Experimental insights into Stannern-trend eucrite petrogenesis     

S. D. Crossley  N. G. Lunning  R. G. Mayne  T. J. McCoy  S. Yang  M. Humayun  R. D. Ash  J. M. Sunshine  R. C. Greenwood  I. A. Franchi 《Meteoritics & planetary science》2018,53(10):2122-2137

The incompatible trace element-enriched Stannern-trend eucrites have long been recognized as requiring a distinct petrogenesis from the Main Group-Nuevo Laredo (MGNL) eucrites. Barrat et al. ( 2007 ) proposed that Stannern-trend eucrites formed via assimilation of crustal partial melts by a MGNL-trend magma. Previous experimental studies of low-degree partial melting of eucrites did not produce sufficiently large melt pools for both major and trace element analyses. Low-degree partial melts produced near the solidus are potentially the best analog to the assimilated crustal melts. We partially melted the unbrecciated, unequilibrated MGNL-trend eucrite NWA 8562 in a 1 atm gas-mixing furnace, at IW-0.5, and at temperatures between 1050 and 1200 °C. We found that low-degree partial melts formed at 1050 °C are incompatible trace element enriched, although the experimental melts did not reach equilibrium at all temperatures. Using our experimental melt compositions and binary mixing modeling, the FeO/MgO trend of the resultant magmas coincides with the range of known Stannern-trend eucrites when a primary magma is contaminated by crustal partial melts. When experimental major element compositions for eucritic crustal partial melts are combined with trace element concentrations determined by previous modeling (Barrat et al. 2007 ), the Stannern-trend can be replicated with respect to both major, minor, and trace element concentrations.  相似文献   

Cooling rates of type I chondrules from Renazzo: Implications for chondrule formation     

Noël Chaumard  Munir Humayun  Brigitte Zanda  Roger H. Hewins 《Meteoritics & planetary science》2018,53(5):984-1005

Cooling rates are one of the few fundamental constraints on models of chondrule formation. In this study, we used Cu and Ga diffusion profiles in metal grains to determine the cooling rates of type I chondrules in the Renazzo CR2 chondrite. To improve previous estimations of cooling rates obtained using this method, we used CT scanning and serial polishing of our sections to analyze equatorial sections of large metal grains. Through the cores of these metal grains situated at the surface of chondrules, the cooling rates calculated range from 21 to 86 K h⁻¹ for a peak temperature T_p ~ 1623–1673 K. A metal grain embedded in the core of a chondrule exhibits a cooling rate of 1.2 K h⁻¹ at a T_p ~ 1573 K. We also measured Cu-Ga diffusion profiles from nonequatorial sections of metal grains and calculated a lower range of cooling rates of 15–69 K h⁻¹ for T_p ~ 1473–1603 K compared to our results from equatorial sections. The high cooling rates inferred from the lightning model (several thousand K h⁻¹) are clearly at odds with the values obtained in this work. The X-wind model predicts cooling rates (~6–10 K h⁻¹) lower than most of our results. The cooling rates calculated here are in close agreement with those inferred from shock wave models, in particular for temperatures at which olivine crystallizes (from ~10 to several hundreds K h⁻¹ between 1900 and 1500 K). However, the chemical compositions of metal grains in Renazzo are consistent with the splashing model, in which a spray of metal droplets originated from a partially molten planetesimal. Volatile siderophile element depletion is explained by evaporation before metal was engulfed within silicate droplets. Liquid metal isolated from the liquid silicate crystallized during cooling, reacted with the ambient gas, and then re-accreted within partially molten chondrules.  相似文献   

Geochemistry of sulphate-bearing water of Akra Kaur Dam,Gwadar, Balochistan,Pakistan and its assessment for drinking and irrigation purposes     

Shahid Naseem  Pazeer Ahmed  Syeda Sadia Shamim  Erum Bashir 《Environmental Earth Sciences》2012,66(7):1831-1838

This paper is an attempt to study the geochemistry of Akra Kaur Dam (AKD) water, north of Gwadar city, southern Balochistan. Representative water samples were collected from AKD reservoir to assess the suitability of water for drinking and agriculture purposes. The major ionic composition is suggestive for freshwater. The average ionic composition demonstrate SO₄ > Ca > Na > Cl > HCO₃ > Mg > K. The plots on Piper diagram reflected Ca–Mg–SO₄ type of water facies. High Ca/SO₄ and Ca/Mg ratios revealed that the water has influence of gypsum dissolution. The negative ratio of chloro-alkaline indices indicated reverse exchange between Ca and Mg in water occurred with Na and K in rocks. The pH, electrical conductivity, total dissolved salts, Ca, Mg, Na, K, HCO₃, Cl and SO₄ concentrations in the dam water were below the permissible limit, however, Na and SO₄ were above the desirable limit, set by the World Health Organization. Important parameters such as residue sodium carbonate, sodium percent, sodium adsorption ratio, permeability index, magnesium content and Kelley’s ratio were calculated to evaluate the suitability of water for irrigation purpose. The result were compared with standard permissible limits and found satisfactory. The health and agriculture hazards of sulphate-bearing water were also discussed.  相似文献   

Elemental characterization of black shales of Khyber Pakthunkhawa (KPK) region of Pakistan using AAS   总被引：1，自引：0，他引：1  

Abdul Aziz  Muhammad Sajjad  Bashir Mohammad 《中国地球化学学报》2013,32(3):248-251

Black shale samples were collected from Chimiari Khyber Pakthunkhawa region of Pakistan and were analyzed for elemental compositions. Atomic Absorption Spectrophotometry (AAS) was utilized for the determination of elements in the digested solutions. The analysis of black shale was performed precisely with relative standard deviation (RSD) lower than 2%. Results showed that the samples contained high concentrations of Ca (11.98 %), Al (7.09%), Fe (3.03%), Mg (0.59%) and Ti (0.58%).  相似文献   

Experimental constraints on the volatility of germanium,zinc, and lithium in Martian basalts and the role of degassing in alteration of surface minerals     

Alexander Rogaski  Gokce K. Ustunisik  Shuying Yang  Munir Humayun  Kevin Righter  Jeff A. Berger  Nicholas DiFrancesco 《Meteoritics & planetary science》2023,58(9):1183-1210

The surface of Mars is enriched in Cl and S which is linked to volcanic activity and degassing. Similarly, elevated Ge and Zn levels in Gale crater sedimentary bedrock indicate a magmatic source for these elements. To constrain the relative effects of Cl and S on the outgassing of these trace metals and chemical characteristics of primary magmatic vapor deposits incorporated to Martian surface, we conducted a set of degassing and fumarolic alteration experiments. Ge is found to be more volatile than Zn in all experiments. In S-bearing runs, the loss of Ge and Zn was less than any other experiments. In Cl-only runs, degassing of Zn was more than twice that of Ge within the first 10 min and percent loss increased for both elements with increasing time. In Cl + S runs, S-induced reduction of GeO₂ and ZnO to metallic Ge and Zn switches the preference of chloride formation from Zn to Ge. Up to 90% of Ge and Zn loss in the 1-h no volatile-added (NVA) experiments might be due to the small amounts of Cl contamination in NVA mixes via other oxides used for synthesis. Alteration experiments show different phases between 1-h and 24-/72-h runs. In 1-h runs, anhydrite and langbeinite dominate while in 24-/72-h runs halite and sylvite dominate the condensate assemblages. S-bearing phases form as the intermediate products of fumarolic deposition, while chlorides are common when the system is allowed to cool gradually. One-hour exposure was sufficient to form alteration phases and vapor deposits such as NaCl, KCl, CaSO₄, and langbeinites on the Martian analog minerals. These salts were identified in Martian meteorites and in situ measurements. Our results provide evidence that volcanic degassing along with fumarolic alteration could be a potential source for the enrichment and varying abundances of Cl, S, Fe, Zn, Ge in Martian surface, as well as a cause for Ge depletion in shergottites.  相似文献   

Si‐bearing metal and niningerite in Almahata Sitta fine‐grained ureilites and insights into the diversity of metal on the ureilite parent body     

Marian Horstmann  Munir Humayun  Mario Fischer‐Gödde  Addi Bischoff  Mona Weyrauch 《Meteoritics & planetary science》2014,49(10):1948-1977

A detailed mineralogical and chemical study of Almahata Sitta fine‐grained ureilites (MS‐20, MS‐165, MS‐168) was performed to shed light on the origin of these lithologies and their sulfide and metal. The Almahata Sitta fine‐grained ureilites (silicates <30 μm grain size) show textural and chemical evidence for severe impact smelting as described for other fine‐grained ureilites. Highly reduced areas in Almahata Sitta fine‐grained ureilites show large (up to ～1 mm) Si‐bearing metal grains (up to ～4.5 wt% Si) and niningerite [Mg_>0.5,(Mn,Fe)_<0.5S] with some similarities to the mineralogy of enstatite (E) chondrites. Overall, metal grains show a large compositional variability in Ni and Si concentrations. Niningerite grains probably formed as a by‐product of smelting via sulfidation. The large Si‐Ni variation in fine‐grained ureilite metal could be the result of variable degrees of reduction during impact smelting, inherited from coarse‐grained ureilite precursors, or a combination of both. Large Si‐bearing metal grains probably formed via coalescence of existing and newly formed metal during impact smelting. Bulk and in situ siderophile trace element abundances indicate three distinct populations of (1) metal crystallized from partial melts in MS‐20, (2) metal resembling bulk chondritic compositions in MS‐165, and (3) residual metal in MS‐168. Almahata Sitta fine‐grained ureilites developed their distinctive mineralogy due to severe reduction during smelting. Despite the presence of E chondrite and ureilite stones in the Almahata Sitta fall, a mixing relation of E chondrites or their constituents and ureilite material in Almahata Sitta can be ruled out based on isotopic, textural, and mineral‐chemical reasons.  相似文献   

Drinking quality assessment of some groundwater sources along the stretch of Jhelum River in Kashmir Himalaya   总被引：1，自引：0，他引：1  

Rifat Ara Wani  Bhat Mohd Skinder  Aasimah Tanveer  Bashir Ahmad Ganai 《Environmental Earth Sciences》2017,76(18):630

The physicochemical properties and major ion chemistry of the groundwater sources from alluvial aquifers along the stretch (60 km) of Jhelum River in Kashmir Himalaya were determined in order to identify hydro-geochemical processes and their suitability for drinking purposes. The data depicted that calcium and bicarbonates were dominating among the cations and anions. The results indicate the trend of cation dominance as Ca²⁺ > Na⁺ > Mg²⁺ > K⁺, whereas anion dominance was in the order of HCO₃ ^? > Cl^? > SO₄ ^2?. Ratio of calcium to magnesium indicated the dissolution of Ca²⁺ from CaCO₃, which results in an increased levels of Ca²⁺ in the groundwater. Interpretation of Piper Trilinear plot understands the various geochemical processes affecting the groundwater quality and shows groundwater was dominated by Ca–HCO₃ type. The pH was recorded in the slightly alkalinity range 7.2–7.8 and was showing positive correlation with HCO₃ ^?. The chloro-alkaline indices revealed 86% of the sources exchange by a type of base-exchange reactions, rest by cation–anion exchange. Gibbs diagram revealed groundwater sources fall in the category of rock dominance. The concentration of the nitrogen compounds was in the progression of NO₃–N > NH₄–N > NO₂–N, and the PO₄ ^? fluctuated from 0.12 to 0.22 mg/L. Moreover, corrosivity ratio indicated that water from the majority of sources (71%) is safe to supply using pipes without any corrosive effects, while 29% of sources are corrosive in nature and need non-corrosive pipes for transporting and lifting of groundwater. The results revealed, groundwater samples were within permissible limits as prescribed by International and National standards, for drinking purposes. The State government and NGO’s can show their interest in utilizing such water resources to overcome the shortage of drinking water in a sustainable way for the daily consumption of the people living in the vicinity of Jhelum River.  相似文献   

Re-Os isotopic systematics and platinum group element composition of the Tagish Lake carbonaceous chondrite     

Alan D. Brandon  Munir Humayun  Igor S. Puchtel  Michael E. Zolensky 《Geochimica et cosmochimica acta》2005,69(6):1619-1631

The Tagish Lake meteorite is a primitive C2 chondrite that has undergone aqueous alteration shortly after formation of its parent body. Previous work indicates that if this type of material was part of a late veneer during terrestrial planetary accretion, it could provide a link between atmophile elements such as H, C, N and noble gases, and highly siderophile element replenishment in the bulk silicate portions of terrestrial planets following core formation. The systematic Re-Os isotope and highly siderophile element measurements performed here on five separate fractions indicate that while Tagish Lake has amongst the highest Ru/Ir (1.63 ± 0.08), Pd/Ir (1.19 ± 0.06) and ¹⁸⁷Os/¹⁸⁸Os (0.12564-0.12802) of all carbonaceous chondrites, these characteristics still fall short of those necessary to explain the observed siderophile element systematics of the primitive upper mantles of Earth and Mars. Hence, a direct link between atmophile and highly siderophile elements remains elusive, and other sources for replenishment are required, unless an as yet poorly constrained process fractionated Re/Os, Ru/Ir, and Pd/Ir following late accretion on both the Earth and Mars mantles.The unique elevated Ru/Ir combined with elevated ¹⁸⁷Os/¹⁸⁸Os of Tagish Lake may be attributed to Ru and Re mobility during aqueous alteration very early in its parent body history. The Os, Ir, Pt, and Pd abundances of Tagish Lake are similar to CI chondrites. The elevated Ru/Ir and the higher Re/Os and consequent ¹⁸⁷Os/¹⁸⁸Os in Tagish Lake, are balanced by a lower Ru/Ir and lower Re/Os and ¹⁸⁷Os/¹⁸⁸Os in CM-chondrites, relative to CI chondrites. A model that links Tagish Lake with CI and CM chondrites in the same parent body may explain the observed systematics. In this scenario, CM chondrite material comprises the exterior, grading downward to Tagish Lake material, which grades to CI material in the interior of the parent body. Aqueous alteration intensifies towards the interior with increasing temperature. Ruthenium and Re are mobilized from the CM layer into the Tagish Lake layer. This model may thus provide a potential direct parent body relationship between three separate groups of carbonaceous chondrites.  相似文献   

Tungsten and hafnium distribution in calcium-aluminum inclusions (CAIs) from Allende and Efremovka   总被引：1，自引：0，他引：1  

Munir Humayun  Steven B. Simon 《Geochimica et cosmochimica acta》2007,71(18):4609-4627

Recent ¹⁸²Hf-¹⁸²W age determinations on Allende Ca-, Al-rich refractory inclusions (CAIs) and on iron meteorites indicate that CAIs have initial ε¹⁸²W (−3.47 ± 0.20, 2σ) identical to that of magmatic iron meteorites after correction of cosmogenic ¹⁸²W burn-out (−3.47 ± 0.35, 2σ). Either the Allende CAIs were isotopically disturbed or the differentiation of magmatic irons (groups IIAB, IID, IIIAB, and IVB) all occurred <1 m.y. after CAI formation. To assess the extent of isotopic disturbance, we have analyzed the elemental distribution of Hf and W in two CAIs, Ef2 from Efremovka (CV3 reduced), and Golfball from Allende (CV3 oxidized). Fassaite is the sole host of Hf (10-25 ppm) and, therefore, of radiogenic W in CAIs, with ¹⁸⁰Hf/¹⁸⁴W > 10³, which is lowered by the ubiquitous presence of metal inclusions to ¹⁸⁰Hf/¹⁸⁴W > 10 in bulk fassaite. Metal alloy (Ni ∼ 50%) is the sole host of W (∼500 ppm) in Ef2, while opaque assemblages (OAs) and secondary veins are the hosts of W in Golfball. A large metal alloy grain from Ef2, EM2, has ¹⁸⁰Hf/¹⁸⁴W < 0.006. Melilite has both Hf and W below detection limits (<0.01 ppm), but the presence of numerous metallic inclusions or OAs makes melilite a carrier for W, with ¹⁸⁰Hf/¹⁸⁴W < 1 in bulk melilite. Secondary processes had little impact on the ¹⁸²Hf-¹⁸²W systematics of Ef2, but a vein cross-cutting fassaite in Golfball has >100 ppm W with no detectable Pt or S. This vein provides evidence for transport of oxidized W in the CAI. Because of the ubiquitous distribution of OAs, interpretations of the ¹⁸²Hf-¹⁸²W isochron reported for Allende CAIs include: (i) all W in the OAs was derived by alteration of CAI metal, or (ii) at least some of the W in OAs may have been equilibrated with radiogenic W during metamorphism of Allende. Since (ii) cannot be ruled out, new ¹⁸²Hf-¹⁸²W determinations on CAIs from reduced CV3 chondrites are needed to firmly establish the initial W isotopic composition of the solar system.  相似文献   

Formation of metal in the CH chondrites ALH 85085 and PCA 91467     

Andrew J. Campbell  Munir Humayun 《Geochimica et cosmochimica acta》2004,68(16):3409-3422

Siderophile element distributions within individual metal grains in two CH chondrites, Allan Hills 85085 and Pecora Escarpment 91467, were measured by laser ablation inductively coupled plasma mass spectrometry. Those metal grains that are zoned in Ni were also found to be zoned in other refractory siderophile elements, such as Ru, but not in Pd, which is not refractory but is highly siderophile. This pattern is consistent with an origin by condensation from a gas of approximately solar composition, but not with an origin by redox processes or fractional crystallization. The unzoned metal grains in CH chondrites were found to be frequently depleted in Ru but not in Pd, consistent with later stage condensation from a solar gas after removal of the zoned metal. Gold is inversely correlated with Ni in the unzoned metal grains, and mean Au abundances in zoned metal are always low. Both zoned and unzoned metal in CH chondrites could plausibly be produced from a thermostatically regulated nebula, followed by rapid removal of the zoned metal, and slower removal of the unzoned metal, both at temperatures near or above the condensation temperature of Au (∼1250 K). This is also consistent with the isolation temperatures inferred from silicate grains in CH chondrites by previous workers based on their volatile element inventories. The volatile siderophile Cu is enriched in the rims relative to the interiors of both zoned and unzoned grains, and is interpreted as the product of diffusion during low-grade thermal processing. The similarity of Cu distributions, and degree of kamacite/taenite exsolution, between zoned and unzoned metal in CH chondrites suggests that the two populations of metal experienced modest thermal metamorphism after they were brought together in the same environment, probably on the CH parent body. Fragmentation and size-sorting of the metal must have post-dated the Cu zoning, and may have occurred in a regolith on the CH parent body. The compositions of CH metal, like that of metal from QUE 94411 and HH 237, are consistent with a nebular origin, and may be the most primitive nebular materials (as distinct from presolar grains) sampled by chondrites.  相似文献