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Stable carbon, oxygen, and strontium isotope records were obtained from uppermost Hauterivian to lowermost Aptian belemnite rostra, which were collected in well-dated sections from the Vocontian Trough (southeastern France). This data set complements previously published belemnite-isotope records from the uppermost Berriasian-Hauterivian interval from the same basin. The belemnite carbon and oxygen isotope record is compared to the carbonate bulk-rock isotope record from the same sections, and from additional Italian sections. With regards to their long-term trends, both belemnite and whole-rock δ18O records are well correlated, except for the uppermost Hauterivian-lower Barremian interval, within which they deviate. This discrepancy is interpreted to be linked to the latest Hauterivian Faraoni oceanic anoxic event and its early Barremian aftermath. The Faraoni level is characterized by enhanced sea-water stratification, probably induced by the onset of a warmer and more humid climate along the northern Tethyan margin. The early Barremian was characterized by stronger vertical sea-water mixing reflected by a decrease in density contrast between sea-surface and deeper waters. The belemnite oxygen isotope record shows a more stable evolution with smaller fluctuations than its bulk-rock counterpart, which indicates that deeper water masses were not as much subjected to density fluctuations as sea-surface water. The comparison of belemnite and bulk-rock carbon isotope records allows observing the impact of regional influence exerted by platform carbonate ooze shedding on the carbon cycle. Discrepancies in the two records are observed during time of photozoan carbonate platform growth. The strontium isotopic record shows a gradual increase from the uppermost Berriasian to the uppermost lower Barremian followed by a rapid decrease until the uppermost Barremian and a renewed small increase within the lowermost Aptian. The major inflection point in the uppermost lower Barremian appears to predate the onset in the formation of the Ontong-Java volcanic plateau.  相似文献   
364.
Early Triassic paleobiogeography is characterised by the stable supercontinental assembly of Pangea. However, at that time, several terranes such as the South Kitakami Massif (SK), South Primorye (SP) and Chulitna (respectively, and presently located in Japan, eastern Russia and Alaska) straddled the vast oceans surrounding Pangea. By means of quantitative biogeographical methods including Cluster Analysis, Non-metric Multidimensional Scaling and Bootstrapped Spanning Network applied to Smithian and Spathian (Early Triassic) ammonoid assemblages; we analyze similarity relationships between faunas and suggest paleopositions for the above-cited terranes.Taxonomic similarities between faunas indicate that primary drivers of the ammonoid distribution were Sea Surface Temperature and currents. Possible connections due to current-controlled faunal exchanges between both sides of the Panthalassa are shown and terranes such as SK, SP and Chulitna played an important role as stepping stones in the dispersal of ammonoids. SK and SP terranes show strong sub-equatorial affinities during the Smithian, thus suggesting a location close to South China. At the same time, the Chulitna terrane shows strong affinities with equatorial faunas of the eastern Panthalassa. This paleoceanographic pattern was markedly altered during the Spathian, possibly indicating significant modifications of oceanic circulation at that time, as illustrated by the development of a marked intertropical faunal belt across Tethys and Panthalassa.  相似文献   
365.
New experimental data on the effect of anorthite (An) on liquidus phase equilibria in the system Qz–Ab–Or are presented. The data were obtained for 5 wt% An added to variable Qz/Ab/Or compositions at 300 MPa and under H2O-saturated conditions. Crystal–liquid equilibria were determined for 13 synthetic glass compositions made from gels in experiments performed between 660 and 750 °C in cold-seal pressure vessels. Forward and reversal experiments were systematically conducted on each composition to demonstrate equilibrium. A total of 51 charges was examined. Three crystalline phases, quartz, alkali feldspar and plagioclase appear on the H2O-saturated liquidus surface. The determined minimum liquidus 5 wt% An “piercing” point (39% Qz, 33% Ab, 28% Or) is shifted away from the Ab apex toward the Qz–Or sideline when compared with the An-free 300 MPa H2O-saturated minimum. This shift is of the same type as that observed at 100 MPa in the same system and at 200 MPa in a rhyolitic system. The new experimental results are used to test both empirical and thermodynamic models for silicic magmas. Empirical models reproduce reasonably well the new experimental data, although more sophisticated calculations schemes appear to be required to improve their accuracy. The new experimental results in the haplogranodiorite system are not well reproduced with the model of Holland and Powell (2001), mainly because plagioclase stability appears greatly enhanced in the model. Rhyolite-MELTS satisfactorily reproduces the Qz-, Pl- and Af-liquid phase equilibria, but model H2O solubilities are significantly lower and crystallization temperatures higher than in experiments.  相似文献   
366.
Chemical mass balance of calcrete genesis on the Toledo granite (Spain)   总被引:2,自引:0,他引:2  
The chemical mass balance of calcrete genesis is studied on a typical sequence developed in granite, in the Toledo mountains, Central Spain.

Field evidence and petrographic observations indicate that the texture and the bulk volume of the parent rock are strictly preserved all along the studied calcrete profile.

Microscopic observations indicate that the calcitization process starts within the saprolite, superimposed on the usual mechanisms of granite weathering: the fresh rock is first weathered to secondary clays, mainly smectites, which are then pseudomorphically replaced by calcite. Based on this evidence, chemical mass transfers are calculated, assuming iso-volume transformation from the parent rock to the calcrete.

The mass balance results show the increasing loss of matter due to weathering of the primary phases, from the saprolite towards the calcrete layers higher in the sequence. Zr, Ti or Th, which are classically considered as immobile during weathering, are also depleted along the profile, especially in the calcrete layer. This results from the prevailing highly alkaline conditions, which could account for the simultaneous precipitation of CaCO3 and silicate dissolution.

The calculated budget suggests that the elements exported from the weathering profile are provided dominantly by the weathering of plagioclase and biotite. We calculate that 8–42% of the original Ca remains in granitic relics, while only 15% of the authigenic Ca released by weathering is reincorporated in the calcite. This suggests that 373 kg/m2 of calcium (i.e., three times the original amount) is imported into the calcrete from allochtonous sources, probably due to aeolian transport from distant limestone formations.  相似文献   

367.
Highly-collimated outflows are believed to be the earliest stage in outflow evolution, so their study is essential for understanding the processes driving outflows. The BHR71 Bok globule is known to harbour such a highly-collimated outflow, which is powered by a protostar belonging to a protobinary system. Using the APEX telescope on Chajnantor, we mapped the BHR71 highly-collimated outflow in CO(3-2), and observed several bright points of the outflow in the molecular transitions CO(4-3), CO(7-6), 13CO(3-2), C18O(3-2), CH3OH(7-6) and H2CO(4-3). We use an LVG code to characterise the temperature enhancements in these regions. These observations are particularly interesting for investigating the interaction of collimated outflows with the ambient molecular cloud. In our CO(3-2) map, the second outflow driven by IRS2, which is the second source of the binary system, is completely revealed and shown to be bipolar. We also measure temperature enhancements in the lobes. The CO and methanol LVG modelling points to temperatures between 30 and 50 K in the two lobes. The methanol emission in the southern lobe bright knot is barely resolved with the APEX single-dish. ALMA will thus be a central tool to study the shock chemistry in these regions.  相似文献   
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369.
Soils in pro‐glacial areas are often approached from a chronosequence viewpoint. In the chronosequence approach, the objective is to derive rates of soil formation from differences in properties between soils of different age. For this reason, in chronosequence studies, soils are sampled in locations that are assumed geomorphically stable and that have different age. As a result, these studies do not necessarily yield a complete view of soil variability in pro‐glacial areas, and may miss important relations between geomorphology and soil development. In this contribution, we present new soil observations from three closely related pro‐glacial areas in Switzerland. These observations were intended to get closer to a complete view of soil variability, and to assess impacts from factors other than time on soil development. About 40 soils were visited in each pro‐glacial valley in a combined design‐convenience sampling scheme and described in the field. Linear modelling was used to assess effects of time and topographic factors on soil properties. The time since glacial retreat turned out to rarely explain more than half of the variation in soil properties, and a linear model combining effects of time and topographic variables explained typically about half of the variation in each pro‐glacial valley. Models differed and were not transferable between valleys. Apparently, time and the present‐day shape of the landscape combined are insufficient information to accurately predict soil properties. Field evidence points to the importance of the geomorphic history and regime of the valleys as a reason for this. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
370.
Sediment flux dynamics in fluvial systems have often been related to changes in external drivers of topography, climate or land cover. It is well known that these dynamics are non‐linear. Recently, model simulations of fluvial activity and landscape evolution have suggested that self‐organization in landscapes can also cause internal complexity in the sedimentary record. In this contribution one particular case of self‐organization is explored in the Sabinal field study area, Spain, where several dynamic zones of sedimentation and incision are observed along the current river bed. Whether these zones can be caused by internal complexity was tested with landscape evolution model (LEM) LAPSUS (Landscape Process Modelling at Multi‐dimensions and Scales). During various 500 year simulations, zones of sedimentation appear to move upstream and downstream in eroding river channels (‘waves’). These waves are visualized and characterized for a range of model settings under constant external forcing, and the self‐organizing process behind their occurrence is analysed. Results indicate that this process is not necessarily related to simplifications in the model and is more generic than the process of bed‐armouring that has recently been recognized as a cause for complexity in LEM simulations. We conclude that autogenic sediment waves are the result of the spatial propagation in time of feedbacks in local transport limited (deposition) and detachment limited (erosion) conditions. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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