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31.
The building-up of the Andean Range is linked to the subduction of the Pacific lithosphere beneath the South American plate. However, the formation of the Central Andes is marked by continental crustal shortening, whereas accretion and underplating of exotic oceanic terranes occurred in the northern Andes. The study of various magmatic and metamorphic rocks exhumed in the Western Cordillera of Ecuador by Miocene transpressive faults enables us to constrain the nature and thermal evolution of the crustal root of this part of Ecuador. These rocks are geochemically similar to oceanic plateau basalts. The thermobarometric peak conditions of a granulite and an amphibolite indicate temperatures of 800–850?°C and pressures less than 6–9 kbar (lack of garnet). The abnormally high geothermal gradient (≈40?°C?km?1) is probably due to the activity of the magmatic arc, which developed on the accreted oceanic terranes after Late Eocene times, and may have provoked the re-mobilisation of deeply underplated oceanic material during the genesis of the Neogene to Recent arc. To cite this article: É. Beaudon et al., C. R. Geoscience 337 (2005).  相似文献   
32.
The impact of dietary and water exposure on the accumulation and distribution of cadmium (Cd) in subcellular components of the polychaete Capitella sp. I was investigated. Worms were exposed to either dissolved Cd alone ('Water-Only' treatments; WO) or diet-bound Cd alone ('Algae-bound Only' treatments; AO). Thus, WO worms were starved and AO worms were fed. Differential centrifugation was used to fractionate worm homogenates into debris- (DE), mitochondrial- (MI), microsomal- (MC) and cytosolic- (CY) fractions, and the concentration of Cd in these fractions was quantified by radiometric analysis using the specific activity of the (109)Cd radioisotope. Neither exposure route nor Cd exposure affected the total protein content in the worms. However, fed, but not starved worms relocated proteins from the mitochondria to the cytosol in response to Cd exposure. In systems without Cd addition, starvation likewise influenced the distribution of protein between mitochondria and cytosol. Cutaneous uptake and accumulation of Cd from the water was related to surface area while dietary uptake was influenced by the amount of sediment passing through the gut. Irrespective of exposure route, Cd was accumulated primarily in the debris fraction although comparisons between the treatments indicated that relatively less Cd was located in DE and more in MI, MC and CY fractions in worms in AO compared to worms in WO. Cd per unit protein in DE and MI fractions was twice as high as in MC and CY fractions in WO, whereas MC contained the highest Cd content followed by MI, DE and CY fractions in AO worms. Our results stress the importance of exposure route for the internal distribution and toxicity of Cd to deposit feeders such as Capitella sp. I.  相似文献   
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In 2005 the Geostandards and Geoanalytical Research editorial team, in the true spirit of scientific endeavour, embarked on an experiment of our own. We decided to trial a new kind of review, somewhat different from those more typically observed in journals, and one that would provide readers with a summary of analytical developments across a broad range of topics appropriate to the Earth sciences. The first contribution of this kind appeared in 2005, and reported on developments in 2003 (Hergt et al. 2005). The second, this time a biennial review, was published in 2006 and reported on highlights of the 2004 and 2005 literature (Hergt et al. 2006). Based on reprint requests, positive remarks at conferences and strong citations we consider the experiment a resounding success and proudly present here the third in this series. This comprises six individual review sections that cover the main analytical technologies and topical application fields in geoanalysis and geochemistry, including geological and environmental reference materials, ICP‐thermal and secondary ionisation‐mass spectrometry, as well as neutron activation analysis, X‐ray fluorescence and atomic absorption spectrometry.  相似文献   
35.
This collection of articles represents the fourth in a series of reviews in which authors have aimed at capturing the key advances in a range of analytical fields ( Hergt et al. 2005, 2006, 2008 ). The publication period under review is 2008–2009 and the intention here is to provide readers with a summary of the most influential developments published during this period, across a broad range of topics appropriate to the Earth and environmental sciences. Most authors comment on the ways in which the emphases of research in their specific fields of examination have changed over time. All note an increase in rigour and focus on data quality. Whether advances have taken place in instrumentation, sample manipulation or data deconvolution, there are a large number of dedicated scientists out there contributing to the high quality of geochemical data employed in geological and environmental research.  相似文献   
36.
In this study we have obtained 17 cosmogenic exposure ages from three well‐developed moraine systems – Halland Coastal Moraines (HCM), Göteborg Moraine (GM) and Levene Moraine (LM) – which were formed during the last deglaciation in southwest Sweden by the Scandinavian Ice Sheet (SIS). The inferred ages of the inner HCM, GM and LM are 16.7 ± 1.6, 16.1 ± 1.4 and 13.6 ± 1.4 ka, respectively, which is slightly older than previous estimates of the deglaciation based on the minimum limiting radiocarbon ages and pollen stratigraphy. During this short interval from 16.7 ± 1.6 to 13.6 ± 1.4 ka a large part (100–125 km) of the marine‐based sector of the SIS in southwest Sweden was deglaciated, giving an average ice margin retreat between 20 to 50 m a?1. The inception of the deglaciation pre‐dated the Bølling/Allerød warming, the rapid sea level rise at 14.6 cal. ka BP and the first inflow of warm Atlantic waters into Skagerrak. We suggest that ice retreat in southwest Sweden is mainly a dynamical response governed by the disintegration of the Norwegian Channel Ice Stream and not primarily driven by climatic changes. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
37.
The Late Weichselian ice sheet of western Svalbard was characterized by ice streams and inter‐ice‐stream areas. To reconstruct its geometry and dynamics we investigated the glacial geology of two areas on the island of Prins Karls Forland and the Mitrahalvøya peninsula. Cosmogenic 10Be surface exposure dating of glacial erratics and bedrock was used to constrain past ice thickness, providing minimum estimates in both areas. Contrary to previous studies, we found that Prins Karls Forland experienced a westward ice flux from Spitsbergen. Ice thickness reached >470 m a.s.l., and warm‐based conditions occurred periodically. Local deglaciation took place between 16 and 13 ka. At Mitrahalvøya, glacier ice draining the Krossfjorden basin reached >300 m a.s.l., and local deglaciation occurred at c. 13 ka. We propose the following succession of events for the last deglaciation. After the maximum glacier extent, ice streams in the cross‐shelf troughs and fjords retreated, tributary ice streams formed in Forlandsundet and Krossfjorden, and, finally, local ice caps were isolated over both Prins Karls Forland and Mitrahalvøya and their adjacent shelves.  相似文献   
38.
Advances in the chemical and isotopic characterisation of geological and environmental materials can often be ascribed to technological improvements in analytical hardware. Equally, the creation of novel methods of data acquisition and interpretation, including access to better reference materials, can also be crucial components enabling important breakthroughs. This biennial review highlights key advances in either instrumentation or data acquisition and treatment, which have appeared since January 2010. This review is based on the assessments by scientists prominent in each of the given analytical fields; it is not intended as an exhaustive summary, but rather provides insight from experts of the most significant advances and trends in their given field of expertise. In contrast to earlier reviews, this presentation has been formulated into a unified work, providing a single source covering a broad spectrum of geoanalytical techniques. Additionally, some themes that were not previously emphasised, in particular thermal ionisation mass spectrometry, accelerator‐based methods and vibrational spectroscopy, are also presented in detail.  相似文献   
39.
Luminescent lamination in a stalagmite from northern Norway is used to construct a ~2780-year long, floating record of annual growth rate. Thermal ionisation mass-spectrometric (TIMS) U–Th ages (n = 12) were determined along the growth axis and three subsample locations and ages (corrected and uncorrected for initial 230Th/232Th activity) were selected as anchor points for the floating chronology. On the basis of these anchor points, termination of growth occurred between AD 1729 and AD 1826. The annual banding records are used to evaluate the initial 230Th/232Th activity ratio adopted for correction of the U–Th ages. To achieve a reasonable fit between U–Th ages and estimates predicted by the anchored annual band age models, mean initial 230Th/232Th activity ratios of between 0.44 and 1.47 must be invoked. However, there remains a reasonable degree of scatter about the expected linear relationship between annual bands and U–Th chronology for individual subsamples indicating that the use of a single correction factor for Holocene stalagmites should be applied with caution.Stalagmite growth rate fluctuates on annual to centennial scale. The growth termination of the stalagmite presented here could have been a result of environmental change associated with the Little Ice Age, or, possibly local percolation pathway changes after an Ms  6 earthquake in the region in AD 1819. Stable-isotope data from the same axis of growth show a pattern similar to the large-scale growth rate variations, and these combined proxy records are interpreted as showing gradual cooling and/or shortening of the vegetation growth season for the last 3000 years.  相似文献   
40.
The vertical transport of contaminants from source areas is employed in many risk assessment models and screening tools in order to estimate the contaminant mass discharge (CMD) into underlying aquifers. The key parameters for estimating CMD are the contaminant source area and concentration, and the vertical water flux, the latter of which depends on the vertical hydraulic conductivity and the vertical hydraulic gradient in the subsurface. This study focuses on advancing the use of the combined membrane interface probe hydraulic profiling tool (MiHPT) to investigate the vertical hydraulic gradient across a clay till overlying a sandy aquifer at a contaminated site in Denmark. Only the HPT is necessary for the estimate of vertical hydraulic gradient. The hydraulic head, clay till thickness, and resulting vertical hydraulic gradients found using the MiHPT compared well with observations from nearby nested wells. The parameter with the largest discrepancy was the thickness of the clay till. The advantage of the MiHPT is its relatively quick depth discrete access to information regarding subsurface permeability, vertical hydraulic gradients and contaminant distribution across a site. In this case study, performance of additional dissipationtests during the HPT log to acquire determination of the vertical hydraulic gradient increased the cost by 3% compared to standard HPT logs.  相似文献   
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