徐州土壤多环芳烃的环境地球化学迁移特征   总被引：1，自引：1，他引：0  

葛晓立  焦杏春  袁欣  李奇  罗松光  孙玮琳 《岩矿测试》2008,27(6):409-412

选择江苏徐州黄棕壤进行不同深度层位多环芳烃含量的定量分析,研究并探讨了多环芳烃在土壤深度剖面中的地球化学迁移特征。研究结果显示,多环芳烃在徐州土壤剖面中主要集中在地表0~20 cm内。其中低环多环芳烃化合物的迁移能力较强,4~6环等高环化合物相对较难迁移,主要残留于地表生态系统环境中。  相似文献   

Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge   总被引：10，自引：0，他引：10  

Qiang Wang  Derek A. Wyman  Jifeng Xu  Yusheng Wan  Chaofeng Li  Feng Zi  Ziqi Jiang  Huaning Qiu  Zhuyin Chu  Zhenhua Zhao  Yanhui Dong 《Contributions to Mineralogy and Petrology》2008,155(4):473-490

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.  相似文献   

An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting   总被引：1，自引：0，他引：1  

Mauro Lo Cascio  Yan Liang  Nobumichi Shimizu  Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Simple models for dynamic melting in an upwelling heterogeneous mantle column: Analytical solutions     

Yan Liang 《Geochimica et cosmochimica acta》2008,72(15):3804-3821

Several lines of evidence suggest that the melt generation and segregation regions of the mantle are heterogeneous, consisting of chemically and lithologically distinct domains of variable size and dimension. Partial melting of such heterogeneous mantle source regions gives rise to a diverse range of basaltic magmas. In order to better assess the role of source heterogeneity during mantle melting, we have undertaken a theoretical study of trace element distribution and fractionation during concurrent melting and melt migration in an upwelling, chemically heterogeneous, two-porosity double lithology melting column. Analytical solutions for the abundance of a trace element in the matrix and channel were obtained under the assumptions that the porosity, melt and solid velocities, and solid-melt partition coefficients are constant and uniform. For simplicity, we neglected diffusion and dispersion in the melt. Chemical source heterogeneities of arbitrary size and shape were integrated into the simple melting models by allowing trace element abundance in the source region to vary as a function of time and space. Concurrent melting and melt migration in an upwelling heterogeneous mantle may be approximated as a quasi-steady state problem in which time-dependent concentration patterns produced by melting of heterogeneous source regions are superimposed on a reference steady-state concentration distribution established by melting of the ambient or background mantle. Chromatographic fractionation is especially important for the matrix melt and solid when chemical heterogeneities are involved during melting and melt migration in the mantle, giving rise to significant phase-shift between two incompatible trace elements in the matrix melt and scattered correlations among incompatible trace elements in residual peridotites. Mixing is the chief mass transfer process in the dunite channel where the chromatographic effect is negligible for most of the incompatible trace elements. The lack of chromatographic fractionation among incompatible trace elements and isotopic ratios in MORB suggests either most MORB are channel melts or mixing in magma conduit and chamber is very efficient such that the phase-shift is averaged out during magma transport and storage processes. Advection brings melt produced by smaller-degree of melting in the deeper part of the melting column to the overlying melting region, increasing the incompatible trace element abundance in the matrix and the channel. This advection-induced self-enrichment is especially important when heterogeneous sources are involved and may account for some of the enriched incompatible trace element patterns observed in residual peridotite that were previously interpreted to be a result of mantle metasomatism. Systematic studies of high-resolution spatially correlated mantle samples may help to constrain the melting history and the size and nature of chemical heterogeneities in the mantle.  相似文献   

晚三叠世松潘甘孜和川西前陆盆地的物源对比：构造演化和古地理变迁的线索   总被引：3，自引：0，他引：3  

邓飞  贾东  罗良  李海滨  李一泉  武龙 《地质论评》2008,54(4):561-573

为了研究龙门山褶皱冲断带两侧的松潘甘孜和川西前陆盆地在大地构造和沉积学方面存在的联系,笔者等分别在松潘甘孜东缘马尔康—理县地区和川西前陆盆地都江堰地区进行了采样和碎屑锆石的LAICPMS UPb定年工作。269颗锆石的定年结果显示,中—晚三叠世拉丁期—诺利期松潘甘孜复理石盆地东缘沉积地层中的碎屑锆石年龄主要集中在250~280 Ma、1800~1900 Ma和2400~2500 Ma、200~245 Ma、400~450 Ma,对应的物源主要为东昆仑岛弧、华北陆块基底、义敦岛弧以及北秦岭。与之相比,川西前陆盆地诺利期—瑞替期的须家河组地层中的碎屑锆石年龄大致主要集中在1800~1900 Ma和2400~2500 Ma、720~850 Ma、950~1200 Ma、400~450 Ma。该统计结果总体上继承了松潘甘孜数据体的特征,揭示出须家河组物源来自西部——松潘甘孜褶皱带的再旋回沉积和龙门山前陆冲断带。  相似文献   

松辽盆地尚家—太平川地区石油地质条件及勘探方向分析   总被引：17，自引：9，他引：8       下载免费PDF全文

施立志  林铁锋  吴海波  王卓卓  祁越 《地质科学》2008,43(3):558-568

通过对尚家—太平川地区构造演化、烃源岩特征、沉积特征、储盖组合、油水关系及油藏类型和油气成藏特征的分析,研究了本区的石油地质条件,认为烃源岩具有较好的生、排烃能力,分流河道砂体为油气聚集提供较好的沉积环境,良好的储盖组合有利于油气的聚集与保存。研究区没有统一油水界面,尚家地区以岩性—构造油藏为主,太平川地区以构造—岩性油藏为主。区内扶余—杨大城子油层油气成藏受有效性圈闭、优势运移通道、过剩压力、储集条件和构造诱导作用控制。据上述认识确定了研究区下一步的勘探方向,并已在指导勘探实践中取得了较好的效果。  相似文献   

The age of the Nantuo Formation and Nantuo glaciation in South China   总被引：1，自引：0，他引：1  

Shihong Zhang  Ganqing Jiang  Yigui Han 《地学学报》2008,20(4):289-294

A U–Pb sensitive high‐resolution ion microprobe (SHRIMP) age of 654.5 ± 3.8 Ma from an ash bed immediately below the Nantuo Formation in South China provides the lowest age constraint for the Nantuo glaciation, which has been correlated with the global ‘Marinoan’ glaciation. A U–Pb SHRIMP age of 636.3 ± 4.9 Ma from a fallout tuff within the basal layer of the Nantuo Formation, along with the existing age of 635.2 ± 0.6 Ma from its overlying Doushantuo cap carbonate, suggests that the traditionally defined Nantuo Formation may have been deposited in a short time period at the end of the Nantuo glaciation. In combination with available ages globally, the data support a relatively short duration and rapid termination of ‘Marinoan’ glaciations.  相似文献   

祁连山不同植被类型对积雪消融的影响   总被引：7，自引：1，他引：6  

车宗玺  金铭  张学龙  张虎  牛云  董晓丽 《冰川冻土》2008,30(3):392-397

为研究祁连山植被对积雪消融的影响, 利用人工调查积雪深度逐日变化量和积雪盖度变化, 并结合空气雪面感热通量(SH)观测, 对祁连山水源林生态站排露沟流域海拔2 600～2 700 m青海云杉林、灌丛林、林缘、阳坡草地在2003-2007年的积雪消融进行了研究, 每年的观测从10月降雪开始到翌年5月积雪消融完结束, 共获取数据134 400个. 结果表明: 当SH<0时, 积雪消融停止;当SH>0时, 积雪消融开始;植被可以减缓积雪消融速率, 有植被的地方消融速率减慢, 反之则加快;不同植被消融速率大小顺序为草地>林缘>灌木林>乔木林;同一植被、不同坡向消融速率不同, 半阳坡云杉林＞半阴坡云杉林＞阴坡云杉林. 积雪含水率随气温升高而增大, 1月融化积雪占整个积雪的5%, 2月增大到28%, 大量积雪在3月消融, 占55%. 从坡位看, 下坡消融速率最大;在一个垂直带上, 低海拔消融速率大于高海拔. 温度是影响积雪消融的主要因子, 积雪消融速率随温度升高而增大, 反之则减小.  相似文献   

祁连山近期七一冰川融水径流特征分析   总被引：3，自引：1，他引：2  

宋高举  王宁练  陈亮  贺建桥  蒋熹  武小波 《冰川冻土》2008,30(2):321-328

利用2006年8月1日-9月30日的实测水文数据,对"七一"冰川融水径流产汇流特征进行了分析,并揭示出该冰川日消融特征.通过对冰川融水量的估算以及径流模数的计算,并与过去的观测结果进行对比,表明近些年来"七一"冰川消融强度和消融量都在增大,而且2006年消融量为近几年观测的最大值.虽然不同年份消融量不一样,但"七一"冰川总的趋势是一直处于萎缩状态,随着全球变暖,"七一"冰川的萎缩可能将继续下去.通过对设立在沿冰川下游方向两个不同的水文断面进行对比分析,结果表明"七一"冰川融水径流在向下游运动过程中有部分水入渗为河谷潜流,观测期内两个相距不到2 km的水文断面间渗漏损耗占近1/3左右.  相似文献   

河南省洛宁县寨凹钼矿床流体包裹体研究及矿床成因   总被引：10，自引：0，他引：10  

邓小华陈衍景  姚军明李文博李 诺王 运糜 梅张 颖 《中国地质》2008,35(6):1250-1266

寨凹钼矿床位于华北克拉通南缘的熊耳地体．矿床定位受马超营断裂带的次级断裂控制,矿体呈脉状贼存于太华超群石板沟组黑云角闪斜长片麻岩中。成矿过程包括3个阶段：石英-辉钼矿阶段（I）、石英-多金属硫化物阶段（Ⅱ）、石英-碳酸盐阶段（Ⅲ）,其中,I阶段为主成矿阶段。寨凹钼矿床可见2类流体包裹体,即水溶液型和含子晶包裹体;激光拉曼指示包裹体成分主要为H2O。从早到晚,流体包裹体均一温度从I阶段100～260℃,经Ⅱ阶段110～160℃．变化为Ⅲ阶段120—180℃．矿床总体属于低温热液矿床：流体包裹体盐度从I阶段的2～25wt％NaCl．eqv演化至Ⅱ阶段的6—30wt％NaCl．eqv．然后降为Ⅲ阶段的7～25wt％NaCl．eqv。I阶段均一温度范围宽广、流体包裹体盐度由双峰式演化为单峰式以及包裹体温度-盐度双变图的负相关性指示了流体混合是主要的成矿机制。寨凹钼矿流体包裹体以高密度、高盐度的低温低压流体为特征,是含CaCl,流体参与成矿的结果,热的岩浆流体与冷的含CaCl,的卤水的混合．导致了辉钼矿的沉淀。寨凹钼矿床地质和流体包裹体特征与侵入岩相关的成矿系统一致．指示其成因类型为与侵入岩有关的钼矿床．  相似文献