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41.
42.
Ioannis Liritzis and Helen Vassiliou assess the evidence that the Ancient Greeks saw the aurora borealis, and that it was a rare and special event, strongly enough associated with particular gods to build temples of unusual orientation.  相似文献   
43.
The stratified water column of the Black Sea is partitioned into oxic, suboxic, and euxinic zones, each characterized by different biogeochemical processes and by distinct microbial communities. In 2003, we collected particulate matter by large volume in situ filtration at the highest resolution to date for lipid biomarker analysis and bacterioplankton for enumeration of major prokaryotic groups. Abundances of several prokaryotic groups were estimated using CARD-FISH probes specific for Bacteria, Archaea (Crenarchaeota and Euryarchaeota), epsilonproteobacteria (mainly sulfide oxidizers) and sulfate reducing bacteria. We also measured a wide range of bacterial and archaeal lipid biomarkers. Depth distributions of diagnostic biomarkers are matched with zonation of microbial processes, including aerobic bacterial oxidation of methane, oxidation of ammonium by bacteria and archaea, metal reduction, and sulfide oxidation at the chemocline, and bacterial sulfate reduction and anaerobic oxidation of methane by archaea in the anoxic zone. Cell densities for archaea and sulfate reducing bacteria are estimated based on water column biomarker concentrations and compared with CARD-FISH results.  相似文献   
44.
We develop and test an algorithm for modeling and removing elevation error in kinematic GPS trajectories in the context of a kinematic GPS survey of the salar de Uyuni, Bolivia. Noise in the kinematic trajectory ranges over 15 cm and is highly autocorrelated, resulting in significant contamination of the topographic signal. We solve for a noise model using crossover differences at trajectory intersections as constraints in a least-squares inversion. Validation of the model using multiple realizations of synthetic/simulated noise shows an average decrease in root-mean-square-error (RMSE) by a factor of four. Applying the model to data from the salar de Uyuni survey, we find that crossover differences drop by a factor of eight (from an RMSE of 5.6 to 0.7 cm), and previously obscured topographic features are revealed in a plan view of the corrected trajectory. We believe that this algorithm can be successfully adapted to other survey methods that employ kinematic GPS for positioning.  相似文献   
45.
A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A2Π3/2 ← X2Π3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N2O/CF3I/N2 mixtures with O3 actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.  相似文献   
46.
Fluid inclusions in garnet, kyanite and quartz from microdiamond-bearing granulites in the Western Gneiss Region, Norway, document a conspicuous fluid evolution as the rocks were exhumed following Caledonian high- and ultrahigh-pressure (HP–UHP) metamorphism. The most important of the various fluid mixtures and daughter minerals in these rocks are: (N2 + CO2 + magnesian calcite), (N2 + CO2 + CH4 + graphite + magnesian calcite), (N2 + CH4), (N2 + CH4 + H2O), (CO2) and (H2O + NaCl + CaCl2 + nahcolite). Rutile also occurs in the N2 + CO2 inclusions as a product of titanium diffusion from the garnet host into the fluid inclusions. Volatiles composed of N2 + CO2 + magnesian calcite characterise the ambient metamorphic environment between HP–UHP (peak) and early retrograde metamorphism. During progressive decompression, the mole fraction of N2 increased in the fluid mixtures; as amphibolite-facies conditions were reached, CH4 and later, H2O, appeared in the fluids, concomitant with the disappearance of CO2 and magnesian calcite. Graphite is ubiquitous in the host lithologies and fluid inclusions. Thermodynamic modelling of the metamorphic volatiles in a graphite-buffered C-O-H system demonstrates that the observed metamorphic volatile evolution was attainable only if the f O2 increased from c. −3.5 (±0.3) to −0.8 (±0.3) log units relative to the FMQ oxygen buffer. External introduction of oxidising aqueous solutions along a system of interconnected ductile shear zones adequately explains the dramatic increase in the f O2. The oxidising fluids introduced during exhumation were likely derived from dehydration of oceanic crust and continental sediments previously subducted during an extended period of continental collision in conjunction with the Caledonian orogeny. Received: 15 December 1997 / Accepted: 25 May 1998  相似文献   
47.
This paper examines similarities and differences in the emergence of high-tech enterprise and the growth of associated industry in Cambridgeshire and Oxfordshire since the 1960s. These cases are viewed as instances of a generic phenomenon: the emergence and growth of the science-based ‘innovative milieu’. A conceptual scheme drawn from complexity studies is used to introduce explanatory coherence into the apparently scattered and disconnected factors relevant to the genesis of high-tech milieux.  相似文献   
48.
The amount of hydroxonium or hydroxyl ion sorbed by the sodium form of clays (kaolin, illite or montmorillonite) has been found to increase in proportion with the amount added (i.e., data fits a Boedeker type equation). The adsorptive capacities, and bonding strengths (as evaluated from Langmuir isotherm plots) varied with clay type and nature of the adsorbing species (values for OH? being greater than for H+).The presence of clay suspensions reduced the pH required for total precipitation of heavy metal ions (e.g., Cu, Pb, Cd, Zn), as hydroxy species, and this behaviour has been re-examined in terms of observed pM, pOH relationships and the effect of ligand additions.  相似文献   
49.
Concentrations of metals in mature females of the mussel Choromytilus meridionalis are approximately twice those in males and some other trace elements also differ according to sex. If this species is to be used as an indicator of trace-metal pollution, comparative data should relate to individuals of similar size and care must be taken to determine whether differences in trace-metal content are the result of seasonal variations or reflect abnormal metal uptake.  相似文献   
50.
A proxy climate record from a raised bog in County Fermanagh, Northern Ireland, is presented. The record spans the interval between 2850 cal. yr BC and cal. yr AD 1000 and chronological control is achieved through the use of tephrochronology and 14C dating, including a wiggle‐match on one section of the record. Palaeoclimatic inferences are based on a combination of a testate amoebae‐derived water table reconstruction, peat humification and plant macrofossil analyses. This multiproxy approach enables proxy‐specific effects to be identified. Major wet shifts are registered in the proxies at ca. 1510 cal. yr BC, 750 cal. yr BC and cal. yr AD 470. Smaller magnitude shifts to wetter conditions are also recorded at ca. 380 cal. yr BC, 150 cal. yr BC, cal. yr AD 180, and cal. yr AD 690. It is hypothesised that the wet shifts are not merely local events as they appear to be linked to wider climate deteriorations in northwest Europe. Harmonic analysis of the proxies illustrates statistically significant periodicities of 580, 423–373, 307 and 265 years that may be related to wider Holocene climate cycles. This paper illustrates how the timing of climate changes registered in peat profiles records can be precisely constrained using tephrochronology to examine possible climatic responses to solar forcing. Relying on interpolated chronologies with considerable dating uncertainty must be avoided if the climatic responses to forcing mechanisms are to be fully understood. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
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