岩浆岩的熔点、粘度及其与化学成分的关系   总被引：4，自引：0，他引：4  

周殉若  吴国忠  朱广玲 《岩石学报》1987,3(1)

本文研究了我国中、新生代一些岩浆岩的化学成分、熔点、人工玻璃的折射率和比重以及它们在不同温度下的粘度。在常压下岩石酸度愈大,熔点愈高。熔点与岩石的Fe~(2+(+Fe~(3+)+Mn+Mg±Ca为反相关;与Si+Al+K+Na为正相关。计算粘度与温度的关系表明,酸度愈大,粘度愈大;碱度愈大,粘度愈小,温度愈高,粘度愈低;同一温差下,酸度愈大,粘度变化愈大。  相似文献   

Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals   总被引：9，自引：0，他引：9  

Lei Chou  Robert M. Garrels  Roland Wollast 《Chemical Geology》1989,78(3-4):269-282

The influence of pH on the rate of dissolution of various carbonates (calcite, aragonite, witherite, magnesite and dolomite) has been investigated at 25°C using a continuous fluidized bed reactor. The general rate dependence on pH observed for the simple carbonates is very similar and is in agreement with the results observed for calcite and aragonite by L.N. Plummer and coworkers. However, the rate of dissolution of magnesite is approximately four orders of magnitude lower than calcite.

For simple carbonates, the elementary steps involved in the dissolution reaction are:

where M represents the metal ion which can be Ca, Mg and Ba. According to the stoichiometry of the three reaction steps and the thermodynamic constraints, the total forward and backward rates can be expressed as:

The rate constants (k₁, k₂, k₃ and k₋₃) determined with our experimental results for calcite, aragonite and witherite show that the dissolution rates are similar for these three minerals and that the nature of the cations does not play a significant role. The good agreement between the K_sp calculated from the measured k₃/k₋₃ ratio and the theromodynamic value suggests that our dissolution mechanism is coherent.

The rate dependence on pH of the dissolution of dolomite obeys a fractional order at low pH's and confirms previously published observations therein. However, the two-step reaction mechanism proposed does not explain the fractional reaction order observed, which is likely due to a more complex surface reaction.  相似文献   

Organic geochemical characterization of the New Albany Shale group in the Illinois Basin     

Mei-In M. Chou  Donald R. Dickerson 《Organic Geochemistry》1985,8(6):413-420

Benzene extractable aliphatic hydrocarbons from the New Albany Shale in the Illinois Basin were characterized by gas chromatography and mass spectrometry, and the total organic matter of the shale was characterized by solid state carbon-13 cross polarization magic angle spinning nuclear magnetic resonance. Core samples from a northwest-trending cross-section of the Illinois Basin were studied. Gas chromatography (GC) and gas chromatography-mass spectrometric analysis (GC/MS) data indicate a regional variation of the aliphatic composition of the shale extracts. A positive, linear relationship between the two ratios, pristane/n-C₁₇ and phytane/n-C₁₈, is indicated. The NMR results indicated that organic matter deposited in northwestern Illinois shale is relatively high in aliphatic hydrocarbon content while, in contrast, organic matter found in southeastern Illinois shale is relatively low in aliphatic hydrocarbon content. Our findings suggest that the organic variation of the shale is mainly due to the differences in thermal maturity of the shale organic matter and the use of pristane/n-C₁₇ ratio as a thermal parameter in the study of oil may be extended to the study of the ancient sediments.  相似文献   

Propagation of spiral density waves in a magneto-active disk     

Chih-Kang Chou  Pei-Long Chen 《Astrophysics and Space Science》1994,211(1):13-29

The propagation of spiral density waves in a differentially rotating, self-gravitating, magnetoactive and highly flattened disk is investigated by using the asymptotic theory for tightly wound spirals developed by Lin and his collaborators. We adopt the continuum fluid model as the primary basis, and our treatment will be largely analytical. The disk plasma is studied in the frozen field approximation and inhomogenceous magnetic fields in the plane of the disk are considered in detail.In a differentially rotating disk with strong magnetic fields, the field lines will be considerably distorted and the mutual influence of magnetic fields and differential rotation is by no means obvious.In this paper we present a new asymptotic dispersion relation for tightly wound spiral density waves with magnetic fields along the spiral armsB (r). The effects of the magnetic fields lead to such terms likek ²(a ² +V _A ² ), wherek is the wave number,a represents the speed of sound,V _A = (B ²/4)^1/2 is the Alfvén speed,B denotes the field strength, and is the plasma density. These terms depict the well-known magnetoacoustic waves and could have been anticipated without a detailed computation. However the interaction of magnetic fields and differential rotation may give rise to other significant terms which are not so easy to foresee.We also present a more exact local dispersion relation by using the WKB approximation and study the effects of magnetic fields on the growth rate through the parametersQ andJ defined in the literature.Although the effects of the magnetic fields are rather insignificant for applications to Galactic dynamics, the effects of the magnetic fields are important for applications to star formation and problems related to the solar nebula.  相似文献   

Effects of Climate Change on Evapotranspiration from Paddy Fields in Southern Taiwan   总被引：1，自引：0，他引：1  

Pao-Shan Yu  Tao-Chang Yang  Chien-Chih Chou 《Climatic change》2002,54(1-2):165-179

The major objective of this study was to investigate the effects of climate change on evapotranspiration from paddy fields. A sensitivity analysis of meteorological variables at the Kao-Hsiung station, one of meteorological stations in southern Taiwan, was carried out using the modified Penman formula. Forty-eight-year records of temperature, relative humidity, sunshine duration, wind speed, and precipitation depth comprised the database. Trend and persistence analyses of the data were performed using the Mann–Kendall test, the Cumulative Deviation test, Linear Regression, andthe Autocorrelation Coefficient. The results indicated that only temperature and relative humidity have significant long-term trends and persistence. Two climatic scenarios, viz. (1) linear extrapolation of climatic trends and (2) the predictions of General Circulation Models (GCMs), were assumed to investigate the effects of climate change on evapotranspiration. The study revealed that evapotranspiration from paddy fields increased under both climatic scenarios studied.  相似文献   

基于PALSAR数据的青藏高原冻土形变检测方法研究   总被引：1，自引：0，他引：1  

谢酬  李震  李新武 《国土资源遥感》2008,19(3):15-19

季节性冻胀和融沉导致的地面形变是青藏高原冻土区建设施工与维护的主要问题。对冻融造成的形变进行有效监测是青藏铁 路建设与维护的前提。差分干涉测量技术是地表形变监测的重要手段之一,PALSAR（L波段的合成孔径雷达）数据在非城市区域具 有较高的相关性,适合青藏高原冻土区的地表形变监测。本文选用4景覆盖研究区域的PALSAR数据,研究利用该数据进行冻土形变 检测的方法,并对其检测结果进行了分析。结果表明,该方法与水准测量方法有较好的一致性。  相似文献   

Effects of freeze-thaw cycle and dry-wet alternation on slope stability     

YaLing Chou  LiYuan Sun  BaoAn Li  XiaoLi Wang 《寒旱区科学》2019,11(2)

The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the unsaturated loess was investigated by laboratory experimental methods. Moreover, the temperature field, seepage field, and stability of slopes with different gradients were simulated under the effect of the freeze-thaw cycle and dry-wet alternation by using the geotechnical analysis software Geo-Studio. The research results showed(1) when the freeze-thaw cycle was repeated on the slope, with the frozen depth increasing, the melted depth did the same; besides, the closed loop of isotherms formed on the slope;(2) under the action of dry-wet circulation, the negative pore-water pressure and volumetric water content showed an upward tendency. However, owing to the different slope gradients, rainfall infiltration was not the same. As time went by, the differences of the negative pore-water pressure and volumetric water content between the slopes of different gradients continued to increase;(3) with the freeze-thaw cycle and dry-wet alternation increasing, the slope-safety factor decreased. Especially in the early period, the slope-safety factor changed remarkably. For slopes undergoing freeze-thaw action, the slope-safety factor was negatively correlated with the gradient. However, with regard to slopes undergoing dry-wet alternation, the result became more complex because the slope-safety factor was related to both seepage strength and slope grade. Accordingly, further research is needed to study the effect of seepage strength and slope grade on the stability of loess slopes.  相似文献   

煤中硫的地质特征和洁净煤技术的发展(英文)   总被引：6，自引：0，他引：6  

Chou Chenglin 《地学前缘》1999,6(Z1):23-27

媒中硫的含量大都由煤层的沉积环境控制,并取决于成煤物质是否曾受过海水影响及其受海水影响的程度。煤中硫的含量对于煤的有效利用甚为重要。这主要是因为燃煤时有相当量的二氧化硫释放到大气中造成对环境有害的酸雨。因此,煤层中硫的分布和地质特征是评估煤的品质及解决有关环境问题的一个重要参数。洁净煤技术是为了有效解决能源需求并减少用煤对环境的影响而发展起来的。它包括煤燃烧前的洁净方法（物理、化学和微生物的煤洁净法）、烟气脱硫、吸附剂喷撒和各种媒燃烧技术（流化床、气化联合循环等）。  相似文献   

Seasonal and interannual variability of carbon cycle in South China Sea: A three-dimensional physical-biogeochemical modeling study   总被引：5，自引：1，他引：4  

Fei Chai  Guimei Liu  Huijie Xue  Lei Shi  Yi Chao  Chun-Mao Tseng  Wen-Chen Chou  Kon-Kee Liu 《Journal of Oceanography》2009,65(5):703-720

The South China Sea (SCS) exhibits strong variations on seasonal to interannual time scale, and the changing Southeast Asian Monsoon has direct impacts on the nutrients and phytoplankton dynamics, as well as the carbon cycle. A Pacific basin-wide physical-biogeochemical model has been developed and used to investigate the physical variations, ecosystem responses, and carbon cycle consequences. The Pacific basin-wide circulation model, based on the Regional Ocean Model Systems (ROMS) with a 50-km spatial resolution, is driven with daily air-sea fluxes derived from the National Centers for Environmental Prediction (NCEP) reanalysis between 1990 and 2004. The biogeochemical processes are simulated with the Carbon, Si(OH)₄, Nitrogen Ecosystem (CoSINE) model consisting of multiple nutrients and plankton functional groups and detailed carbon cycle dynamics. The ROMS-CoSINE model is capable of reproducing many observed features and their variability over the same period at the SouthEast Asian Time-series Study (SEATS) station in the SCS. The integrated air-sea CO₂ flux over the entire SCS reveals a strong seasonal cycle, serving as a source of CO₂ to the atmosphere in spring, summer and autumn, but acting as a sink of CO₂ for the atmosphere in winter. The annual mean sea-to-air CO₂ flux averaged over the entire SCS is +0.33 moles CO₂ m⁻²year⁻¹, which indicates that the SCS is a weak source of CO₂ to the atmosphere. Temperature has a stronger influence on the seasonal variation of pCO₂ than biological activity, and is thus the dominant factor controlling the oceanic pCO₂ in the SCS. The water temperature, seasonal upwelling and Kuroshio intrusion determine the pCO₂ differences at coast of Vietnam and the northwestern region of the Luzon Island. The inverse relationship between the interannual variability of Chl-a in summer near the coast of Vietnam and NINO₃ SST (Sea Surface Temperature) index in January implies that the carbon cycle and primary productivity in the SCS is teleconnected to the Pacific-East Asian large-scale climatic variability.  相似文献   

圆尾斗鱼的胚胎和仔鱼发育的研究   总被引：7，自引：0，他引：7  

周洁  周玉 《海洋湖沼通报》1995,(2):30-36

圆尾斗鱼的受精卵呈圆球形，光滑，略带淡黄色，浮性；卵膜吸水膨胀后的平均直径为１．１９ｍｍ，当水温２１－２３．５℃时，从受精卵到孵化出膜需４２．５小时；水温２２－２４．５℃时，刚出膜仔鱼到卵黄囊消失需４天，到油球消失约２５天。出膜３０天仔鱼的形态基本与成体相似。  相似文献