartz and using the equation of state of Duan et al. (1995) for H₂O-CO₂-NaCl, along with f _{CO 2}-values extracted from it, the reaction progress curve was recalculated in the P-T-X-space. The calculated progress curve passes through the two fluid solvus up to 380° C/210 bars, continues in the one fluid field and meets the solvus again at trapping conditions. The P-T slope is steep, most of the reaction occurs above 450° C and there is high correspondence between calculated and measured reaction progress. We emphasize that with the exception of quartz, back-reactions between inclusion fluids and mineral hosts is a common process. For almost any prograde metamorphic mineral that was formed by a devolatilization reaction and that trapped the equilibrium fluid or any peak metamorphic fluid as an inclusion, a fluid-host back-reaction exists which must occur somewhere along the retrograde path. Such retrograde reactions may cause drastic changes in density and composition of the fluid. In most cases, however, evidence of the evolving mineral assemblages is not given for they might form submicroscopical layers at the inclusion walls. Received: 15 March 1995 / Accepted: 1 June 1995  相似文献   

A fluid inclusion reconnaissance study of the Huanuni tin deposit (Bolivia), using LA-ICP-MS micro-analysis   总被引：1，自引：0，他引：1  

Barbara Müller  Rolf Frischknecht  Terry Seward  Christoph Heinrich  Willy Camargo Gallegos 《Mineralium Deposita》2001,36(7):680-688

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Zwei Methoden zur Berechnung der Mächtigkeit tektonisch bewegter Regionalschollen     

Heinrich Quiring 《International Journal of Earth Sciences》1926,17(6):391-397

Ohne Zusammenfassung  相似文献   

Atmosphärische Fronten und Vertikalaustausch     

Dr. Heinrich Faust 《Pure and Applied Geophysics》1951,19(1-2):52-59

Zusammenfassung Die vom Verfasser aufgestellten fünf Typen von Kaltfronten, die als wesentliches Unterscheidungsmerkmal die vertikale Temperaturschichtung im Frontbereich benutzen, sowie stabile und labile Warmfronten zeichnen sich in den Wetterkarten durch typische Wettererscheinungen aus. Für jeden dieser Fronttypen, die nach diesen Erscheinungen aus den Wetterkarten des Jahres 1950 für Hamburg ausgesucht wurden, wurde das Jahresmittel des vertikalen Austauschkoeffizienten in 35 m Höhe und der Oxydationswert der Bodenluft bestimmt. Die Ergebjisse bestätigen die Berechtigung der gegebenen Frontenklassifikation.

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Summary The five cold front types adopted by the author, with the vertical lapse rate of temperature in the frontal area as the essential characteristic, and stable und unstable warm frontal systems are distinguishable in the weather maps by specific weather phenomena connected with them. Based on the weather maps for Hamburg Germany, in 1950, the annual mean coefficient of vertical exchange at the 35-m level and the oxydation value of the surface air layer were determined for each of these frontal types. The results obtained are confirming as justified the adopted classification.

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Die Beziehung zwischen dem Luftdruck in 8 km Höhe und der Dichte in 11 Km Höhe     

Dr. Heinrich Faust 《Pure and Applied Geophysics》1963,56(1):194-202

Zusammenfassung Oberhalb der Nullschicht addieren sich Druck und Temperatur hinsichtlich ihrer Wirkung auf die Dichte. Es existiert in etwa 11 km Höhe eine Horizontalfläche maximaler Dichteabnahme vom Hoch zum Tief. Der Luftdruck in der Schicht maximalen Horizontalgradienten des Drucks in etwa 8 km ist ein Maß für die Intensität eines Druckgebildes. Die Stärke der Korrelation zwischen dem Druck in 8 km und der Dichte in 11 km ist somit ein maß für die Stärke der Nullschichtvorgänge.

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Summary The large scale vertical motions in high and low pressure systems are, in the mean, reversed in the null layer, connected with the upper-tropospheric wind maximum layer (about 10 km altitude). Above the null layer pressure and temperature influence the air density in the same sense; below it their influence upon the air density is opposite. In an altitude of 11 km (middle latitudes) there exists a horizontal surface with a maximum of density-decrease from high to low pressure areas. Typical for the intensity of a pressure system is the pressure in the layer of maximum horizontal pressure gradient in an altitude of 8 km. The strength of the correlation between pressure in 8 km and density in 11 km is proportional to the strength of the processes in the null layer (Fig. 5a-d). The non-gradientic mass flow to high pressure areas in the null layer is great in high latitudes (high Coriolis parameter) and in winter (high meridional temperature gradient). In a low in formation more potential energy is available in winter, which can be transformed in kinetic energy of the winds in the null layer.

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Diese Arbeit wurde unterstützt vom US-Department of the Army, European Research Office, unter Kontrakt Nr. DA-91-591-EUC 2847.  相似文献   

Toward a radiometric ice clock: uranium ages of the Dome C ice core     

Sarah Aciego  Bernard Bourdon  Jakob Schwander  Heinrich Baur  Alessandro Forieri 《Quaternary Science Reviews》2011,30(19-20):2389-2397

Ice sheets and deep ice cores have yielded a wealth of paleoclimate information based on continuous dating methods while independent radiometric ages of ice have remained elusive. Here we demonstrate the application of (²³⁴U/²³⁸U) measurements to dating the EPICA Dome C ice core based on the accumulation of ²³⁴U in the ice matrix from recoil during ²³⁸U decay out of dust bound within the ice. Measured (²³⁴U/²³⁸U) activity ratios within the ice generally increase with depth while the surface areas of the dust grains are relatively constant. Using a newly designed device for measuring surface area for small samples, we were able to estimate reliably the recoil efficiency of nuclides from dust to ice. The resulting calculated radiometric ages range between 80 ka and 870 ka. Measured samples in the upper 3100 m fall on the previously published age-depth profile. Samples in the 3200–3255 m section show a marked change from 723–870 ka to 85 ka indicating homogenization of the deep ice prior to resetting of the (²³⁴U/²³⁸U) age in the basal layers. The mechanism for homogenization is likely enhanced lateral ice flow due to high basal melting and geothermal heat flux.  相似文献   

Olivier Reubi receives the 2008 Paul Niggli Medal     

Christoph Heinrich  Michael Dungan 《Swiss Journal of Geoscience》2009,102(2):371-372

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Sedimentology of the December 26, 2004, Sumatra tsunami deposits in eastern India (Tamil Nadu) and Kenya     

Heinrich Bahlburg  Robert Weiss 《International Journal of Earth Sciences》2007,96(6):1195-1209

The December 26, 2004 Sumatra tsunami caused severe damage at the coasts of the Indian ocean. We report results of a sedimentological study of tsunami run-up parameters and the sediments laid down by the tsunami at the coast of Tamil Nadu, India, and between Malindi and Lamu, Kenya. In India, evidence of three tsunami waves is preserved on the beaches in the form of characteristic debris accumulations. We measured the maximum run-up distance at 580 m and the maximum run-up height at 4.85 m. Flow depth over land was at least 3.5 m. The tsunami deposited an up to 30 cm thick blanket of moderately well to well-sorted coarse and medium sand that overlies older beach deposits or soil with an erosional unconformity. The sand sheet thins inland without a decrease of grain-size. The deposits consist frequently of three layers. The lower one may be cross-bedded with foresets dipping landward and indicating deposition during run-up. The overlying two sand layers are graded or parallel-laminated without indicators of current directions. Thus, it remains undecided whether they formed during run-up or return flow. Thin dark laminae rich in heavy minerals frequently mark the contacts between successive layers. Benthic foraminifera indicate an entrainment of sediment by the tsunami from water depths less than ca. 30 m water depth. On the Indian shelf these depths are present at distances of up to 5 km from the coast. In Kenya only one wave is recorded, which attained a run-up height of 3 m at a run-up distance of ca. 35 m from the tidal water line at the time of the tsunami impact. Only one layer of fine sand was deposited by the tsunami. It consists predominantly of heavy minerals supplied to the sea by a nearby river. The sand layer thins landward with a minor decrease in grain-size. Benthic foraminifera indicate an entrainment of sediment by the tsunami from water depths less than ca. 30 m water depth, reaching down potentially to ca. 80 m. The presence of only one tsunami-related sediment layer in Kenya, but three in India, reflects the impact of only one wave at the coast of Kenya, as opposed to several in India. Grain-size distributions in the Indian and Kenyan deposits are mostly normal to slightly positively skewed and indicate that the detritus was entrained by the tsunami from well sorted pre-tsunami deposits in nearshore, swash zone and beach environments.  相似文献   

Microthermometry, Raman and LA-ICP-MS of Fluid Inclusions Constrain on Fluids Chemistry and Evolution of Carlin-Type Gold System, Guizhou, China: Implications for Ore Genesis     

Wen-chao Su　Christoph A. Heinrich　Thomas Pettke　Xing-chun Zhang　Rui-zhong Hu　Bin Xia 《矿物岩石地球化学通报》2006,25(Z1):192

The Shuiyindong and Yata Carlin-type gold deposits, located in Southwestern Guizhou, China, are hosted by Permianbioclastic limestone in the form of stratabound mineralization and Middle Triassic calcareous clastic rocks as fault-controlled mineralization, respectively. In these deposits, quartz crystals in the veins or veinlets associated with mineralization have contained several populations of fluid inclusions with relatively quite big size and clear paragenetic relationship of entrapment. Petrography, microthermometry, Raman and LA-ICPMS of fluid inclusions analyses are used to characterize fluids chemistry and their evolution of Carlin-type system in Guizhou.  相似文献