沸石基储能基元的研究     

杨玉山  董发勤  段涛 《矿物岩石》2008,28(1):13-16

以酸活化沸石为载体,十二醇为储能工质.制备沸石基储能基元,并采用X射线衍射、红外光谱和差示扫描量热等对沸石基储能基元进行表征.结果表明:储能基元在2θ=22.50时的衍射峰变强,相变储能材料十二醇和沸石栽体之间仅仅是简单的嵌合关系.储能基元的相变温度有一定的降低,并且熔融峰变宽.  相似文献   

长江流域河水和悬浮物的锂同位素地球化学研究   总被引：9，自引：1，他引：8  

汪齐连  刘丛强  赵志琦  丁虎 《地球科学进展》2008,23(9):952-958

深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成（δ⁷Li）分别为150~4 570 nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成（δ⁷Li）变化比较稳定,分别为41~92 μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合：其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。  相似文献   

GVG采样线代表性检验     

吴胜军  李涛  吴炳方  宋月君  冯奇 《遥感学报》2008,12(2):263-269

通过在实验区内设置不同类型的采样线,对GVG采样线的代表性进行检验.结果表明,高速公路和乡村道路类型的采样线对区域代表性的精度在95%以上;国道为86.726%;省道为65.447%.对于不同的缓冲区,高速公路、省道和乡村道路类型采样线,以200m缓冲区的代表性最好.而国道则以800m缓冲区的代表性最好.对于不同的作物而言,无论何种类型的采样线或者缓冲区,种植面积最大的棉花的精度是最好的.最低的是省道采样线1000m缓冲区,精度是78.146%,最好的是国道采样线800m缓冲区,精度是99.974%.除省道外,其他精度都在94.8%以上.这说明GVG采样线所获得的成数对于区域主要作物的代表性是很好的.  相似文献   

山东三山岛金矿床流体包裹体特征及其地质意义   总被引：5，自引：0，他引：5  

周国发  吕古贤  邓军  申玉科  郭涛 《现代地质》2008,22(1):24-33

三山岛金矿床位于莱州市三山岛—仓上断裂带内,矿石主要为蚀变岩和含金石英脉2种类型。随着胶东金矿床研究的深入和三山岛金矿资源的不断减少,对三山岛金矿床的成矿作用及深部开发前景问题研究具有更重要的意义。针对上述问题,对三山岛金矿床2种类型矿石的成矿流体特征进行对比研究,认为代表成矿早—中期的蚀变岩型矿石形成于中温(均一温度为325～240℃)、低盐度(2.07%～6.88%)、低密度(0.720～0.868g/cm3)、酸碱性不均匀(pH=3.27～10.43)、以氟化物和氯化物为成矿物质载体的还原性流体;代表成矿中—晚期的含金石英脉型矿石形成于中—低温(均一温度为306～160℃)、低盐度(1.05%～9.73%)、低密度(0.739～0.962g/cm3)、碱性(pH=9.25～9.85)、以氯化物和硫化物为成矿物质载体的还原性流体。成矿流体性质的转变反映了成矿流体处于由比较封闭到比较开放的构造环境的转变期,且成矿流体早期以原生岩浆水为主,后期有变质水、大气降水以及海水的参与作用。三山岛金矿成矿深度为2.5～5km,根据目前的开采深度推算其深部还有一定的资源量可供开发。  相似文献   

Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance     

Qingtao Zeng  Jianren Mao  Qing Hu  Xilin Zhao  Haimin Ye 《中国地球化学学报》2008,27(3):276-284

Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.  相似文献   

Helium-argon isotopic tracing for the Pb-Zn-Ag polymetallic ore deposits in the central-south segment of the Da Hinggan Ling Range     

Baode Wang  Shuyin Niu  Aiqun Sun  Huabin Hu  Yaming Liu  Lijun Guo  Shuo Wang 《中国地球化学学报》2008,27(3):235-241

In recent years big strides have been made in the exploration of ores in the central-south segment of the Da Hinggan Ling Range, though some debates still exist on the metallogenesis and sources of ore-forming materials. Pyrite and other sulfides in direct relation to the Pb-Zn-Ag ore deposits were chosen for the He and Ar isotopic analysis of ore-forming fluids, and the first He and Ar isotope data have been obtained from the study region. ^3He/^4He ratios in 14 samples collected from 7 mining districts are 2.17×10^-6-12.52×10^-6, averaging 6.86×10^-6 and their R/Ra ratios are 1.56-9.01 Ra, averaging 4.37 Ra. By projecting the data points onto the ^3He-^4He concentrations diagram, all the points fall near the mantle helium area. The calculated mantle-source helium ratios are within the range of 19.58%-76.96%, with an average of 49.52%. Argon isotopic characteristics are close to those of mantle source, indicating that the ore-forming material was transport upwards via the multi-stage evolution of mantle plume and concentrated as ores in the favorable loci of mantle branch structures.  相似文献   

The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin   总被引：2，自引：2，他引：0  

Xianqing Li  Guoyi Hu  Jian Li  Dujie Hou  Peng Dong  Zhihong Song  Yunfeng Yang 《中国地球化学学报》2008,27(2):109-120

The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.  相似文献   

Benthic nutrient fluxes in the intertidal flat within the Changjiang （Yangtze River） Estuary   总被引：1，自引：0，他引：1  

GAO Lei    LI Daoji  WANG Yanming  YU Lihua  KONG Dingjiang  LI Mei  LI Yun  and FANG Tao State Key Laboratory of Marine Geology  Tongji University  Shanghai  China State Key Laboratory of Estuarine  Coastal Research  East China Normal University  Shanghai  China 《中国地球化学学报》2008,27(1):58-71

In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang （Yangtze River） Estuary. Except for NH4^＋, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water （Dw） in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 （n=18）. These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification.  相似文献   

Changes in nutrient uptake of phytoplankton under the interaction between sunlight and phosphate in the Changjiang （Yangtze） River Estuary     

FANG Tao LI Daoji YU Lihua LI Yun 《中国地球化学学报》2008,27(2):161-170

We conducted ship-board incubation experiments to investigate changes in nutrient uptake of phytoplankton under different phosphate concentrations and irradiances in the Changjiang River Estuary and its adjacent waters in China. Under 100% natural irradiance the uptake rates of phosphate, silicate, and nitrate were accelerated at high phosphate levels （1.84 μM）, while under low irradiance （about 50% natural irradiance） their uptake rates were restrained at the high but stimulated greatly at the intermediate phosphate concentrations （1.26 μM）, as the growth of phytoplankton, changes in nitrite and ammonium uptake didn＇t follow an obvious pattern. Our results also showed that there were linear relationships between nitrate, silicate and phosphate uptake at different phosphate concentrations under low and high irradiances, and the growth period of phytoplankton was prolonged both at the high phosphate concentrations under high irradiance and at the intermediate concentrations under low irradiance, suggesting that the limitation of phytoplankton growth mainly reflected changes in its growth period, and because no such environment （low irradiance and low phosphate concentrations） actually existed in a high turbidity zone, phytoplankton blooms hardly occurred there. In the absence of irradiance, denitrification occurred readily and phytoplankton was kept decreasing, which resulted in phosphate regeneration.  相似文献   

<Superscript>40</Superscript>Ar-<Superscript>39</Superscript>Ar dating of lamprophyre dykes in the Baimazhai nickel deposit,Yunnan Province,China, and its geological significance     

Bo Li  Zhilong Huang  Tao Guan  Wei Ding 《中国地球化学学报》2008,27(4):351-355

The Baimazhai nickel deposit, Yunnan Province, China, is located in the southern part of the Sanjiang （Tri-river） alkali-rich intrusive rock belt （Sanjiang ARIR）. In this paper was conducted ^40Ar-^39Ar dating of two phlogopites in lamprophyres which are, as dikes, widely distributed in the orefield, and two plateau ages were acquired, i.e., 32.46±0.62 Ma and 32.01±0.60 Ma, respectively （averaging 32.23±0.60 Ma）. The ages are obviously younger than those of the ore-hosted complex and mineralization of the Baimazhai nickel deposit. In combination with the characteristics, it is indicated that lamprophyres in the orefield and those in the Sanjiang ARIR are similar in tectonic setting, mineral assemblage and geochemistry. It is considered that lamprophyres in the orefield are the important component of the Sanjiang ARIR, and the lamprophyres and ore-hosted complex in the orefield represent the products of two times of different magmatic activity from different mantle sources. On the other hand, the age of lamprophyres in the orefield is older than that of the strike-slip shearing of the Ailaoshan-Honghe fault belt, suggesting that the strike-slip shearing of the Ailaoshan-Honghe fault belt is not the factor leading to magmatic activity of lamprophyres in the orefield, while it is more possible that magmatic activity of the Sanjiang ARIR promoted strike-slip shearing of the fault belt.  相似文献