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261.
The large-scale post-perihelion evolution of the dust tail in Comet C/1995 O1 (Hale–Bopp) was monitored with Schmidt telescope exposures at the European Southern Observatory (ESO) La Silla in Chile. In early October 1997 signatures of a peculiar dust-tail appeared as straight, but diffuse extensions in the northern and southern coma hemisphere. With the approach of the Earth to the orbital plane of the comet a needle-like anti-tail with a similar, but much longer counterpart in the region of the normal dust tail formed. In early January 1998, i.e., close to the plane crossing, the anti-tail pointed towards position angle 190° and was at least 0.4°long, its counter part extended over more than 5° into oppositedirection. During February and March 1998 the position angles of both features increased by more than 40$°– while their appearance became shorter, wider and more diffuse again. Thepeculiar dust tail was last observed in April 1998.Modeling of the dust tail dynamics shows that the anti-tail andpeculiar tail phenomenon observed is formed by a neck-line structureof heavy dust grains released around perihelion passage. Two scenariiare introduced to explain the extension of the anti-tail feature:(1) grains ejected about 20 days post-perihelion with a initial velocity of 170 m/s in radial direction towards the Sun and(2) grains released about 60–80 days before perihelion at a speed of70m/s into the orbital plane and against the motion directionof the comet. The out-of-plane velocity component of the dust wasless than 25 m/s. Both scenarios require dust of < 0.001to be involved, i.e., grains of at least mm-size. The rather symmetric shading of the neck-line structure before and after passage of theEarth through the orbital plane of the comet in early January 1998 supports the idea that dust of both scenarii may have contributed to the phenomenon.  相似文献   
262.
The application of finite element methods (FEM) is often restricted by the available computer capacity and the computing costs. The purpose of this paper, therefore, is, to present test results and to discuss possible ways of achieving a substantial reduction in computing times. Dividing the numerical analysis into the five levels–hardware, software, element-mesh and element-type, iteration technique (approximation of non-linearity) and constitutive model–one can show that the computing time can be reduced by about 20 per cent at every level. In particular, the use of the modified Newton-Raphson method for approximation of non-linearity and the constitutive model–apart from the theoretical concept (elastoplastic, hypoelastic etc.)—must be formulated in a manner which does not produce substantial changes in the coefficients of the material matrix caused by small stress changes. On the whole, computing time can be reduced to about 10 per cent of present computing costs. Thus, it would even be economically viable to solve three-dimensional non-linear problems by FEM.  相似文献   
263.
We discuss the implications of a lithospheric model of the Moroccan Atlas Mountains based on topography, heat flow, gravity and geoid anomalies, taking into account the regional geology. The NW African cratonic lithosphere, some 160–180 km thick, thins to c. 80 km beneath the Atlas fold-thrust belts, in contrast with the shortening regime prevailing there since the early Cenozoic. This fact explains several geological and geophysical features as high topography with modest tectonic shortening, the occurrence of alkaline magmatism contemporaneous to compression, the absence of large crustal roots to support elevation, the scarce development of foreland basins, and a marked geoid high. The modelled lithosphere thinning is related to a thermal upwelling constrained between the Iberia–Africa convergent plate boundary and the Saharan craton.  相似文献   
264.
265.
Gradients controlling natural attenuation of ammonium   总被引:1,自引:0,他引:1  
Oxidation of reduced pollutants such as in groundwater often takes place at steep redox gradients where oxygenated water is being mixed into polluted water such as landfill leachate. In order to identify controlling parameters and quantify the influence of environmental factors for degradation, sensitivity analysis was performed by means of scenario specific numerical modelling. Geometrical factors such as aquifer thickness have been shown to be very influential on the capability of natural attenuation of pollutants in groundwater. The scenarios investigated here include biodegradation at redox gradients in groundwater, so called fringe processes, for (i) a partly contaminated aquifer with two reaction fronts, (ii) and a spatially variable aquifer thickness. In addition, (iii) the influence of groundwater recharge and (iv) restricted supply of O2 to contaminated water by slow dispersion and diffusion across the capillary fringe are investigated. Contaminated aquifer thickness, zones of enhanced mixing due to flow focussing and diffusion/dispersion coefficients in the capillary fringe are identified qualitatively as controlling factors for natural attenuation under complex conditions, whereas predictive functions will require further research.  相似文献   
266.
The diffusion, substitution mechanism and solubility limits of Zr and Hf in synthetic forsterite (Mg2SiO4) and San Carlos olivine (Mg0.9Fe0.1)2SiO4 have been investigated between 1,200 and 1,500 °C as a function of the chemical potentials of the components in the system MgO(FeO)–SiO2–ZrO2(HfO2). The effect of oxygen fugacity and crystallographic orientation were also investigated. The solubilities of Zr in forsterite are highest and diffusion fastest when the coexisting three-phase source assemblage includes ZrSiO4 (zircon) or HfSiO4 (hafnon), and lower and slower, respectively, when the source assemblage includes MgO (periclase). This indicates that Zr and Hf substitute on the octahedral sites in olivine, charge balanced by magnesium vacancies. Diffusion is anisotropic, with rates along the crystal axes increasing in the order a < b < c. The generalized diffusion relationship as a function of chemical activity (as \(a_{{{\text{SiO}}_{2} }}\)), orientation and temperature is: \(logD_{\text{Zr}} = \frac{1}{4}loga_{{{\text{SiO}}_{2} }} + logD_{0} - \left( {\frac{{368 \pm 17\;{\text{kJ}}\;{\text{mol}}^{ - 1} }}{{2.303\;{\text{RT}}}}} \right)\) where the values of log D 0 are ?3.8(±0.5), ?3.4(±0.5) and ?3.1(±0.5) along the a, b and c axes, respectively. Most experiments were conducted in air (fO2 = 10?0.68 bars), but one at fO2 = 10?11.2 bars at 1,400 °C shows no resolvable effect of oxygen fugacity on Zr diffusion. Hf is slightly more soluble in olivine than Zr, but diffuses slightly slower. Diffusivities of Zr in experiments in San Carlos olivine at 1,400 °C, fO2 = 10?6.6 bars are similar to those in forsterite at the same conditions, showing that the controls on diffusivities are adequately captured by the simple system (nominally iron-free) experiments. Diffusivities are in good agreement with those measured by Spandler and O’Neill (Contrib Miner Petrol 159:791–818, 2010) in San Carlos olivine using silicate melt as the source at 1,300 °C, and fall within the range of most measurements of Fe–Mg inter-diffusion in olivine at this temperature. Forsterite–melt partitioning experiments in the CaO–MgO–Al2O3–SiO2–ZrO2/HfO2 show that the interface concentrations from the diffusion experiments represent true equilibrium solubilities. Another test of internal consistency is that the ratios of the interface concentrations between experiments buffered by Mg2SiO4 + Mg2Si2O6 + ZrSiO4 or Mg2SiO4 + ZrSiO4 + ZrO2 (high silica activity) to those buffered by Mg2SiO4 + MgO + ZrO2 (low silica activity) agree well with the ratios calculated from thermodynamic data. This study highlights the importance of buffering chemical potentials in diffusion experiments to provide constraints on the interface diffusant concentrations and hence validate the assumption of interface equilibrium.  相似文献   
267.
Climate sensitivity estimated from ensemble simulations of glacial climate   总被引:1,自引:0,他引:1  
The concentration of greenhouse gases (GHGs) in the atmosphere continues to rise, hence estimating the climate system’s sensitivity to changes in GHG concentration is of vital importance. Uncertainty in climate sensitivity is a main source of uncertainty in projections of future climate change. Here we present a new approach for constraining this key uncertainty by combining ensemble simulations of the last glacial maximum (LGM) with paleo-data. For this purpose we used a climate model of intermediate complexity to perform a large set of equilibrium runs for (1) pre-industrial boundary conditions, (2) doubled CO2 concentrations, and (3) a complete set of glacial forcings (including dust and vegetation changes). Using proxy-data from the LGM at low and high latitudes we constrain the set of realistic model versions and thus climate sensitivity. We show that irrespective of uncertainties in model parameters and feedback strengths, in our model a close link exists between the simulated warming due to a doubling of CO2, and the cooling obtained for the LGM. Our results agree with recent studies that annual mean data-constraints from present day climate prove to not rule out climate sensitivities above the widely assumed sensitivity range of 1.5–4.5°C (Houghton et al. 2001). Based on our inferred close relationship between past and future temperature evolution, our study suggests that paleo-climatic data can help to reduce uncertainty in future climate projections. Our inferred uncertainty range for climate sensitivity, constrained by paleo-data, is 1.2–4.3°C and thus almost identical to the IPCC estimate. When additionally accounting for potential structural uncertainties inferred from other models the upper limit increases by about 1°C.  相似文献   
268.
Elevated groundwater salinity associated with produced water, leaching from landfills or secondary salinity can degrade arable soils and potable water resources. Direct-push electrical conductivity (EC) profiling enables rapid, relatively inexpensive, high-resolution in-situ measurements of subsurface salinity, without requiring core collection or installation of groundwater wells. However, because the direct-push tool measures the bulk EC of both solid and liquid phases (ECa), incorporation of ECa data into regional or historical groundwater data sets requires the prediction of pore water EC (ECw) or chloride (Cl?) concentrations from measured ECa. Statistical linear regression and physically based models for predicting ECw and Cl? from ECa profiles were tested on a brine plume in central Saskatchewan, Canada. A linear relationship between ECa/ECw and porosity was more accurate for predicting ECw and Cl? concentrations than a power-law relationship (Archie’s Law). Despite clay contents of up to 96%, the addition of terms to account for electrical conductance in the solid phase did not improve model predictions. In the absence of porosity data, statistical linear regression models adequately predicted ECw and Cl? concentrations from direct-push ECa profiles (ECw = 5.48 ECa + 0.78, R 2 = 0.87; Cl? = 1,978 ECa – 1,398, R 2 = 0.73). These statistical models can be used to predict ECw in the absence of lithologic data and will be particularly useful for initial site assessments. The more accurate linear physically based model can be used to predict ECw and Cl? as porosity data become available and the site-specific ECw–Cl? relationship is determined.  相似文献   
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