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141.
The presence of polycyclic aromatic hydrocarbons (PAHs) may change the mechanisms of metal uptake, thus influencing kinetics and extent of metal phytoextraction. Studies on the subject are scarce, particularly for salt marsh plants. The aim of this work was to investigate the effect of PAHs on the uptake of Cu by Halimione portulacoides, a plant commonly found in salt marshes. Experiments were carried out in the laboratory, either in hydroponics (sediment elutriate) or in sediment soaked in elutriate, which were prepared with sediment and water from a salt marsh of the Cavado river estuary (NW Portugal). Groups of H. portulacoides (grown in a greenhouse) were exposed to those media during six days. Cu(2+) (as Cu(NO(3))(2)), 10(2) and 10(4)mugl(-1), was added to the media as well as 1.6mugl(-1) of the sixteen EPA priority PAHs (0.1mugl(-1) of each PAHs). Cu was assayed in solutions, sediments and different plant tissues before and after experiments. After exposure, photosynthetic efficiency and levels of chlorophylls were also measured, indicating that plant stress indicators were identical in all plants independently of the media to which the plants were exposed. PAHs influenced both the soluble Cu fraction and Cu uptake by plants. The amounts of metal accumulated in both roots and stems were significantly higher when the 10(4)mugl(-1) of Cu enriched elutriate was amended with PAHs. Thus, results suggest that PAHs may modify Cu solubility, the Cu sorption by plants and/or the passive penetration of Cu into the root cells. Therefore, the combined effects of different types of pollutants should be taken in consideration when studying the remediation potential of plants, namely in terms of phytoextraction.  相似文献   
142.
Traditional approaches to develop 3D geological models employ a mix of quantitative and qualitative scientific techniques,which do not fully provide quantification of uncertainty in the constructed models and fail to optimally weight geological field observations against constraints from geophysical data.Here,using the Bayesian Obsidian software package,we develop a methodology to fuse lithostratigraphic field observations with aeromagnetic and gravity data to build a 3D model in a small(13.5 km×13.5 km)region of the Gascoyne Province,Western Australia.Our approach is validated by comparing 3D model results to independently-constrained geological maps and cross-sections produced by the Geological Survey of Western Australia.By fusing geological field data with aeromagnetic and gravity surveys,we show that 89%of the modelled region has>95%certainty for a particular geological unit for the given model and data.The boundaries between geological units are characterized by narrow regions with<95%certainty,which are typically 400-1000 m wide at the Earth's surface and 500-2000 m wide at depth.Beyond~4 km depth,the model requires geophysical survey data with longer wavelengths(e.g.,active seismic)to constrain the deeper subsurface.Although Obsidian was originally built for sedimentary basin problems,there is reasonable applicability to deformed terranes such as the Gascoyne Province.Ultimately,modification of the Bayesian engine to incorporate structural data will aid in developing more robust 3D models.Nevertheless,our results show that surface geological observations fused with geophysical survey data can yield reasonable 3D geological models with narrow uncertainty regions at the surface and shallow subsurface,which will be especially valuable for mineral exploration and the development of 3D geological models under cover.  相似文献   
143.
We perform a detailed measurement of the electron density along two slit position angles in the bright, low metallicity extragalactic HII region NGC 2363. A comparison of the density structures obtained with the two independent diagnostics given by [AIV]4711/4740 and [SII]6716/6731, show that they present both different absolute values and different radial dependencies, with the [AIV] densities reaching up to 1000 cm-3. We explore the implications for the computation of the He abundance.  相似文献   
144.
An earth dam was to be constructed on a site which posed non-uniform foundation conditions. The most prominent feature was a vertical contact between unweathered quartzite and decomposed diabase running parallel to the valley. The paper describes a two-dimensional finite element analysis on the foundation and embankment to determine relative settlements and the possibility of hydraulic fracturing of the clay core. The analysis was extended to evaluate the effectiveness of site improvement measures such as excavation and recompaction of the decomposed diabase and elimination of the contact problem by blasting into the unweathered quartzite. Comparing results from the various analyses, it was concluded that the latter was the only viable solution to the problem.  相似文献   
145.
Inverse and direct methods have been used to analyze a large number of borehole temperature logs in order to infer past climatic changes. Results indicate a warming of 1–2°C in eastern and central Canada during the past 150 years. A period of cooling between 500 and 200 years before present, corresponding to the time of the “Little Ice Age”, has also been identified in the same areas. A regional ground temperature history is estimated for eastern and central Canada from the simultaneous inversion of several temperature logs. The inferred temperature changes appear correlated with the concentration of atmospheric carbon dioxide as reported from a Greenland ice core, and agree with existing meteorological and dendrochronological records for the area.  相似文献   
146.
Solar global radiation was measured in several places in Costa Rica during the total solar eclipse that occurred on July 11, 1991. In two of these places, Puntarenas and Santa Cruz, measurements in the ultraviolet range (295–385 nm) were also taken. In Santa Cruz, a normal incidence pyrheliometer with Schott filters OG530 and RG630 was used to measure direct solar radiation in its whole range, and in the 530–2800 nm and 630–2800 wavebands respectively. Global radiation, and consequently direct, diffuse and irradiance in any of the wavebands considered, decreased gradually as the sun was being eclipsed and reached zero during the totality, then increased to their normal values. Data registered in Santa Cruz were used to determine Ångstrom's atmospheric turbidity parameters and. Computations show that between 13:00 and 14:30 LT (local time), decreased and increased significantly. This indicates that atmospheric turbidity was high and large particles were more abundant than small ones. The size of hygroscopic particles increased during the eclipse when temperature decreased and relative humidity increased in a comparatively short time.  相似文献   
147.
Starting with a stochastic differential equation with random coefficients describing steady-state flow, the effective hydraulic conductivity of 1-, 2-, and 3-dimensional aquifers is derived. The natural logarithm of hydraulic conductivity (lnK) is assumed to be heterogeneous, with a spatial trend, and isotropic. The effective conductivity relates the mean specific discharge in an aquifer to the mean hydraulic gradient, thus its importance in predicting Darcian discharge when field data represent mean or average values of conductivity or hydraulic head. Effective conductivity results are presented in exact form in terms of elementary functions after the introduction of special sets of coordinate transformations in two and three dimensions. It was determined that in one, two, and three dimensions, for the type of aquifer heterogeneity considered, the effective hydraulic conductivity depends on: (i) the angle between the gradient of the trend of lnK and the mean hydraulic gradient (which is zero in the one-dimensional situation); (2) (inversely) on the product of the magnitude of the trend gradient of lnK, b, and the correlation scale of lnK, and (3) (proportionally) on the variance of lnK, f 2 . The productb plays a central role in the stability of the results for effective hydraulic conductivity.  相似文献   
148.
149.
This study presents an analysis of up to 30 years of hydrological variables and selected water quality parameters (pH, SO4, Fe, Cu, and As) in the upper area of the Elqui River basin in North‐Central Chile. A correlation analysis determined statistically significant positive relationship for SO4‐Cu, Fe‐As, and Fe‐Cu. In terms of historical behaviour, no statistically significant trends were detected for precipitation or temperature. In contrast, for flow, there is an overall decreasing pattern for the entire area of study, although only in one case this trend was statistically significant. Along with the aforementioned analysis, a characterization of the flow‐water quality relationships is considered for the time period analyzed. Although erratic behaviours were confirmed, a negative (i.e., inverse) flow‐concentration relationship was identified for SO4, a positive (i.e., direct) relationship for Fe, and undefined relationships for As and Cu were obtained. From these analyses and based on previous studies on projections regarding climate change for the Andean region, and in particular for the upper Elqui zone, an estimation of the possible effects of the change in water regimes on water quality in the area of study is developed. It is likely that a decrease in surface flow, as a consequence of climate change could translate into improvements in water quality in terms of Fe and eventually As and Cu, but into an impairment in the case of SO4. In any case, this is a complex situation that demands special attention in the face of industrial activities that could be developed in tributaries like the Claro River, which currently play an important role in depurating or diluting contaminants in the waters of the Elqui River. Finally, it should be noted that this study addresses an issue that goes beyond the local interest and could be used as a reference to compare other transitional environments containing sulphide ores or areas of hydrothermal alterations, which are considered to be highly vulnerable to climate change and variability.  相似文献   
150.
In boreal forest ecosystems, wildfire severity (i.e. the extent of fire‐related tree mortality) is affected by environmental conditions and fire intensity. A burned area usually includes tree patches that partially or entirely escaped fire, called ‘residual patches’. Although the occurrence of residual patches has been extensively documented, their persistence through time, and thus their capacity to escape several consecutive fires, has not yet been investigated. Macroscopic charcoal particles embedded in organic soils were used to reconstruct the fire history of 13 residual patches of the eastern Canadian boreal mixedwood forest. Our results display the existence of two types of residual patches: (i) patches that only escaped fire by chance, maybe because of local site or meteorological conditions unsuitable for fire spread (random patches), and (ii) patches with lower fire susceptibility, also called ‘fire refuges’ that escaped at least two consecutive fires, probably because of particular site characteristics. Fire refuges can escape fire for more than 500 years, up to several thousand years, and probably burn only during exceptionally severe fire events. Special conservation efforts could target fire refuges owing to their old age, long ecological continuity and potential specific biological diversity associated to different microhabitats.  相似文献   
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