Trace element distribution among rock-forming minerals from metamorphosed to partially molten basic igneous rocks in a contact aureole (Fuerteventura, Canaries)     

M.I. Holloway  F. Bussy 《Lithos》2008,102(3-4):616-639

Low pressure partial melting of basanitic and ankaramitic dykes gave rise to unusual, zebra-like migmatites, in the contact aureole of a layered pyroxenite–gabbro intrusion, in the root zone of an ocean island (Basal Complex, Fuerteventura, Canary Islands). These migmatites are characterised by a dense network of closely spaced, millimetre-wide leucocratic segregations. Their mineralogy consists of plagioclase (An_32–36), diopside, biotite, oxides (magnetite, ilmenite), +/− amphibole, dominated by plagioclase in the leucosome and diopside in the melanosome. The melanosome is almost completely recrystallised, with the preservation of large, relict igneous diopside phenocrysts in dyke centres. Comparison of whole-rock and mineral major- and trace-element data allowed us to assess the redistribution of elements between different mineral phases and generations during contact metamorphism and partial melting.

Dykes within and outside the thermal aureole behaved like closed chemical systems. Nevertheless, Zr, Hf, Y and REEs were internally redistributed, as deduced by comparing the trace element contents of the various diopside generations. Neocrystallised diopside – in the melanosome, leucosome and as epitaxial phenocryst rims – from the migmatite zone, are all enriched in Zr, Hf, Y and REEs compared to relict phenocrysts. This has been assigned to the liberation of trace elements on the breakdown of enriched primary minerals, kaersutite and sphene, on entering the thermal aureole. Major and trace element compositions of minerals in migmatite melanosomes and leucosomes are almost identical, pointing to a syn- or post-solidus reequilibration on the cooling of the migmatite terrain i.e. mineral–melt equilibria were reset to mineral–mineral equilibria.  相似文献   

Geochemistry of S-type granitic rocks from the reversely zoned Castelo Branco pluton (central Portugal)     

I.M.H.R. Antunes  A.M.R. Neiva  M.M.V.G. Silva  F. Corfu 《Lithos》2008,103(3-4):445-465

The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in ⁸⁷Sr/⁸⁶Sr_310 Ma between 0.708 and 0.712, Nd_310 Ma values between − 1 and − 4 and δ¹⁸O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ¹⁸O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.  相似文献   

Geological structure, evolution stages, and petroliferous complexes of the Gulf of Mexico basin     

A. I. Konyukhov 《Lithology and Mineral Resources》2008,43(4):380-393

The Gulf of Mexico basin occupies a vast region encompassing the southern continental margin of North America, a considerable part of the Greater Antilles, and the intervening Sigsbee Deep with the oceanic crust. In the north, the basin is contiguous with spurs of the Hercynian Appalachians, the Mississippi Interior and Permian basins. The Mississippi Fan, one of the largest in the world, governs the bottom topography and structure in the eastern Gulf of Mexico. The abyssal basin is surrounded in many areas by steep continental slopes passing in places into escarpments: Sigsbee, Campeche, and others. It is only in the Yucatan Peninsula region that the continental slope merges with a wide shelf. The Cuban-North Haiti meganticlinorium frames the basin on the Cuba Island side.  相似文献   

New data on geology of the Shatak Complex (western slope of the Southern Urals)     

S. G. Kovalev  I. V. Vysotskii 《Lithology and Mineral Resources》2008,43(3):250-259

The comprehensive study of sections of the Shatak Complex has revealed that conglomerates at the base of Middle Riphean rocks are not basal but intraformational rocks. Previously described angular unconformities between shales of the Sukhin Subformation (Yusha Formation, R₁) and conglomerates of the Kuz”elga Subformation (Mashak Formation, R₂) are related to late tectonic movements. Magmatic rocks developed at the base of the Middle Riphean section are represented by sheet intrusions formed in the course of emplacement of a fluid-saturated magmatic melt into partially or completely lithified terrigenous rocks at the graben formation stage during the origination of synkinematic faults that served as magma conduits. It is inferred that distribution of provenances of clastic materials and sedimentation basins in the Burzyanian and Yurmatian should be scrutinized in the study region, because the normal regressive sequence of rocks from the uppermost Yusha Formation to the lowermost Mashak Formation, which was established in the Shatak Ridge, eliminates a clear boundary distinguished between them at present. The idea about an older age of the Mashak conglomerates is substantiated.  相似文献   

Lithology and stratigraphy of the Ordovician facies complexes of Gornyi Altai     

V. N. Korzhnev 《Lithology and Mineral Resources》2008,43(6):596-602

In the Ordovician time, the transform margin of the Gornyi Altai region consisted of two bathymetric stages: (1) shelf and upper parts of continental slope; (2) foothills and lower parts of continental slope. The first stage includes the shallow-water facies complexes (terrigenous and terrigenous-carbonate schlieren and variegated flyschoid), while the second stage is composed of deep-water (black shale terrigenous) and subflysch gray (carbonate terrigenous) complexes. Model series of the facies complexes established in our work should be taken into account during the geodynamic analysis of fold zones.  相似文献   

Archean high-Mg monzodiorite–syenite,epidote skarn,and biotite–sericite gold lodes in the Granny Smith–Wallaby district,Australia: U–Pb and Re–Os chronometry of two intrusion-related hydrothermal systems     

Andreas G. Mueller  Gregory C. Hall  Alexander A. Nemchin  Holly J. Stein  Robert A. Creaser  Douglas R. Mason 《Mineralium Deposita》2008,43(3):337-362

The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie, in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia. At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma, cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km) thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite + calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series, high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + Fe_TOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO₂ metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid. At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid released by the source pluton of the differentiated alkali granite dikes.  相似文献   

Petrochemistry of the Paleoproterozoic Udokan copper-bearing sedimentary complex     

B. N. Abramov 《Lithology and Mineral Resources》2008,43(1):37-43

The maturity of terrigenous material of the Paleoproterozoic Udokan copper-bearing sedimentary complex is considered. The average values of hydrolyzate module (HM), alumina-silica module (AM), and Pettijohn’s coefficient of maturity appreciably vary throughout the Udokan Complex. Among cupriferous sandstones, rocks of the Aleksandrovka Formation are characterized by the highest maturity, whereas rocks of the Chitkanda Formation are distinguished by the lowest maturity. The maturity of cupriferous sandstones of the Sakukan Formation corresponds to that of host rocks. The maturity of cupriferous sandstones from the Aleksandrovka Formation is much higher than that of host rocks. In the Chitkanda Formation, the cupriferous sandstones are much less mature than host rocks. Climatic conditions in provenances estimated from the Nesbitt index of chemical weathering or chemical index of alteration (CIA) may be characterized as temperate ones without prominent climatic features. Most CIA values range from 46 to 66. The formation of copper-bearing sediments was closely related to the periods of volcanic activity.  相似文献   

Glauconite from Paleogene volcano-terrigenous rocks in Western Kamchatka     

A. R. Geptner  T. A. Ivanovskaya  E. V. Pokrovskaya  N. P. Kuralenko 《Lithology and Mineral Resources》2008,43(3):228-249

It is shown that glauconite-bearing interbeds are widespread in the layer-by-layer studied sections on the Sea of Okhotsk coast (Mainach section) and Kheisliveem River valley (Kavran section), the volcanoterrigenous rocks of the Kovachin, Amanin, and Gakkhin formations of the Paleogene in western Kamchatka (Upper Eocene-Lower Oligocene boundary beds). Detailed mineralogical and structural-crystallochemical characteristics of glauconite from the Amanin Formation are presented. It is suggested that such glauconite should not be used for geochronological purposes.Some specific features of glauconite formation, particularly, the preservation of specific morphological forms at high accumulation rates of volcano-terrigenous rocks, are discussed. Possibility of the formation of glauconite with the active influence of bacterial metabolism is considered.  相似文献   

The 45th anniversary of the journal <Emphasis Type="Italic">Lithology and Mineral Resources</Emphasis>     

V. N. Kholodov 《Lithology and Mineral Resources》2008,43(4):303-306

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Some types of small clinoforms in latest continental deposits     

G. F. Ufimtsev 《Lithology and Mineral Resources》2008,43(1):76-80

Some rare types of small clinoforms found in the latest continental deposits of lowland platform and mountain regions are described. The clinoforms are represented by prodelta deposits of mountain lakes, oblique-bedded horizons of floodplain alluvium of strongly meandering rivers, thick and short lenses of mountain alluvium, and alluvium horizons of great lowland rivers with oblique bedding grading into horizontal bedding. Such structures bear information on paleogeographic, morphological, and lithodynamic features of continental sedimentation.  相似文献