Cloning and analysis of the CYP1A promoter from the atlantic killifish (Fundulus heteroclitus)     

Wade H. Powell  Hilary G. Morrison  E. Jennifer Weil  Sibel I. Karchner  Mitchell L. Sogin  John J. Stegeman  Mark E. Hahn 《Marine environmental research》2004,58(2-5):119

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Burial dolomitization driven by modified seawater and basal aquifer‐sourced brines: Insights from the Middle and Upper Devonian of the Western Canadian Sedimentary Basin     

Jack Stacey  Cathy Hollis  Hilary Corlett  Ardiansyah Koeshidayatullah 《Basin Research》2021,33(1):648-680

Dolomitization in the Western Canadian Sedimentary Basin has been extensively researched, producing vast geochemical datasets. This provides a unique opportunity to assess the regional sources and flux of dolomitizing fluids on a larger scale than previous studies. A meta‐analysis was conducted on stable isotope, strontium isotope (⁸⁷Sr/⁸⁶Sr), fluid inclusion and lithium‐rich formation water data published over 30 years, with new petrographic, X‐ray diffraction, stable isotope and rare‐earth element (REE+Y) data. The Middle to Upper Devonian Swan Hills Formation, Leduc Formation and Wabamun Group contain replacement dolomite (RD) cross‐cut by stylolites, suggesting replacement dolomitization occurred during shallow burial. Stable isotope, REE+Y and ⁸⁷Sr/⁸⁶Sr data indicate RD formed from Devonian seawater, then recrystallized during burial. Apart from the Wabamun Group of the Peace River Arch (PRA), saddle dolomite cement (SDC) is more δ¹⁸O_(PDB) depleted than RD, and cross‐cuts stylolites, suggesting precipitation during deep burial. SDC ⁸⁷Sr/⁸⁶Sr data indicate contributions from ⁸⁷Sr‐rich basinal brines in the West Shale Basin (WSB) and PRA, and authigenic quartz/albite suggests basinal brines interacted with underlying clastic aquifers before ascending faults into carbonate strata. The absence of quartz/albite within dolomites of the East Shale Basin (ESB) suggests dolomitizing fluids only interacted with carbonate strata. We conclude that replacement dolomitization resulted from connate Devonian seawater circulating through aquifers and faults during shallow burial. SDC precipitated during deep burial from basinal brines sourced from basal carbonates (ESB) and clastic aquifers (WSB, PRA). Lithium‐rich formation waters suggest basinal brines originated as residual evapo‐concentrated Middle Devonian seawater that interacted with basal aquifers and ascended faults during the Antler and Laramide Orogenies. These results corroborate those of previous studies but are verified by new integrated analysis of multiple datasets. New insights emphasize the importance of basal aquifers and residual evapo‐concentrated seawater in dolomitization, which is potentially applicable to other regionally dolomitized basins.  相似文献   

Regional metamorphism and the alteration response of selected Silurian to Devonian mineral systems in the Nymagee area,Central Lachlan Orogen,New South Wales: a HyLogger™ case study     

P. M. Downes  D. B. Tilley  J. A. Fitzherbert  M. E. Clissold 《Australian Journal of Earth Sciences》2016,63(8):1027-1052

The southern Cobar Superbasin includes the Mount Hope, Cobar and Rast troughs and adjacent Winduck, Mouramba and Kopyje shelves. These stratotectonic units host a range of mineral systems within deformed upper Silurian to Lower Devonian rocks. Despite the metallogenic importance of the terrane the regional metamorphic- and alteration-related mineral assemblages have not been systematically described until now. Here, we present a study using the HyLogger? spectral scanner to systematically map changes in both background and alteration-related mineralogy for 14 mineral systems across the Nymagee area. The study found that, with the exception of the late diagenetic zone assemblages associated with the Winduck Shelf, the mineral assemblages for zones away from mineralisation are consistent with uniform sub- to lowest-greenschist facies metamorphic conditions, with no evidence for a regional, thermal field gradient across the basin. By contrast, proximal to mineralisation, there are significant changes in alteration-related mineral abundances and species reflecting elevated fluid temperatures. For several zones, including Browns Reef, Great Central, Hera, May Day, Nymagee and Shuttleton, there is a systematic change in chlorite composition from Fe- and/or Fe–Mg-chlorites to more Mg-rich varieties towards mineralisation. In addition, talc was noted for May Day, Mineral Hill and Shuttleton. The change in chlorite composition suggests that these ore-forming fluids were undersaturated with respect to iron. Furthermore, although present in discrete zones, carbonate alteration is not a dominant alteration type. However, at Manuka and Blue Mountain, the mineralisation is associated with carbonate-rich (calcite, ankerite, dolomite) units that have been dolomitised (Mg alteration) but not all dolomite-rich zones are mineralised. For Mineral Hill, there are systematic changes to mineral species/chemistry with observed data consistent with Parkers Hill being proximal to the centre of a mineralising system. The G and H Lode area (Southern Ore Zone) is slightly more distal whereas the Pearse deposit may represent a zone more distal again.  相似文献   

Diatom responses to late-glacial and early-Holocene environmental changes at Kråkenes, western Norway   总被引：1，自引：0，他引：1  

E.G. Bradshaw  V. J. Jones  H.J.B. Birks  Hilary H. Birks 《Journal of Paleolimnology》2000,23(1):21-34

A stratigraphic diatom sequence is presented for the period from 13,870-9,170 cal BP from Kråkenes Lake, western Norway. Changes in species assemblages are discussed with reference to the changing environmental conditions in the Allerød, Younger Dryas, and the early Holocene and to the development of the aquatic ecosystem. The site is sensitive to acidification, and diatom-based transfer functions are applied to estimate the past pH status. The combination of rapid sediment accumulation together with an excellent calibrated radiocarbon chronology means that the rate of inferred pH change and associated increase in [H⁺] can be assessed and compared with recent, anthropogenically acidified situations.The Allerød diatom assemblages are dominated by benthic taxa particularly Fragilaria species, indicating an unproductive, alkaline, turbid, and immature system. Diatoms are absent in the early part of the Younger Dryas, but subsequently a sparse planktonic flora develops reflecting decreased turbidity and/or increased nutrient supply. A clear sequence of diatom assemblages is seen in the early Holocene. A short-lived peak of Stephanodiscus species indicating a period of increased nutrient availability occurred at ca. 11,500 cal BP. Throughout the early Holocene, acid-tolerant species increasingly replaced less acidophilous, circumneutral taxa.The lake became slightly more acid during the Allerød, but this was statistically insignificant in a trend test involving regression of pH or [H⁺] in relation to age. Diatom-inferred pH declined rapidly during the early Holocene period investigated (9,175-11,525 cal BP) with a statistically significant overall rate of 0.024 pH units per 100 yrs. This consisted of an older (ca. 11,525-10,255 cal BP) phase, where pH fell more rapidly at up to 0.095 pH units per 100 yrs; and a younger phase after ca. 10,500 cal BP where the pH fall was extremely slow (0.008 pH units per 100 yrs) and was not statistically significant.In the Allerød a combination of low catchment productivity together with disturbance, weathering, and minerogenic inwash ensured that the base-cation status remained relatively high. In the Holocene the catchment soils stabilised and base cations were sequestered by terrestrial vegetation and soil. This resulted in reduced base-cation leaching and this, together with the production of organic acids caused the lake to acidify, reaching an equilibrium by ca. 10,000 cal BP.  相似文献   

The Gove relict iron meteorite from Arnhem Land,Northern Territory,Australia     

Alex W. R. Bevan  Peter J. Downes  Dermot A. Henry  Michael Verrall  Peter W. Haines 《Meteoritics & planetary science》2019,54(8):1710-1719

On February 24, 1979, a deeply oxidized mass of iron meteorite was excavated from bauxite at an open cut mine on the Gove Peninsula, Northern Territory, Australia. The meteorite, measuring 0.75–1 m in diameter and of unknown total weight, was found at coordinates 12°15.8′S, 136°50.3′E. On removal from the ground, the meteorite is reported to have disintegrated rapidly. A preliminary analysis at the mine laboratory reportedly gave 8.5 wt% Ni. A modern analysis of oxidized material gave Ni = 32.9, Co = 3.67 (both mg g^?1), Cr = 168, Cu = 195, Ga = 22.5, Ge = <70, As = 4.16, W = 1.35, Ir = 10.5, Pt = 21.2, Au = 0.672 (all μg g^?1), Sb = <150, and Re = 844 (both ng g^?1). Competent fragments of oxidized material retain a fine to medium Widmanstätten pattern with an apparent average bandwidth of 0.5 mm (range 0.2–0.9 mm in plane section). Primary mineralogy includes rare γ–taenite and daubréelite, and secondary minerals produced by weathering include awaruite (with up to 78.5 wt% Ni) and an, as yet, unnamed Cu‐Cr‐bearing sulfide with the ideal formula CuCrS₂ that is hitherto unknown in nature. Deep weathering has masked many of the features of the meteorite; however, the analysis normalized to the analyses of fresh iron meteorites favors chemical group IIIAB. The terrestrial age of the meteorite is unknown, although it is likely to be in the Neogene (2.5–23 Ma), which is widely accepted as the major period of bauxite formation in the Northern Territory of Australia. Gove is the second authenticated relict meteorite found in Australia.  相似文献   

MicroRaman spectroscopy of diamond and graphite in Almahata Sitta and comparison with other ureilites     

Aidan J. ROSS  Andrew STEELE  Marc D. FRIES  Lukas KATER  Hilary DOWNES  Adrian P. JONES  Caroline L. SMITH  Peter M. JENNISKENS  Michael E. ZOLENSKY  Muawia H. SHADDAD 《Meteoritics & planetary science》2011,46(3):364-378

This work is the first detailed study of carbon phases in the ureilite Almahata Sitta (sample #7). We present microRaman data for diamond and graphite in Almahata Sitta, seven unbrecciated ureilites, and two brecciated ureilites. Diamond in Almahata Sitta was found to be distinct from that in unbrecciated and brecciated ureilites, although diamond in unbrecciated and brecciated ureilites is indistinguishable. Almahata Sitta diamond shows a peak center range of 1318.5–1330.2 cm^?1 and a full width at half maximum (FWHM) range of 6.6–17.4 cm^?1, representing a shock pressure of at least 60 kbar. The actual peak shock pressure may be higher than this due to postshock annealing, if shock synthesis is the source of ureilite diamonds. Diamond in unbrecciated and brecciated ureilites have peak center wave numbers closer to terrestrial kimberlite diamond, but show a wider range of FWHM than Almahata Sitta. The larger peak shift observed in Almahata Sitta may indicate the presence of lonsdaleite. Alternatively, the lower values in brecciated ureilites may be evidence of an annealing step either following the initial diamond‐generating shock or as a consequence of heating during reconsolidation of the breccia. Graphite in Almahata Sitta shows a G‐band peak center range of 1569.1–1577.1 cm^?1 and a G‐band FWHM range of 24.3–41.6 cm^?1 representing a formation temperature of 990 ± 120 °C. Amorphous carbon was also found. We examine the different theories for diamond formation in ureilites, such as chemical vapor deposition and shock origin from graphite, and explore explanations for the differences between Almahata Sitta and other ureilites.  相似文献   

Lead isotope systematics of ore systems of the Macquarie Arc — Implications for arc substrate     

David B. Forster  Graham R. Carr  Peter M. Downes 《Gondwana Research》2011,19(3):686-705

The Macquarie Arc of New South Wales hosts several major Au and Cu deposits. We present new Pb isotope results for Cadia, the Copper Hill, Little Copper Hill and Cowal deposits, along with data from the CSIRO database. The results generally plot close to established mantle growth curves and are similar to oceanic basalts. Data for individual deposits mostly have Pb model ages consistent with independent age constraints on mineralization. Intrusions associated with the Early Silurian mineralization at Cadia and Goonumbla have narrow and distinct Pb isotope signatures that we interpret to be the result of partial melting of already LILE-enriched mantle-like sources. The data suggest that deposits of the Macquarie Arc derived Pb from one or more long-lived mantle-like Pb isotope reservoirs without significant contributions of crustal Pb prior to the Benambran Orogeny.Data for the Copper Hill deposits includes unradiogenic, possibly old Pb and supports previous workers who suggested that old MORB-like basalts may occur at depth in the area. The Peak Hill deposit has the most unradiogenic signature and has the lowest ²⁰⁸Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb. These signatures closely match Cambrian MORB-like basalts in the Koonenberry Belt and are unlike Cambrian mafic rocks in Victoria. Similar rocks could form part of the substrate to other parts of the Macquarie Arc.  相似文献   

A search for X-ray variability in the open cluster NGC 2516     

Gavin Ramsay  Louise Harra  Hilary Kay 《Monthly notices of the Royal Astronomical Society》2003,341(4):1388-1392

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Searching for nonlocal lithologies in the Apollo 12 regolith: A geochemical and petrological study of basaltic coarse fines from the Apollo lunar soil sample 12023,155     

Louise Alexander  Joshua F. Snape  Ian A. Crawford  Katherine H. Joy  Hilary Downes 《Meteoritics & planetary science》2014,49(7):1288-1304

New data from a petrological and geochemical examination of 12 coarse basaltic fines from the Apollo 12 soil sample 12023,155 provide evidence of additional geochemical diversity at the landing site. In addition to the bulk chemical composition, major, minor, and trace element analyses of mineral phases are employed to ascertain how these samples relate to the Apollo 12 lithological basalt groups, thereby overcoming the problems of representativeness of small samples. All of the samples studied are low‐Ti basalts (0.9–5.7 wt% TiO₂), and many fall into the established olivine, pigeonite, and ilmenite classification of Apollo 12 basaltic suites. There are five exceptions: sample 12023,155_1A is mineralogically and compositionally distinct from other Apollo 12 basalt types, with low pigeonite REE concentrations and low Ni (41–55 ppm) and Mn (2400–2556 ppm) concentrations in olivine. Sample 12023,155_11A is also unique, with Fe‐rich mineral compositions and low bulk Mg# (=100 × atomic Mg/[Mg+Fe]) of 21.6. Sample 12023,155_7A has different plagioclase chemistry and crystallization trends as well as a wider range of olivine Mg# (34–55) compared with other Apollo 12 basalts, and shows greater similarities to Apollo 14 high‐Al basalts. Two other samples (12023,155_4A, and _5A) are similar to the Apollo 12 feldspathic basalt 12038, providing additional evidence that feldspathic basalts represent a lava flow proximal to the Apollo 12 site rather than material introduced by impacts. We suggest that at least one parent magma, and possibly as many as four separate parent magmas, are required in addition to the previously identified olivine, pigeonite, and ilmenite basaltic suites to account for the observed chemical diversity of basalts found in this study.  相似文献   

Announcements     

H. J. B. Birks  Hilary H. Birks 《Journal of Paleolimnology》1988,1(1):84-84

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