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Sedimentary basins containing igneous intrusions within sedimentary reservoir units represent an important risk in petroleum exploration. The Upper Triassic to Lower Jurassic sediments at Wilhelm?ya(Svalbard) contains reservoir heterogeneity as a result of sill emplacement and represent a unique case study to better understand the effect of magmatic intrusions on the general burial diagenesis of siliciclastic sediments. Sills develop contact metamorphic aureoles by conduction as presented in many earlier studies. However, there is significant impact of localized hydrothermal circulation systems affecting reservoir sediments at considerable distance from the sill intrusions. Dolerite sill intrusions in the studied area are of limited vertical extent(~12 m thick), but created localized hydrothermal convection cells affecting sediments at considerable distance(more than five times the thickness of the sill)from the intrusions. We present evidence that the sedimentary sequence can be divided into two units:(1) the bulk poorly lithified sediment with a maximum burial temperature much lower than 60-70 ℃,and(2) thinner intervals outside the contact zone that have experienced hydrothermal temperatures(around 140 ℃). The main diagenetic alteration associated with normal burial diagenesis is minor mechanical plastic deformation of ductile grains such as mica. Mineral grain contacts show no evidence of pressure dissolution and the vitrinite reflectance suggests a maximum temperature of ~40 ℃. Contrary to this, part of the sediment, preferentially along calcite cemented flow baffles, show evidence of hydrothermal alteration. These hydrothermally altered sediment sections are characterized by recrystallized carbonate cemented intervals. Further, the hydrothermal solutions have resulted in localized sericitization(illitization) of feldspars, albitization of both K-feldspar and plagioclase and the formation of fibrous illite nucleated on kaolinite. These observations suggest hydrothermal alteration at T 120-140 ℃ at distances considerably further away than expected from sill heat dissipation by conduction only, which commonly affect sediments about twice the thickness of the sill intrusion. We propose that carbonate-cemented sections acted as flow baffles already during the hydrothermal fluid mobility and controlled the migration pathways of the buoyant hot fluids. Significant hydrothermally induced diagenetic alterations affecting the porosity and hence reservoir quality was not noted in the noncarbonate-cemented reservoir intervals.  相似文献   
84.
Accurate simulation of flow and transport processes in fractured rocks requires that flow in fractures and shear zones to be coupled with flow in the porous rock matrix. To this end, we will herein consider a single-continuum approach in which both fractures and the porous rock are represented as volumetric objects, i.e., as cells in an unstructured triangular grid with a permeability and a porosity value associated with each cell. Hence, from a numerical point of view, there is no distinction between flow in the fractures and the rock matrix. This enables modelling of realistic cases with very complex structures. To compute single-phase advective transport in such a model, we propose to use a family of higher-order discontinuous Galerkin methods. Single-phase transport equations are hyperbolic and have an inherent causality in the sense that information propagates along streamlines. This causality is preserved in our discontinuous Galerkin discretization. We can therefore use a simple topological sort of the graph of discrete fluxes to reorder the degrees-of-freedom such that the discretized linear system gets a lower block-triangular form, from which the solution can be computed very efficiently using a single-pass forward block substitution. The accuracy and utility of the resulting transport solver is illustrated through several numerical experiments.  相似文献   
85.
Since 2005, five different ballast water management systems (BWMSs) based on chlorination treatment have been tested by Norwegian Institute for Water Research (NIVA) according to guidelines from the International Maritime Organization (IMO). 25% and >50% of all the tested discharge samples exhibited acute and chronic toxic effects on algae, respectively. In most cases this toxicity was plausibly caused by a high free residual oxidant (FRO) level (>0.08 mg Cl/l). Of the 22 disinfection by-products (DBPs) that were identified in treated water at discharge, four compounds were at times found at concentrations that may pose a risk to the local aquatic environment. However, there seemed to be no clear indication that the measured DBP concentrations contributed to the observed algal toxicity. The addition of methylcellulose instead of lignin in the test water to comply with IMO requirements seemed to limit the formation of DBP.  相似文献   
86.
Continental flood basalts (CFB) are considered as potential CO2 storage sites because of their high reactivity and abundant divalent metal ions that can potentially trap carbon for geological timescales. Moreover, laterally extensive CFB are found in many place in the world within reasonable distances from major CO2 point emission sources. Based on the mineral and glass composition of the Columbia River Basalt (CRB) we estimated the potential of CFB to store CO2 in secondary carbonates. We simulated the system using kinetic dependent dissolution of primary basalt-minerals (pyroxene, feldspar and glass) and the local equilibrium assumption for secondary phases (weathering products). The simulations were divided into closed-system batch simulations at a constant CO2 pressure of 100?bar with sensitivity studies of temperature and reactive surface area, an evaluation of the reactivity of H2O in scCO2, and finally 1D reactive diffusion simulations giving reactivity at CO2 pressures varying from 0 to 100?bar. Although the uncertainty in reactive surface area and corresponding reaction rates are large, we have estimated the potential for CO2 mineral storage and identified factors that control the maximum extent of carbonation. The simulations showed that formation of carbonates from basalt at 40?C may be limited to the formation of siderite and possibly FeMg carbonates. Calcium was largely consumed by zeolite and oxide instead of forming carbonates. At higher temperatures (60 ?C 100?C), magnesite is suggested to form together with siderite and ankerite. The maximum potential of CO2 stored as solid carbonates, if CO2 is supplied to the reactions unlimited, is shown to depend on the availability of pore space as the hydration and carbonation reactions increase the solid volume and clog the pore space. For systems such as in the scCO2 phase with limited amount of water, the total carbonation potential is limited by the amount of water present for hydration of basalt.  相似文献   
87.
利用一个全球海气耦合模式(BCM),结合观测资料,讨论了热带太平洋强迫对北大西洋年际气候变率的影响.研究表明,BCM能够相对合理地模拟赤道太平洋的年际变率模态及相应的海温距平型和大气遥相关型,尽管其准3年的振荡周期过于规则.来自数值模式和观测上的证据都表明,北大西洋冬季海温的主导性变率模态,即自北而南出现的"-+-"的海温距平型,受到来自热带太平洋强迫的显著影响,其正位相与赤道中东太平洋冷事件相对应.换言之,赤道太平洋暖事件的发生,在太平洋-北美沿岸激发出PNA遥相关型,进而通过在北大西洋产生类似NAO负位相的气压距平型,削弱本来与NAO正位相直接联系的三核型海温距平.北大西洋三核型海温距平对热带太平洋强迫的响应,要滞后2-3个月的时间.  相似文献   
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