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71.
72.
UPb geochronology provides an absolute time framework for the evolution of the Sigma gold deposit and surrounding rocks at Val d'Or, southern Abitibi subprovince. The Bourlamaque batholith, the largest pluton in the area, gives a 2699.8 ± 1.0 Ma UPb zircon age. This pluton cuts the Val d'Or Formation which hosts the mineralization. A UPb zircon age of 2704.9 ± 1.1 Ma on a felsic volcanic rock, the Colombière “rhyolite”, 13 km east of the mine dates that formation. The gold-bearing quartz vein system at Sigma is hosted by andesites and two generations of porphyry intrusions, all metamorphosed to the greenschist facies. The oldest porphyry (“porphyritic diorite”) shows the same deformation as the volcanic rocks, and has a 2703.7 ± 2.5 Ma UPb zircon age. The porphyritic diorite and volcanic rocks are cut by feldspar-porphyry dykes which post-date regional folding and have a 2694.0 ± 2.2 Ma UPb zircon age.Regional greenschist metamorphism has been dated directly, with a UPb date of 2684 ± 7 Ma on rutile in the Colombière “rhyolite”. The mineralization and hydrothermal alteration in the mine are superimposed on the metamorphic minerals. Hydrothermal rutile, from an alteration halo around the veins in andesite, has a 2599 ± 9 Ma UPb age. Textural evidence clearly indicates that the wall-rock alteration and vein filling are contemporaneous, and hence the vein system and gold mineralization appear to have developed at least 80 m.y. after the formation and metamorphism of host greenstones.  相似文献   
73.
A numerical model of the cloudy marine boundary layer is described and used to investigate the role of entrainment instability on the developing boundary layer. In general, previous studies have been limited to boundary layers capped by convectively stable inversions or have described only cumulus fields. Here we extend a stratus-capped boundary-layer model to consider the transition to a convectively unstable cloud layer capped by an inversion across which there is a rapid decrease in wet-bulb or equivalent potential temperature. In this case, the inversion is very active and the entrainment rate is determined by the active instability at the interface, in contrast to the mean turbulent motion within the boundary layer.The model is used to interpret the observed boundary layer from the JASIN experiment. Cool, dry air is modified by prolonged passage over increasingly warmer ocean which leads to the development of a convectively unstable cloud layer.  相似文献   
74.
The composition of chromian spinel in alpine-type peridotites has a large reciprocal range of Cr and Al, with increasing Cr# (Cr/(Cr+Al)) reflecting increasing degrees of partial melting in the mantle. Using spinel compositions, alpine-type peridotites can be divided into three groups. Type I peridotites and associated volcanic rocks contain spinels with Cr#<0.60; Type III peridotites and associated volcanics contain spinels with Cr#>0.60, and Type II peridotites and volcanics are a transitional group and contain spinels spanning the full range of spinel compositions in Type I and Type II peridotites. Spinels in abyssal peridotites lie entirely within the Type I spinel field, making ophiolites with Type I alpine-type peridotites the most likely candidates for sections of ocean lithosphere formed at a midocean ridge. The only modern analogs for Type III peridotites and associated volcanic rocks are found in arc-related volcanic and intrusive rocks, continental intrusive assemblages, and oceanic plateau basalts. We infer a sub-volcanic arc petrogenesis for most Type III alpine-type peridotites. Type II alpine-type peridotites apparently reflect composite origins, such as the formation of an island-arc on ocean crust, resulting in large variations in the degree and provenance of melting over relatively short distances. The essential difference between Type I and Type III peridotites appears to be the presence or absence of diopside in the residue at the end of melting.Based on an examination of co-existing rock and spinel compositions in lavas, it appears that spinel is a sensitive indicator of melt composition and pressure of crystallization. The close similarity of spinel composition fields in genetically related basalts, dunites and peridotites at localities in the oceans and in ophiolite complexes indicates that its composition reflects the degree of melting in the mantle source region. Accordingly, we infer from the restricted range of spinel compositions in abyssal basalts that the degree of mantle melting beneath mid-ocean ridges is generally limited to that found in Type I alpine-type peridotites. It is apparent, therefore, that the phase boundary OL-EN-DI-SP +meltOL-EN-SP+melt has limited the degree of melting of the mantle beneath mid-ocean ridges. This was clearly not the case for many alpine-type peridotites, implying very different melting conditions in the mantle, probably involving the presence of water.  相似文献   
75.
More finite strain data has been obtained from autochthonous Permian mudstones of the Alpes Maritimes, S.E. France. These new data were computed from field measurements of green spots on all available sections, deformed mudcracks and from the quantitative correlation between magnetic susceptibility anisotropy and finite strain in these rocks. Previously published finite strain data and the new results are presented on a series of structural maps and cross-sections for the Dôme de Barrot, the Tinée and Vionène region and the Roya region. As in previous studies difficulties arise in explaining the apparently variable extension parallel with the 100°, subhorizontal bedding-cleavage intersection: either this is real or there were large volume changes during the tectonic deformation. Study of quartz fibres, developed in deformed mudcracks in the Tinée valley, suggest that early in the tectonic history incremental stretching directions were parallel with the bedding—cleavage intersection, while later they were down-dip in the 100° trending cleavage. Since these Permian rocks have remained stuck to the Argentera basement they also record displacements and deformations in the basement. The early 100°, subhorizontal stretching is consistent with NW-SE dextral, strike-slip basement faulting, while later, down-dip stretching in the cleavage is consistent with contraction faults in the basement. This information and new palaeomagnetic data on the same samples are combined with recent geophysical evidence and regional tectonic studies, to provide a new precision to the tectonic history of this part of the Western Alpine External Zone.  相似文献   
76.
The toxicity of marine sediments in Victoria Harbour, Hong Kong   总被引:4,自引:0,他引:4  
When the toxicity of marine sediment in Hong Kong was evaluated, it was found that the seven sediments collected within Victoria Harbour were severely contaminated with heavy metals, at concentrations many times higher than those in sediments collected from outside the harbour. The highest metal content was recorded in site VS14 (located near the airport runway and the industrialized area), with copper, zinc, lead and chromium values of 3789, 610, 138 and 601 mg kg−1 dry wt, respectively. This site also had the greatest alkaline phosphatase activities (15 fluorescent intensity unit g−1 wet wt), the largest number of total coliforms (910 CFU g−1 wet wt) and sulphate-reducing bacteria (8.5 × 104 cells g−1 wet wt), implying that site VS14 was also contaminated with organic matter and nutrients. Sediment bioassays, Microtox and algal tests, demonstrated that sediment elutriates obtained from site VS14 were of greatest toxicity. The EC10 value in Microtox tests was 17% elutriate, and the 96-h IC50 values using Skeletonema costatum and Dunaliella tertiolecta were 40 and 79% elutriate, respectively. No toxic effects were found in sediment samples collected from the control site outside Victoria Harbour. Significant correlations were found between the results of the algal toxicity test (using S. costatum) and the coliform count and metal content of the sediments. The Microtox test was less sensitive than the algal bioassay, and no sediment elutriate, even from the site mostly contaminated by heavy metals, caused more than 50% inhibition of the light-emitting activity of the bacteria. In this study, S. costatum (the diatom) provided a more sensitive and reliable test species than D. tertiolecta (the flagellate) in differentiating the toxicity of marine sediments.  相似文献   
77.
It is suggested that the hydrothermal vents of the South Pacific Rise produce a beta-governed circulation at mid-depth, and that perhaps the associated plume of excess3He (Lupton and Craig [1]) points westward because of the dynamics of this circulation rather than as a passive tracer.  相似文献   
78.
Scattering of antiplane shear waves (SH) in two dimensions by surface and near-surface defects in a homogeneous, isotropic elastic semi-infinite medium has been studied. Attention has been focused here in the range of medium to long wavelengths. A combined finite element and analytical technique has been used to study the problems of scattering by semi-circular and triangular canyons. The results for the former case are compared with the known exact solution and those for the latter case are compared with some available approximate solutions. Finally a problem of multiple scattering by a triangular canyon and a nearby circular tunnel is studied. Numerical results are presented showing the effects of multiple scattering and different angles of incidence. These results are of interest in earthquake engineering.  相似文献   
79.
The production of metallic iron in silicate melts by the chemical reactions, 2Ti3+(melt) + Fe2+(melt) → 2Ti4+(melt) + Fe0(crystal)2Cr2+(melt) + Fe2+(melt) → 2Cr3+(melt) + Fe0(crystal)2Eu2+(melt)+ Fe2+(melt) → 2Eu3+(melt) + Fe0(crystal) has been demonstrated under experimental conditions in a simplified basaltic liquid, Such reactions may occur in lunar basalts and other reduced systems, and, thus, may aid in the understanding of the reduced nature of lunar basalts. The reactions were studied in a glass-forming Na-Ca-Mg-Al-silicate composition at a melt temperature of 1250°C and an imposed oxygen fugacity at the C/CO buffer (1 atm total pressure). Microtitrations of individually-doped samples were used in the quantitative assessment of their redox ratios and for the calibration of visible and near-infrared spectral absorptions. These spectral absorptions were then applied to the evaluation of the mutual redox interactions in dual-doped samples.  相似文献   
80.
Fluoride-hydroxyl exchange equilibria between phlogopite-pargasite and phlogopite-tremolite mineral pairs were experimentally determined at 1,173K, 500 bars and 1,073–1,173 K, 500 bars respectively. The distribution of fluorine between phlogopite and pargasite was found to favor phlogopite slightly, G ex . (1,173 K)=–1.71 kJ anion–1, while in the case of phlogopite-tremolite, fluorine was preferentially incorporated in the mica, G ex . (1,073)=– 5.67 kJ anion–1 and G ex . (1,173K)=–5.84 kJ anion–1. These results have yielded new values of entropy and Gibbs energy of formation for fluortremolite, S f =–2,293.4±16.0JK–1 mol–1 and G f = –11,779.3±25.0 kJ mol–1, respectively. In addition, F-OH mineral exchange equilibria support a recent molten oxide calorimetric value for the Gibbs energy of fluorphlogopite, G f =–6,014.0±7.0 kJ mol–1, which is approximately 40 kJ mol–1 more exothermic than the tabulated value.This work performed in part at Sandia National Laboratories supported by the U.S. Department of Energy, DOE, under contract number DE-AC04-76DP00789  相似文献   
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